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1.
2.
Alphonse Cossa 《Fresenius' Journal of Analytical Chemistry》1867,6(1):24-28
Ohne Zusammenfassung 相似文献
3.
A series of 1,6-dienes is cyclized to cyclopentene derivatives under neutral conditions with palladium chloride in ethanol or with in situ generated LPd2+ in acetonitrile. 相似文献
4.
Tsang DS Yang S Alphonse FA Yudin AK 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(3):886-894
In the presence of rhodium(I) hydride catalysts, tertiary N-allylamines are known to isomerise into E enamines. In contrast, we have recently found that N-allylaziridines isomerise to form Z enamines. On the basis of literature data, the most likely mechanism of isomerisation would involve a rhodium hydride addition/beta-hydride elimination sequence. We show that the observed selectivity cannot be adequately explained by this pathway and is more consistent with initial CH-activation followed by rearrangement to form a five-membered cyclometallated rhodium intermediate. This intermediate subsequently undergoes reductive elimination to form a C--H bond. The resulting geometrically stable Z enamines are useful building blocks for stereoselective synthesis. 相似文献
5.
Moussa Mbaye Mame Diabou Gaye Seye Atanasse Coly Alphonse Tine Jean-Jacques Aaron 《Analytical and bioanalytical chemistry》2009,394(4):1089-1098
The photochemically induced fluorescence (PIF) spectral properties of α-cypermethrin in organic solvents (hexane, dichloromethane,
acetonitrile, ethanol) and in cyclodextrin aqueous solutions (β-CD and 2-hydroxypropyl-β-CD, 2-HP-β-CD) were investigated.
The photolysis kinetics of α-cypermethrin were evaluated in the various media. The PIF signal was found to be significantly
enhanced in the CD media relative to the organic solvents. The stoichiometry and the formation constants of the α-cypermethrin
inclusion complexes formed with the CDs were determined. The analytical performances of the PIF method were improved in the
presence of HP-β-CD relative to the other media, and a CD-enhanced PIF analytical method was developed. The limits of detection
and limits of quantification ranged, respectively, between 6 and 98 ng/mL and between 24 and 343 ng/mL, depending on the medium.
Application to the analysis of tap water and Senegal natural water samples collected close to agricultural areas and spiked
with α-cypermethrin yielded satisfactory recoveries going from about 77% to 98%. An interference study of foreign species,
including pesticides and inorganic ions likely to be present in natural waters, was also carried out.
Figure Photolysis reaction of α-cypermethrin in presence of HP-β-CD 相似文献
6.
Boehmite xerogels are prepared by hydrolysis of Al(OC4H9)3 followed by peptization with HNO3 (H+/Al = 0, 0.07, 0.2). XRD and TEM show that these gels are made of nanosized crystals (5-9 nm in width and 3 nm thick). According to the amount of acid, no significant differences are found in size and shape, but only in the spatial arrangement of the crystallites. Nitrogen adsorption-desorption isotherms of nonpeptized gels are of type IV, whereas isotherms of peptized gels are of type I. These isotherms are analyzed by the t-plot method. The majority of pore volume results from intercrystalline mesopores, but the peptized gels also contain intercrystalline micropores. The particle packing is very dense for the gel peptized with H+/Al = 0.2 (porosity = 0.26), but it is less dense in non-peptized gel (porosity = 0.44). Heating these gels under vacuum creates, from 250 degrees C onwards, an intracrystalline microporosity resulting from the conversion of boehmite into transition alumina. But heating also causes intercrystalline micropores collapsing. The specific surface area increases up to a limit temperature (300 degrees C for nonpeptized gels and 400 degrees C for peptized) beyond which sintering of the particles begins and the surface decreases. The PSD are calculated assuming a cylindrical pore geometry and using the corrected Kelvin equation proposed by Kruk et al. Peptized xerogels give a monomodal distribution with a maximum near 2 nm and no pores are larger than 6 nm. Nonpeptized gels have a bimodal distribution with a narrow peak near to 2 nm and a broad unsymmetrical peak with a maximum at 4 nm. Heating in air above 400 degrees C has a strong effect on the porosity. As the temperature increases, there is a broadening of the distribution and a marked decrease of small pores (below 3 nm). However, even after treatment at 800 degrees C, micropores are still present. 相似文献
7.
