Determination of 12 additives in beverages by evaporation-assisted dispersive liquid-liquid microextraction based on the solidification of floating organic droplets combined with liquid chromatographyEI北大核心CSCD

An analytical method for the simultaneous determination of 12 additives in beverages was developed using evaporation-assisted dispersive liquid-liquid microextraction based on the solidification of floating organic droplets EVA-DLLME-SFOcombined with high performance liquid chromatography HPLC. The samples were extracted twice with 70%V/Vmethanol aqueous solution and extracted by EVA-DLLME-SFO method after the combination of the extractsand finally determined by HPLC. Extraction parameterssuch as types and amounts of extractantevaporant and heating agentthe concentration of saltand the extraction time were optimized. Under the optimized conditionsthere were good relationships in the ange of 0.25-50 μµg/mL with the limits of detection of 1.5 to 13.6 mg/kg and limits of quantification of 5.2 to 45.3 mg/kg. The recoveries at three spiked levels1025 and 50 mg/kgwere 76.8% to 101.2% with the relative standard deviations of 0.11% to 4.7%. The method can be used for rapid detection of 12 additives in beverages. © 2022, Youke Publishing Co.,Ltd. All rights reserved.     

Mn-Ce-M复合改性无硅残渣炭催化剂的NH3选择性还原NO性能研究

生物质作为极具潜力的可再生能源,其热解制油技术备受关注,副产物残渣炭的高值化利用是当下重要的研究内容之一。脱硅处理不仅可实现硅的资源化利用,同时可以实现炭材料的结构改性。本文开展了残渣炭煮溶脱硅研究,并基于最佳脱硅方式,探究不同金属M（M：Ho、Sb、La、Nd）对无硅残渣炭（FRB）催化剂的脱硝性能的影响规律。结果表明：煅烧预处理结合煮溶脱硅可以脱除99%以上的SiO2,脱硅的同时理化性质显著改善,表现出较大的比表面积（1923 m2/g）、丰富的介/微孔结构以及表面含氧官能团,并促进了催化剂的SCR反应活性（250℃时NOx脱除率可达100%）。此外,Ho改性无硅残渣炭脱硝催化剂具有最好的低温脱硝活性,在200~300℃范围内保持80%以上的脱硝效率。表征结果显示,MnCeHo/FRB催化剂具有较强的表面酸性和氧化还原性,活性组分在载体上均匀分散,且表面化学吸附氧较为丰富。此外,In-situ DRIFTs实验表明MnCe/FRB催化剂表面同时存在E-R和L-H机理,但E-R机理占主要地位。     

氧化石墨烯/麦饭石分离富集-火焰原子吸收法测定水中镉

通过浸渍法制备了新型纳米氧化石墨烯/麦饭石(GO/MFS)复合吸附材料,并用于镉的分离富集。以火焰原子吸收法为检测手段,研究了GO/MFS复合吸附材料对水中Cd(Ⅱ)的吸附性能。结果表明:当pH为9.0时,GO/MFS复合吸附材料用量为20mg,振荡10min,Cd(Ⅱ)可被吸附材料定量富集,最大吸附容量为111.1mg/g。吸附等温线均能符合Langmuir和Freundlich等温线模型,说明该吸附体系是一个单层覆盖与多层吸附相结合的模式。被吸附的Cd(Ⅱ)可用0.15mol/L HNO3定量洗脱。方法测定Cd(Ⅱ)的线性范围为0.04～2.0mg/L,检出限为9.6μg/L;对40μg/LCd(Ⅱ)测定的相对标准偏差(RSD)为2.5%(n=9)。该方法具有操作简单、分析时间短、线性范围宽等优点。用该法对自来水中Cd(Ⅱ)进行加标测定,回收率101%～103%。     

Nonlinear dynamical stability of gap solitons in Bose-Einstein condensate loaded in a deformed honeycomb optical lattice

We investigate the existence and dynamical stability of multipole gap solitons in Bose-Einstein condensate loaded in a deformed honeycomb optical lattice. Honeycomb lattices possess a unique band structure, the first and second bands intersect at a set of so-called Dirac points. Deformation can result in the merging and disappearance of the Dirac points, and support the gap solitons. We find that the two-dimensional honeycomb optical lattices admit multipole gap solitons. These multipoles can have their bright solitary structures being in-phase or out-of-phase. We also investigate the linear stabilities and nonlinear stabilities of these gap solitons. These results have applications of the localized structures in nonlinear optics, and may helpful for exploiting topological properties of a deformed lattice.     

