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1.
In this work, the electrocatalytic reduction of dichloromethane (CH2Cl2) into hydrocarbons involving a main group element-based molecular triazole-porphyrin electrocatalyst H2PorT8 is reported. This catalyst converted CH2Cl2 in acetonitrile to various hydrocarbons (methane, ethane, and ethylene) with a Faradaic efficiency of 70 % and current density of −13 mA cm−2 at a potential of −2.2 V vs. Fc/Fc+ using water as a proton source. The findings of this study and its mechanistic interpretations demonstrated that H2PorT8 was an efficient and stable catalyst for the hydrodechlorination of CH2Cl2 and that main group catalysts could be potentially used for exploring new catalytic reaction mechanisms.  相似文献   
2.
The fundamental properties of nonlinear ion hole modes propagating in current-driven collisionless plasmas are derived. Making use of Schamel's alternative method their spatial structure ?(x) and phase velocities u0 are analyzed and found to depend crucially on the used trapped ion distribution fit. A regular fit represents a continuous spectrum, which is called privileged or perfect since it yields a definite u0 and appears most realistic. A singular fit, on the other hand, involving jumps and moderate slope singularities at the separatrix, does reveal further classes of hole equilibria at the cost, however, of a well-defined u0. This explains why Bernstein, Greene, Kruskal (BGK)-solutions of the Vlasov–Poisson system, exhibiting a strong slope singularity of their derived trapped particle distribution, can principally not provide definite u0s. The nonlinear dispersion relation (or u0) of privileged ion holes, on the other hand, is equivalent with that of cnoidal electron holes, i.e. in addition to the ordinary ion acoustic branch there exists a correspondence to the “Langmuir” branch and to the multiple “slow electron acoustic” branches, reflecting different trapping scenarios.  相似文献   
3.
The role of viscosity coefficient(η′), coulomb coupling parameter(Γ) and dust mass on the growth of jeans mode is investigated in strongly coupled dusty plasma using equations of Generalized Hydrodynamics(GH) Model. The novel aspect of this work is that the force arising due to electrostatic pressure caused by grain grain interaction has been included in the dynamics of dust particles. This force is found to play a significant role in counter balancing the self gravity effect, thereby reducing the growth rate of jeans instability. The present work may provide more physical insight in understanding the mechanisms behind formation of planetesimals, stars etc.  相似文献   
4.
5.
SRUBABATI GOSWAMI 《Pramana》2016,86(2):395-405
In this paper, the recent progress in the determination of neutrino oscillation parameters and future prospects have been discussed. The tiny neutrino masses as inferred from oscillation data and cosmology cannot be explained naturally by the Higgs mechanism and warrant some new physics. The latter can be connected to the Majorana nature of the neutrinos which can be probed by neutrinoless double beta decay (0 νββ). The paper also summarizes the latest experimental results in 0 νββ and discusses some implications for the left–right symmetric model which could be a plausible new physics scenario for the generation of neutrino masses.  相似文献   
6.
The 232Th(n, ??) reaction cross-section at average neutron energies of 13.5, 15.5 and 17.28?MeV from the 7Li(p, n) reaction has been determined for the first time using activation and off-line ??-ray spectrometric technique. The 232Th(n, 2n) cross-section at 17.28?MeV neutron energy has also been determined using the same technique. The experimentally determined 232Th(n, ??) and 232Th(n, 2n) reaction cross-sections from the present work were compared with the evaluated data of ENDF/BVII and JENDL-4.0 and were found to be in good agreement. The present data, along with literature data in a wide range of neutron energies, were interpreted in terms of competition between 232Th(n, ??), (n, f), (n, nf) and (n, xn) reaction channels. The 232Th(n, ??) and 232Th(n, 2n) reaction cross-sections were also calculated theoretically using the TALYS 1.2 computer code and were found to be in good agreement with the experimental data from the present work but were slightly higher than the literature data at lower neutron energies.  相似文献   
7.
B DAS  R GOSWAMI  B BHOWMICK 《Pramana》2016,86(4):723-736
In this paper, we have developed a physics-based model for surface potential, channel potential, electric field and drain current for AlGaN/GaN high electron mobility transistor with high-K gate dielectric using two-dimensional Poisson equation under full depletion approximation with the inclusion of effect of polarization charges. The accuracy of the model has been verified and is found to be in good agreement with the simulated results.  相似文献   
8.
