全文获取类型
收费全文 | 18515篇 |
免费 | 3204篇 |
国内免费 | 2095篇 |
专业分类
化学 | 12846篇 |
晶体学 | 145篇 |
力学 | 1096篇 |
综合类 | 109篇 |
数学 | 2608篇 |
物理学 | 7010篇 |
出版年
2024年 | 18篇 |
2023年 | 413篇 |
2022年 | 372篇 |
2021年 | 557篇 |
2020年 | 845篇 |
2019年 | 754篇 |
2018年 | 653篇 |
2017年 | 612篇 |
2016年 | 917篇 |
2015年 | 867篇 |
2014年 | 1040篇 |
2013年 | 1402篇 |
2012年 | 1641篇 |
2011年 | 1745篇 |
2010年 | 1226篇 |
2009年 | 1074篇 |
2008年 | 1231篇 |
2007年 | 1089篇 |
2006年 | 972篇 |
2005年 | 858篇 |
2004年 | 692篇 |
2003年 | 595篇 |
2002年 | 629篇 |
2001年 | 499篇 |
2000年 | 408篇 |
1999年 | 400篇 |
1998年 | 310篇 |
1997年 | 284篇 |
1996年 | 302篇 |
1995年 | 275篇 |
1994年 | 221篇 |
1993年 | 157篇 |
1992年 | 161篇 |
1991年 | 146篇 |
1990年 | 115篇 |
1989年 | 87篇 |
1988年 | 48篇 |
1987年 | 43篇 |
1986年 | 52篇 |
1985年 | 34篇 |
1984年 | 17篇 |
1983年 | 18篇 |
1982年 | 14篇 |
1981年 | 7篇 |
1980年 | 4篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1969年 | 1篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 171 毫秒
1.
Rui Feng Zi-Ying Li Zhao-Quan Yao Zi-Ang Guo Yi-Nan Zhang Hao-Xiang Sun Wei Li Xian-He Bu 《中国科学:化学(英文版)》2022,65(1):128-134
The rational designability and chemical tunability of metal-organic frameworks(MOFs)are enabling tributes to efficaciously enhance their room temperature phosphorescence(RTP)performance.A family of stable anionic MOFs,[Zn2(4,5-ImDC)2]M2(NKU-132,M=(CH3)2NH2or(CH2CH3)2NH2),featuring significant RTP have been synthesized.By rational cation selection and in-situ replacement from dimethylammonium to diethylammonium,the phosphorescence lifetime is increased from 30.88 to126.3 ms,along with less sensitivity to air.This work provides an anti-quenching and lifetime tuning example for RTP-MOFmaterials via facile host-guest chemistry. 相似文献
2.
Yu He Yating Guo Yanbin Yu Peifu Luo Honglong Qiu Guoming Huang 《Particle & Particle Systems Characterization》2021,38(5):2100038
In this study, manganese tellurite (MnTeO3) nanoparticles are developed as theranostic agents for magnetic resonance imaging (MRI)-guided photothermal therapy of tumor. MnTeO3 nanoparticles are synthesized via a simple one-step method. The as-synthesized MnTeO3 nanoparticles with uniform size show good biocompatibility. In particular, MnTeO3 nanoparticles exhibit a high photothermal conversion efficiency (η = 26.3%), which is higher than that of gold nanorods. Moreover, MnTeO3 nanoparticles also have high MRI performance. The longitudinal relaxivity (r1) value of MnTeO3 nanoparticles is determined to be 8.08 ± 0.2 mm −1 s−1, which is higher than that of clinically approved T1-contrast agents Gd-DTPA (4.49 ± 0.1 mm −1 s−1). The subsequent MnTeO3 nanoparticles-mediated photothermal therapy displays a highly efficient ablation of tumor cells both in vitro and in vivo with negligible toxicity. It is demonstrated that MnTeO3 nanoparticles can serve as promising theranostic agents with great potentials for MRI-guided photothermal therapy. 相似文献
3.
Journal of Algebraic Combinatorics - APR tilts for path algebra kQ can be realized as the mutation of the quiver Q in $${\mathbb Z}Q$$ with respect to the translation. In this paper, we show that... 相似文献
4.
