The ionic conductivity of Li6BaLa2M2O12 with coexisting Nb and Ta on the M sites

In a view to balancing cost and lithium ion conductivity, Li₆BaLa₂Nb _x Ta_2???x O₁₂ (x?=?0–2) was prepared by solid-state reaction, and its corresponding AC impedances were tested at temperatures ranging from 20 to 250 °C in air. Li₆BaLa₂Ta₂O₁₂ exhibits the highest conductivity, 8.77?×?10^?6?S/cm, and the second highest is Li₆BaLa₂Nb₂O₁₂ with 6.69?×?10^?6?S/cm. Partial replacement of Ta with Nb cannot bestow the advantages of cost saving or the enhancement of lithium ion conductivity. X-ray diffraction patterns revealed a gradual change as an increasing amount of Nb replaces Ta in Li₆BaLa₂Nb _x Ta_2???x O₁₂ (x?=?0–2), and it is thought that the trending of Nb and Ta to rest on the crystallographic planes is different.     

微波对人眼的危害及其防护的物理分析

根据已有的微波对眼睛伤害的实例,结合人的眼睛结构,从理论上分析微波对眼睛危害产生的原因.同时,指出了在微波操作和使用过程中,如何保护好自己的眼睛.     

Dual-fibre stretcher and coma as tools for independent 2nd and 3rd order tunable dispersion compensation in a fibre-based ‘scan-free’ time domain optical coherence tomography system

Dispersion compensation up to the third order is experimentally demonstrated by using a dual-fibre stretcher combined with the coma of an imaging lens, in a fibre-based scan-free time domain optical coherence tomography system, leading to an axial resolution of less than 3 μm.     

用时间分辨光谱研究红细胞悬液的荧光发射

实验获得了激光照射红细胞悬液的荧光光谱,并分别监测不同荧光峰值波长处强度随时间的衰变过程,测试了其相应的荧光寿命.结果表明,在波长为407 nm的激光照射下,红细胞悬液向外发射中心波长分别位于596,628,692 nm的荧光光谱,各荧光峰对应衰变过程的平均荧光寿命分别为1.97,13.31,14.58 ns.利用荧光强度和吸收率的加和性表示了混合物的总吸收率和总荧光发射强度,通过理论计算获得了红细胞悬液中锌卟啉、原卟啉和其他游离物参与荧光发射的相对含量和相对强度在不同荧光峰位的变化关系,进一步解释了不同峰位处荧光发射强度和平均荧光寿命的变化原因.     

Channel structure in the new BiCoPO5. Comparison with BiNiPO5. Crystal structure,lone pair localisation and infrared characterisation

The new compound BiCoPO₅, monoclinic, P2₁/n, a = 7.2470(1) A, b = 11.2851(2) A, c = 5.2260(1) A and β = 107.843(1) °, Z = 4, was synthesised and structurally characterised by powder X- ray diffraction and infrared spectroscopy. It is isostructural with bismuth nickel oxyphosphate BiNiOPO₄. The crystal structure is built from a complex tridimensional assembly of (Co/Ni)₂O₁₀ dimers linked by PO₄ groups. This forms large tunnels running along c which host Bi³⁺ cations. Smaller tunnels running along a and crossing the latter were also evidenced. It is noteworthy that the original BiNiPO₅ lattice is appreciably increased with Co²⁺ cations as the transition metal. This feature is essentially pointed out by the Co-O longer distances. The Bi³⁺ cation is surrounded by a strongly distorted oxygen octahedron. Reducing the BiO bonds to the three shortest, Bi environment can be considered as tetrahedral considering the BiO₃Lp polyhedron, Lp = 6s² lone pair (Lp). The lone pair localisation was performed from electrostatic interactions and revealed Lp - Bi distance of 0.68 A and 0.58 A, for Co²⁺ and Ni²⁺ compounds respectively. The infrared spectra of the two compounds are essentially the same and only show slight shifts of the significant bands.     

Cascade C?N and C?O bond constructions for the synthesis of dibenzoimidazo[1,4]oxazepines catalyzed by CuI/o-phen

A novel method for the synthesis of dibenzo[b,f]imidazo[1,2-d][1,4]oxazepine derivatives was described via cascade Csp² N and Csp² O bond constructions. It was a crossed double Ullmann reactions using 4,5-diaryl-2-(2-hydroxylphenyl)-1H-imidazole as the double nucleophilic centers in the presence of Cs₂CO₃, while 1-bromo-2-iodobenzene was used as a substrate catalyzed by CuI and o-phenanthroline in good yields.     

利用自由基引发的1,2-炔基迁移实现非活性烯烃的炔膦酰化

研究了1,4-烯炔衍生物与二芳基膦氧化物在银介导下发生的炔酰化反应.该反应利用自由基引发的1,2-炔基迁移策略合成了一系列γ-酮膦氧化物,产率适中.该反应机理可能涉及膦中心自由基与乙烯基的加成、3-exo-dig环化和1,2-炔基迁移等连续的过程,一步形成了C-P、C-C键等化学键,实现了非活性烯烃的双官能化.