ICP-AES测定镉及镉合金中的杂质元素

采用ICP-AES同时测定镉及镉合金中锌、铅、铁、铜、砷、锑、锡、镍、铋、铊10种杂质元素的含量.各元素的检出限为0.0018-0.030μg/mL,相对标准偏差为1.36％-4.42％,样品加标回收率为90％-110％.测试结果表明,该法是测定镉及镉合金的简单、准确、快速的方法.     

Sorption of radionuclides on natural materials

Information about the sorption of radionuclides on natural materials used for cementation of liquid radioactive wastes (RAW) is important for predictions of migration rates of radionuclides in the products of fixation. Cementation process for conditioning liquid RAW uses, besides cement, materials which improve quality of products. In Czechoslovakia technology among these materials are clinoptilolite tuffit, mordenite tuff, tobermorite and fly ash. Liquid RAW issued from nuclear power plants contains the principal radionuclides⁶⁰Co,¹³⁴Cs and¹³⁷Cs, therefore, a sorption study of these radionuclides was carried out. pH of liquid RAW was 12.5–13.7 and salt content ca. 200 g·dm^–3. Results of sorption are given by distribution coefficients. The best results for cesium in those pH region and salt content had mordenite tuff D_Cs=100 dm³·kg^–1 and the worst results had fly ash D_Cs=4.1 dm³·kg^–1. The best results for cobalt in those solutions had tobermorite D_Co=38 dm³·kg^–1 and the worst results had fly ash D_Co=6.9 dm³·kg^–1.     

一维$P$-Laplace二阶差分系统奇异边值问题正解的存在性

应用锥压缩锥拉伸不动点定理和Leray-Schauder 抉择定理研究了一类具有P-Laplace算子的奇异离散边值问题$$\left\{\begin{array}{l}\Delta[\phi (\Delta x(i-1))]+ q_{1}(i)f_{1}(i,x(i),y(i))=0, ~~~i\in \{1,2,...,T\}\\\Delta[\phi (\Delta y(i-1))]+ q_{2}(i)f_{2}(i,x(i),y(i))=0,\\x(0)=x(T+1)=y(0)=y(T+1)=0,\end{array}\right.$$的单一和多重正解的存在性,其中$\phi(s) = |s|^{p-2}s, ~p>1$,非线性项$f_{k}(i,x,y)(k=1,2)$在$(x,y)=(0,0)$具有奇性.     

Photoluminescence and laser properties of mesostructured SBA-15 monolith doped with coumarin 151

Large, flawless and transparent silica monoliths were prepared at room temperature by solvent evaporation method and loaded with dye. The composites containing dye molecules were characterized by X-ray diffraction, transmission electron microscopy, Uv–vis and photoluminescence spectra. A red-shift in photoluminescence spectrum was observed from the composite monolith compared with that of laser dye in C₂H₅OH solution. The property of laser narrowing has been shown when the composites are pumped at _p = 355 nm by nitrogen laser.     

Approximation to continuous functions by Walsh-Fourier sums

Пусть ω(δ) - модуль непре рывности,H _ω — класс 1-периодических непре рывных функцийf (t), модуль непрерывнос ти которыхω(f, δ)≦ω(δ), и п устьS _n (f,x)=S _n (f),D _n (t), L_n – соответственно ча стичные суммы ряда Фу рье-Уолшаf(t), ядра Дирихле и конст анты Лебега порядкап (п- 1, 2, ...). Доказаны Теорема 1.Для любой не прерывной функции f $$\mathop {\lim \inf }\limits_{k \to \infty } \frac{{\parallel f - S_k (f)\parallel }}{{\omega (f,1/k)L_k }} = 0$$ Теорема 2.Пусть 0n=[nβ]+1 (n=1,2, ...). Пусть, далее, М_n — множество тех k (2ⁿk<2ⁿ⁺¹), для которых Тогда в каждом классе $$\int\limits_0^{2^{ - m_n } } {\left| {D_k (t)} \right|dt \geqq AL_k } $$ найдется функция f, т акая, что $$\mathop {\lim \inf }\limits_{k \in \mathop \cup \limits_n M_n } \frac{{\left\| {f - S_k (f)} \right\|}}{{\omega (1/k)L_k }} \geqq B(A) > 0$$      

Retention of some radionuclides in furnace lining during incineration of radioactive wastes

The incineration is one of the widely used method for treatment of solid radioactive wastes. The high volume and weight reduction coefficient (100–150 respectively 10–15) are advantages of this method. The greater part of radionuclides from solid radioactive wastes is retained in ash. From point of view of workers external irradiation, the radionuclides accumulation in furnace lining is one of risk factors. The Kalinit O 1200 is furnace lining material on NPPRIs Experimental Incineration facility. In the first step the sorption properties of this material from¹³⁷Cs,⁶⁰Co,⁵⁴Mn,⁶⁵Zn solutions were studied. The best results had⁶⁰Co, its distribution coefficient was 7036 kg · dm^–3. Cesium-137 was not absorbed on this material. The cylinders (height 5 cm, diameter 2 cm) from lining materials were made latest and were applicated inside the furnace and technological tract to study sorption properties from combustion gases. The penetration of radionuclide into lining material was studied too. The results obtained with this experiments are described in this paper.     

Recovery of cesium from intermediate level liquid radioactive waste

The antioxidant Lowinox 22M46 (Naftonox 22M46) were used for the extraction of cesium from intermediate level liquid radioactive wastes.