理论力学"四堂融合"混合式教学和考核模式改革的实践

探讨了一种在新兴教育技术下传统课堂、在线课堂、雨课堂和翻转课堂"四堂融合"的混合式理论力学教学方法,并进行基于此模式的考核模式改革,显著提高了学生的学习成绩,提高了课堂教学成效,取得了良好的教学效果。这种教学和考核模式改革给当代理论力学课堂教学改革提供了一种思路。     

Item2vec与改进DDPG相融合的推荐算法

传统的推荐算法能够有效解决信息过载问题,但在冷启动和数据稀疏的情况下,传统方法仍有其局限性。针对以上问题本文提出一种基于深度强化学习理论的推荐算法,该算法使用深度确定性策略梯度(DDPG,deep deterministic policy gradient,DDPG)算法来解决推荐问题,使用Item2vec将离散的动作空间转换为连续的表示,同时提出了一种余弦距离和欧氏距离相结合的奖励函数,能够保障神经网络不会过早的收敛于局部最优。应用该算法进行电影的推荐,实验结果表明本文提出的算法能够产生较好的推荐并能缓解冷启动所带来的影响。     

基于灰色聚类分析的风险评价方法研究——以江苏民间资本进入金融领域风险评价为例

运用灰色系统理论,结合AHP方法,建立灰色聚类分析模型,对风险进行评价,并以江苏民间资本进入金融领域风险评价为例进行研究.结果表明,民间资本进入金融领域的风险属于高风险范畴,其中进入风险中的产业风险和社会风险属于高风险,信用风险属于较高风险,政治风险属于中等风险.并针对上述风险的等级,提出了相应的政策建议.模型具有一定的实用价值,它对于正确认识民间资本进入金融领域的风险和有针对性地制定相应的政策措施具有一定的理论和现实意义.     

High accuracy amplitude and phase measurements based on a double heterodyne architecture

In the digital low level RF (LLRF) system of a circular (particle) accelerator, the RF field signal is usually down converted to a fixed intermediate frequency (IF). The ratio of IF and sampling frequency determines the processing required, and differs in various LLRF systems. It is generally desirable to design a universally compatible architecture for different IFs with no change to the sampling frequency and algorithm. A new RF detection method based on a double heterodyne architecture for wide IF range has been developed, which achieves the high accuracy requirement of modern LLRF. In this paper, the relation of IF and phase error is systematically analyzed for the first time and verified by experiments. The effects of temperature drift for 16 h IF detection are inhibited by the amplitude and phase calibrations.     

钴-席夫碱-壳聚糖/凹凸棒土对苯乙烯环氧化的催化性能

以NaOH固化法制备的壳聚糖/凹凸棒土(CS/ATP)复合树脂为载体,以水杨醛和天冬氨酸合成的席夫碱为配体,分别合成Co、Mn、Cu、Fe和Ni的席夫碱金属配合物及其负载型席夫碱金属配合物,并通过FT-IR对其进行结构表征,且以苯乙烯为底物,分子氧为氧源,分别考察了各种催化剂对苯乙烯的环氧化性能。实验结果表明,在小分子席夫碱金属配体中,Co-Schiff碱催化性能较好。将Co-Schiff碱负载到CS/ATP复合树脂中,综合考察了Co-Schiff碱-CS/ATP的用量、温度、时间对苯乙烯催化环氧化性能的影响,结果表明,反应温度为80℃,反应时间为8 h,苯乙烯的转化率达93.1%。