爆炸荷载作用下钢筋混凝土梁的动力响应及破坏形态分析

对基于Timoshenko梁理论建立的非线性动力有限元法作了改进。根据压区理论得到混凝土的平均剪应力和平均剪应变关系,建立了能反映箍筋的抗剪作用的材料模型;此外,对结构在爆炸荷载作用下可能出现的各种响应现象进行了描述,以准确地预测梁破坏时不同位置截面上钢筋和混凝土的受力、变形及破坏情况。应用改进的材料模型,对爆炸荷载作用下的五个钢筋混凝土试验梁的动力响应和破坏形态进行了数值模拟,结果表明,该数值方法能较好地模拟钢筋混凝土梁的弯曲、弯剪和剪切等破坏形态。     

Sur les Transformations Simultanées de Deux Équations Différentielles Linéaires du Deuxième Ordre dans Elles-mêmes

AMS (MOS) Classification 34C20     

A real analytic constructive proof of the lojasiewicz theorem

In this paper we eliminate the complex analytic part from original Lojasiewicz's proof and show a constructive method of producing a saucissonnage for a set of polynomials.     

Hydrophobic hydration at the level of primitive models

Structural changes which take place in bulk water when a molecule of an apolar solute is brought therein are studied at a very basic elementary level. Water is modelled by two different types of extended primitive models and the solute is a hard sphere. The model mixture, which does not incorporate any water—solute interaction but the hard-core repulsion and is free of any adjustable parameter, is shown to predict the site—site correlation functions and details of the orientational arrangement of water molecules in the first hydration shell in full agreement with results obtained using complex realistic potentials.     

X-RAY CRYSTALLOGRAPHIC AND 35CL N.Q.R. SPECTROSCOPIC STUDIES ON CHLOROCYCLOPHOSPHAZENES

Abstract

X-ray crystallographic structure determinations on a number of chlorocyclophosphazenes are compared with ³⁵Cl N.Q.R. spectroscopic studies of these compounds. Phase changes have been observed.     

THE REACTIONS OF N3P3CL6 AND RELATED COMPOUNDS WITH DIFUNCTIONAL REAGENTS. COMPARISONS AND CONTRASTS

Abstract

The reactions of N₃P₃Cl₆ with a variety of difunctional reagents are discussed. NMR spectroscopic and X-ray crystallographic investigations are presented.     

Tuneable Sagnac comb filter including two wave retarders

In this paper we study theoretically and experimentally a wavelength-tuneable Sagnac birefringence filter. The device is a Sagnac interferometer including a symmetric fibre coupler and a length of high-birefringence fibre in the loop. A wave retarder is inserted at each end of the birefringent fibre for absolute wavelength tuning. We show theoretically that wavelength tuning through wave plate orientation ensuring constant amplitude of the filtering function is possible only if a minimum of two wave retarders are included in the setup. The position of the transmission peaks then varies linearly with the angle of one of the retarders and can be adjusted over one entire channel spacing. This happens only when a quarter-wave retarder and a half-wave retarder are used, if the former is oriented at 45° with respect to the fibre birefringence axes, while the orientation of the latter serves as the adjustment parameter. The theoretical predictions are confirmed by the experimental results.     

The combination of living radical polymerization and click chemistry for the synthesis of advanced macromolecular architectures

Since its introduction, click chemistry has received a considerable amount of interest. In this contribution, the term click chemistry and the reactions that fall under this term are briefly explained. The main focus of this review is on the application of click chemistry in conjunction with living radical polymerization for the synthesis of advanced macromolecular architectures. Therefore the most powerful living radical polymerization (LRP) techniques are discussed and an overview of click chemistry in the different synthetic schemes is given. A large number of examples are shown that include the synthesis of block copolymers, star-shaped polymers, surface modified particles, and polymer-protein conjugates. The enormous potential of LRP/click chemistry is probably best exemplified by the synthesis of different miktoarm star copolymers, to which a separate section is dedicated.