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1.
Set-Valued and Variational Analysis - We aim to establish Karush-Kuhn-Tucker multiplier rules involving higher-order complementarity slackness under Hölder metric subregularity. These rules...  相似文献   
2.
The high-entropy materials have raised much attention in recent years due to their extraordinary performances in mechanical, catalysis, energy storage fields. Herein, a new type of high-entropy hydroxides (e.g., NiFeCoMnAl(OH)x) that are amorphous and capable of broad solar absorption is reported. A facile one-pot co-precipitation method is employed to synthesize these amorphous high-entropy hydroxides (a-HEHOs) under ambient conditions. The a-HEHOs thus obtained display widely tunable bandgap (e.g., from 2.6 to 1.1 eV) due to their high-entropy and amorphous characteristics, enabling efficient light absorbance and photothermal conversion in the solar regime. Further solar water evaporation measurements show that the a-HEHOs delivered a considerable energy conversion efficiency of 55%, comparable to black titanium oxides that are synthesized using more complex and expensive methods.  相似文献   
3.
郑琦  黄立  包德亮  武荣庭  李彦  林晓  杜世萱  高鸿钧 《中国物理 B》2022,31(1):18202-018202
The linkage structures between monomers make great influence on the properties of polymers.The synthesis of some special linkage structures can be challenging,which is often overcome by employing special reaction conditions.Here,we build dihydropentalene linkage in poly-naphthalocyanine on Ag(110)surface.Scanning tunneling microscopy(STM)and non-contact atomic force microscopy(nc-AFM)measurements confirm the dihydropentalene linkage structure and a possible formation path with reconstruction steps is proposed.The controlled experiment on Ag(100)surface shows no dihydropentalene structures formed,which indicates the grooved substrate is necessary for the reconstruction.This work provides insights into the surface restricted reactions that can yield special structures in organic polymers.  相似文献   
4.
Fuzzy Optimization and Decision Making - Data envelopment analysis (DEA) is a classical and prevailing tool for estimating relative efficiencies of multiple decision making units (DMUs). However,...  相似文献   
5.
Achieving tunable band gaps in a structure by external stimuli is of great importance in acoustic applications. This paper aims to investigate the tunability of band gaps in square-lattice-like elastic periodic structures that are usually not featured with notable band gaps.Endowed with chirality, the periodic structures here are able to undergo imperfection-insensitive large deformation under extension or compression. The influences of geometric parameters on band gaps are discussed via the nonlinear finite element method. It is shown that the band gaps in such structures with curved beams can be very rich and, more importantly, can be efficiently and robustly tuned by applying appropriate mechanical loadings without inducing buckling. As expected, geometry plays a more significant role than material nonlinearity does in the evolution of band gaps. The dynamic tunability of band gaps through mechanical loading is further studied. Results show that closing, opening, and shifting of band gaps can be realized by exerting real-time global extension or compression on the structure. The proposed periodic structure with well-designed chiral symmetry can be useful in the design of particular acoustic devices.  相似文献   
6.
We give different conditions for the invariance of closed sets with respect to differential inclusions governed by a maximal monotone operator defined on Hilbert spaces, which is subject to a Lipschitz continuous perturbation depending on the state. These sets are not necessarily weakly closed as in [3], [4], while the invariance criteria are still written by using only the data of the system. So, no need to the explicit knowledge of neither the solution of this differential inclusion, nor the semi-group generated by the maximal monotone operator. These invariant/viability results are next applied to derive explicit criteria for a-Lyapunov pairs of lower semi-continuous (not necessarily weakly-lsc) functions associated to these differential inclusions. The lack of differentiability of the candidate Lyapunov functions and the consideration of general invariant sets (possibly not convex or smooth) are carried out by using techniques from nonsmooth analysis.  相似文献   
7.
In this paper, we use character-theoretic techniques to give new nonexistence results for (n,m,k,λ)-strong external difference families (SEDFs). We also use cyclotomic classes to give two new classes of SEDFs with m=2.  相似文献   
8.
Development of effective organocatalysts for the living ring‐opening polymerization (ROP) of lactones is highly desired for the preparation of biocompatible and biodegradable polyesters with controlled microstructures and physical properties. Herein, a new class of hydrogen‐bond donating bisurea catalysts is reported for the ROP of lactones under solvent‐free conditions. ROP of lactones mediated by the bisurea/7‐methyl‐1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene (MTBD) catalyst exhibits a living/controlled manner, affording the polymers and copolymers with the well‐defined structure, predictable molecular weight, narrow molecular weight distribution, and high selectivity for monomer at low catalyst loadings at ambient temperature. The possible mechanism of bisurea/MTBD‐catalyzed ROP of lactones is proposed, in which the bisurea activates the carbonyl group of lactones while MTBD facilitates the nucleophilic attack of the initiating/propagating alcohol by hydrogen bonding. Moreover, the poly(ε‐caprolactone‐co‐δ‐valerolactone) [P(CL‐co‐VL)] random copolymers with various compositions were synthesized using the bisurea/MTBD catalyst. The measurements of thermal properties and crystalline structure demonstrate that the CL and VL units are cocrystallized in the crystalline phase of P(CL‐co‐VL) copolymers. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 90–100  相似文献   
9.
Real-time crime forecasting is important. However, accurate prediction of when and where the next crime will happen is difficult. No known physical model provides a reasonable approximation to such a complex system. Historical crime data are sparse in both space and time and the signal of interests is weak. In this work, the authors first present a proper representation of crime data. The authors then adapt the spatial temporal residual network on the well represented data to predict the distribution of crime in Los Angeles at the scale of hours in neighborhood-sized parcels. These experiments as well as comparisons with several existing approaches to prediction demonstrate the superiority of the proposed model in terms of accuracy. Finally, the authors present a ternarization technique to address the resource consumption issue for its deployment in real world. This work is an extension of our short conference proceeding paper [Wang, B., Zhang, D., Zhang, D. H., et al., Deep learning for real time Crime forecasting, 2017, arXiv: 1707.03340].  相似文献   
10.
In this paper, we present a compound, 2,3-diphenyl butyronitrile (DPBN), which can be used as a new and efficient radical initiator for the polymerization of methyl methacrylate (MMA) and styrene (St). Very different from other compounds as a carbon-carbon initiator, DPBN is an unsymmetrically substituted ethane and works with high initiation reactivity at lower temperatures. This new compound as an initiator exhibits various advantages, such as easy preparation, high initiation reactivity, safe use and storage, and convenient handling.  相似文献   
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