Bohuai Xiao Jianqiao Dong Zhiye Wang Xu Wang Mingjun Sun Jing Guo Gongming Qian Yunchuan Li Shuai Chang 《Chemphyschem》2022,23(7):e202100833
One important prerequisite for the fabrication of molecular functional device strongly relies on the understanding the conducting behaviors of the metal-molecule-metal junction that can respond to an external stimulus. The model Lewis basic molecule 4,4′-(pyridine-3,5-diyl)dibenzonitrile (DBP), which can react with Lewis acid and protic acid, was synthesized. Then, the molecular conducting behavior of DBP, DBP-B(C6F5)3, and DBP-TfOH (DBP-B(C6F5)3, and DBP-TfOH were produced by Lewis acid and protonic acid treatment of DBP) was researched and compared. Given that their identical physical paths for DBP, DBP-B(C6F5)3, and DBP-TfOH to sustain charge transport, our results indicate that modifying the molecular electronic structure, even not directly changing the conductive physical backbone, can tune the charge transporting ability by nearly one order of magnitude. Furthermore, the addition of another Lewis base triethylamine (of stronger alkaline than DBP), to Lewis acid-base pair reverts the electrical properties back to that of a single DBP junction, that is constructive to propose a useful but simple strategy for the design and construction of reversible and controllable molecular device based on pyridine derived molecule. 相似文献
5.
Yuan Xin Zhang Shuren Zhong Xuanmeng Yuan Hao Song Dongfan Wang Xiaoyu Yu Hanyang Guo Zijian 《中国科学:化学(英文版)》2022,65(10):1978-1984
Science China Chemistry - Oncogenic KRAS reprograms pancreatic ductal adenocarcinoma (PDAC) cells to a state that is awfully resistant to apoptosis. An alternative coping strategy is to trigger a... 相似文献
6.
Mathematical Notes - All the groups considered in this paper are finite, and $$G$$ always denotes a finite group; $$\sigma$$ is a partition of the set $$\mathbb{P}$$ of all primes, i.e.,... 相似文献
7.
A transition in a graph is defined as a pair of adjacent edges. A transition system of an Eulerian graph refers to a set of partitions such that for each vertex of the graph, there corresponds to a partition of the set of edges incident to the vertex into transitions. A generalized transition system over a graph defines a set of transitions over . A compatible Eulerian circuit of an Eulerian graph with a generalized transition system is defined as an Eulerian circuit in which no two consecutive edges form a transition defined by . In this paper, we further introduce the concept of weakly generalized transition system which is an extension of the generalized transition system and prove some Ore-type sufficient conditions for the existence of compatible Eulerian circuits in Eulerian graphs with (weakly) generalized transition systems and obtain corresponding results for Eulerian digraphs. Our conditions improve some previous results due to Jackson and Isaak, respectively. 相似文献
8.
Can Li Dr. Zheng Yang Lei Wang Prof. Dr. Yinlong Guo Prof. Dr. Zheng Huang Prof. Dr. Shengming Ma 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(15):6337-6342
An efficient pincer-ligand-based cobalt-complex-catalyzed allene hydroboration affording Z-allylic boronates is described. The reaction demonstrates an excellent regio- as well as Z-stereoselectivity and a wide substrate scope that tolerates many functional groups. Based on solvent-assisted electrospray ionization mass spectrometry (SAESI-MS) studies, a rationale for the cobalt-catalyzed hydroboration involving the highly selective insertion of an allene into the Co−H bond to form Z-allylic cobalt intermediates is proposed. 相似文献
9.
Wang Xinglei Guo Hangxu Wang Fan Tan Tianshe Wu Hang Zhang Hongxia 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(3):1151-1165
Journal of Radioanalytical and Nuclear Chemistry - In this study, the halloysite nanotubes was characterized and the adsorption of Th(IV) and U(VI) on halloysite nanotubes was investigated as a... 相似文献
10.
Victor J. W. Guo 《Czechoslovak Mathematical Journal》2018,68(2):577-580
We give a new and elementary proof of Jackson’s terminating q-analogue of Dixon’s identity by using recurrences and induction. 相似文献