B K GOSWAMI 《Pramana》2011,77(5):987-1005
We study theoretically the effect of truncating the nonlinear restoring force (exp(F)-1=?n=1Fn/n!\exp (\Phi)-1={\sum}_{n=1}^{\infty}\Phi^{n}/n!) in the bistability pattern of the periodically driven, damped one-degree-of-freedom Toda oscillator that originally exhibits soft-spring bistability with counterclockwise hysteresis cycle. We observe that if the truncation is made third order, the harmonic bistability changes to hard-spring type with a clockwise hysteresis cycle. In contrast, for the fourth-order truncation, the bistability again becomes soft-spring type, overriding the effect of third-order nonlinearity. Furthermore, each higher odd-order truncation attempts to introduce hard-spring nature while each even-order truncation turns to soft-spring type of bistability. Overall, the hard-spring effect of every odd-order nonlinear term is weaker in comparison to the soft-spring effect of the next even-order nonlinear term. As a consequence, higher-order approximations ultimately converge to the soft-spring nature. Similar approximate analysis of Toda lattice has in recent past revealed remarkably similar flip-flop pattern between stochasticity (chaotic behaviour) and regularity (integrability).  相似文献   
9.
A new unsymmetrical aromatic diamine, viz., 4-pentadecylbenzene-1,3-diamine was synthesized through a series of reaction steps starting from 3-pentadecylphenol. 4-Pentadecylbenzene-1,3-diamine was employed to synthesize a series of new polyimides by one-step polycondensation in m-cresol with four commercially available aromatic dianhydrides, viz., 3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA), 3,3′,4,4′-benzophenonetetracarboxylic dianhydride (BTDA), 4,4′-oxydiphthalic anhydride (ODPA) and 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6-FDA). Inherent viscosities of resulting polyimides were in the range 0.33-0.67 dL/g and number average molecular weights were in the range 14,700-52,200 (GPC, polystyrene standard). Polyimides containing pendent pentadecyl chains were soluble in organic solvents such as chloroform, m-cresol, N,N-dimethylacetamide (DMAc), 1-methyl-2-pyrrolidinone (NMP), pyridine and nitrobenzene. Strong and flexible films of polyimides could be cast from their chloroform solutions. Polyimides exhibited glass transition temperature in the range 158-206 °C. The temperature at 10% wt. loss (T10), determined by TGA in nitrogen atmosphere, of polyimides was in the range 470-480 °C indicating good thermal stability.  相似文献   
10.
Two new aromatic diamines containing preformed amide linkages, viz., N,N′-(4-pentadecyl-1,3-phenylene)bis(4-aminobenzamide) I and N,N′-(4-pentadecyl-1,3-phenylene)bis(3-aminobenzamide) II, were synthesized by reaction of 4-pentadecylbenzene-1,3-diamine with 4-nitrobenzoylchloride and 3-nitrobenzoylchloride, followed by reduction of the respective dinitro derivatives. A series of new poly(amideimide)s was synthesized by polycondensation of I and II with four commercially available aromatic dianhydrides, viz., pyromellitic dianhydride (PMDA), 4,4′-biphenyltetracarboxylic dianhydride (BPDA), 4,4′-oxydiphthalic anhydride (ODPA), and 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6-FDA) in N,N-dimethylacetamide (DMAc) employing conventional two step method via poly(amic acid) intermediate followed by thermal imidization. Reference poly(amideimide)s were synthesized by polycondensation of N,N′-(1,3-phenylene)bis(4-aminobenzamide) and N,N′-(1,3-phenylene)bis(3-aminobenzamide) with the same aromatic dianhydrides. Inherent viscosities of poly(amideimide)s containing pendent pentadecyl chains were in the range 0.37-1.23 dL/g in N,N-dimethylacetamide at 30 ± 0.1 °C indicating the formation of medium to high molecular weight polymers. The poly(amideimide)s containing pendent pentadecyl chains were found to be soluble in N,N-dimethylacetamide, N,N-dimethylformamide, 1-methyl-2-pyrrolidinone and pyridine and could be cast into transparent, flexible and tough films from their N,N-dimethylacetamide solution. Wide angle X-ray diffraction patterns exhibited broad halo indicating that the polymers were essentially amorphous in nature. X-ray diffractograms also displayed sharp reflection in the small angle region (2θ ≈ 3°) for poly(amideimide)s containing pentadecyl chains indicating the formation of layered structure arising from packing of flexible pentadecyl chains. The glass transition temperatures observed for reference poly(amideimide)s were in the range 331-275 °C and those for poly(amideimide)s containing pendent pentadecyl chains were in the range 185-286 °C indicating a large drop in Tg owing to the “internal plasticization” effect of pentadecyl chains. The temperature at 10% weight loss (T10), determined by TGA in nitrogen atmosphere, were in the range 460-480 °C indicating their good thermal stability.  相似文献   
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