Christel Laberty Jerzy Pielaszek Pierre Alphonse Abel Rousset 《Solid State Ionics》1998,110(3-4):293-302
Cation deficient spinels NixMn3−x□3δ/4O4+δ (0≤x≤1) have been prepared by thermal decomposition of mixed oxalates Nix/3Mn(3−x)/3(C2O4)·nH2O in air at 623 K. They have been characterised by temperature programmed reduction (TPR) under H2, the reaction being followed by gravimetric and powder X-ray diffraction measurements. It has been shown that TPR proceeds in several steps. The first steps correspond to the loss of nonstoichiometric oxygen leading to the formation of a stoichiometric oxide. During the following stages the manganese cations are reduced, causing the spinel structure to be destroyed, and the formation of solid solution of NiO in a cubic MnO. Subsequently, Ni2+ cations undergo a reduction to metallic nickel, and, finally, a mixture of nonstoichiometric MnO1−δ and metallic nickel is formed. These oxides contain a high level of vacancies which vary with the nickel content with a maximum of δ≈1 near x=0.6. This nonstoichiometry is ascribed both to the presence of Ni3+ and excess of Mn4+. 相似文献
8.
The eigenfunctions of the one dimensional Schrödinger equation Ψ″ + [E ? V(x)]Ψ=0, where V(x) is a polynomial, are represented by expansions of the form . The functions ?k (ω, x) are chosen in such a way that recurrence relations hold for the coefficients ck: examples treated are Dk(ωx) (Weber-Hermite functions), exp (?ωx2)xk, exp (?cxq)Dk(ωx). From these recurrence relations, one considers an infinite bandmatrix whose finite square sections permit to solve approximately the original eigenproblem. It is then shown how a good choice of the parameter ω may reduce dramatically the complexity of the computations, by a theoretical study of the relation holding between the error on an eigenvalue, the order of the matrix, and the value of ω. The paper contains tables with 10 significant figures of the 30 first eigenvalues corresponding to V(x) = x2m, m = 2(1)7, and the 6 first eigenvalues corresponding to V(x) = x2 + λx10 and x2 + λx12, λ = .01(.01).1(.1)1(1)10(10)100. 相似文献
9.
Fluorimetric Determination of Histamine in Fish Using Micellar Media and Fluorescamine as Labelling Reagent 总被引:1,自引:0,他引:1
Adamou R Coly A Douabalé SE Saleck ML Gaye-Seye MD Tine A 《Journal of fluorescence》2005,15(5):679-688
An analytical method based on the use of fluorescamine to produce a fluorescent derivative with histamine and combined with
micellar-enhanced fluorescence detection of the formed complex is developed for the sensitive and rapid determination of histamine
in fishes. The fluorescence properties of the obtained complex in water and micellar solutions of sodium dodecyl sulfate (SDS),
cetyltrimethylammonium chloride (CTAC) and brij-700 are reported. Physicochemical variables influencing the sensitivity of
the method (pH, micellar, fluorescamine and NaCl relative concentrations) have been optimized. The stability of the formed
complex, as shown by kinetic study, depends on the pH of the solution. Linear calibration curves allowing an effective histamine
determination were established with large linear dynamic range (LDR), and low limits of detection (LOD) between 0.5 and 33
ng mL−1, according to the solvent. Application to the analysis of fish samples (sardines) yielded satisfactory results. The method
seems to be suitable for environmental fish quality control.
Presented in part, at the 39th IUPAC Congress and the 86th Conference of the Canadian Society for Chemistry, August, 10–15,
2003, Ottawa (Canada). 相似文献
10.
A. Michael Alphonse 《Journal of Fourier Analysis and Applications》2000,6(4):449-456
In this paper we prove that the maximal commutator of singular integral operator [b, T]* satisfies the inequality:
where f is any smooth function with compact support, λ>0 and C is a positive constant independent of f and λ. 相似文献