Manufacturing of Volumetric Glass–Based Composites with Single‐ and Double‐QD Doping

Quantum dot (QD)‐based light‐emitting materials are gaining increased attention because of their easily tunable optical properties desired for various applications in biology, optoelectronics, and photonics. However, few methods can be used to manufacture volumetric materials doped with more than one type of QD other than QD‐polymer hybrids, and they often require complicated preparation processes and are prone to luminescence quenching by QD aggregation and separation from the matrix. Here, simultaneous doping of a volumetric glass‐based nanocomposite with two types of QDs is demonstrated for the first time in a single‐step process using the nanoparticle direct doping method. Glass rods doped with CdTe, CdSe/ZnS, or co‐doped with both QDs, are obtained. Photoluminescence and lifetime experiments confirm temperature‐dependent double emission with maxima at 596 and 720 nm with mean lifetimes up to 16 ns, as well as radiative energy transfer from the short wavelength–emitting QDs to the long wavelength–emitting QDs. This approach may enable the simple and cost‐efficient manufacturing of bulk materials that produce multicolor luminescence with cascade excitation pumping. Applications that could benefit from this include broadband optical fiber amplifiers, backlight systems in LCD screens, high‐power LEDs, or down‐converting solar concentrators used to increase the efficiency of solar panels.     

基于波长调制-直接吸收光谱方法的CO分子1567 nm处谱线参数高精度标定

直接吸收光谱(DAS)可直接测量分子吸收率函数,并通过拟合吸收率函数确定待测气体参数.波长调制-直接吸收光谱(WM-DAS)在DAS基础上,结合了波长调制光谱(WMS)中谐波分析思想,利用傅里叶变换复现吸收率函数,可有效提高吸收率函数的测量精度.本文利用WM-DAS方法结合长光程气体吸收池,在室温低压条件下,对CO分子1567 nm处R5-R11近红外弱吸收谱线吸收率函数进行了精确复现,其拟合残差标准差低至3×10^-5,随后根据测得的吸收率函数对谱线的碰撞展宽、Dicke收敛以及速度依赖的碰撞展宽系数等光谱参数进行了高精度标定,并将其与高灵敏度的连续波腔衰荡光谱(CW-CRDS)测量结果进行了比较,实验结果表明该方法与CW-CRDS测量结果具有高度一致性,更具有系统简单、测量速度快、对环境要求低等优点.     

半波长超导共面波导谐振腔传输及温度特性研究

超导共面波导谐振腔主要包括四分之一波长型和半波长型.本文对半波长超导共面波导谐振腔使用并联RLC电路进行等效分析,使用sonnet软件进行仿真其传输特性,通过电子束蒸发和激光直写等工艺制备出样品,在低温超导状态下使用矢量网络分析仪对其传输特性进行测量,以及通过持续降温方式研究其传输特性受温度的影响.实验表明:测得的谐振频率和外部品质因数与设计值吻合;谐振频率受动态电感的影响随温度降低而升高;外部品质因数随温度降低而保持基本不变;内部品质因先受导体损耗的影响随温度降低而急剧升高,当温度降低至一定温度后内部品质因数受介电损耗的影响随温度降低而保持基本不变;总品质因数在温度较高时主要来自于导体损耗,在温度较低时主要来自于介电损耗和外部品质因数,随温度的变化趋势和内部品质因数一致.     

200 km沙漠链路高精度光纤时频传递关键技术研究

针对沙漠环境实地链路存在的温度变化大、室外风力、地表振动等多种复杂噪声来源,通过对系统反馈补偿带宽、反馈补偿强度、光功率等时频传递系统关键参数的优化配置,研究了不同反馈补偿参数下复杂链路噪声的有效抑制技术.全链路的频率传递稳定度8×10~(-14)@1s,1×10~(-16)@1000 s,千秒尺度下时间信号传递的时间方差仅为1.2 ps.实现了氢钟信号在200 km量级沙漠环境实地链路的无损传输.该验证实验在基于短基线干涉测量的卫星测轨系统中发挥了重要作用.     

级联光栅结合Sagnac环的可调谐光纤激光器

提出并验证了一种单-双波长可调谐掺铒光纤激光器。利用级联光纤布拉格光栅(Cascaded Fiber Bragg gratings,Cascaded FBGs)结合Sagnac环结构所产生的复合滤波效应,实现较高精细度滤波,并通过调节环内偏振控制器(Polarization Controller,PC),引入双折射效应,得到波长可调谐的光纤激光器。基于耦合模理论并使用传输矩阵法对该结构的传输特性进行了分析,在此基础上搭建实验系统,验证了理论分析的正确性。实验结果表明:通过调节PC,激光器输出激光的波长范围约为1 555.644～1 556.112 nm,双波长间隔的可调范围约为0.108～0.452 nm,单-双波长的边模抑制比(SMSR)均高于40 dB;在稳定性测试中,输出单-双波长激光的波长最大漂移量小于0.008 nm。该方法具有结构简单、调谐方便、易于实现且精细度较高的优点,可应用于密集波分复用及全光通信系统等领域。     

Wavelength selection framework for classifying food and pharmaceutical samples into multiple classes

Near infrared (NIR) spectroscopy is an efficient, low‐cost analytical technique widely applied to identify the origin of food and pharmaceutical products. NIR spectra‐based classification strategies typically use thousands of equally spaced wavelengths as input information, some of which may not carry relevant information for product classification. When that is the case, the performance of predictive and exploratory multivariate techniques may be undermined by such noisy information. In this paper, we propose an iterative framework for selecting subsets of NIR wavelengths aimed at classifying samples into categories. For that matter, we integrate Principal Components Analysis (PCA) and three classification techniques: k‐Nearest Neighbor (KNN), Probabilistic Neural Network (PNN) and Linear Discriminant Analysis (LDA). PCA is first applied to NIR data, and a wavelength importance index is derived based on the PCA loadings. Samples are then categorized using the wavelength with the highest index and the classification accuracy is calculated; next, the wavelength with the second highest index is inserted into the dataset and a new classification is performed. This forward‐based iterative procedure is carried out until all original wavelengths are inserted into the dataset used for classification. The subset of wavelengths leading to the maximum accuracy is chosen as the recommended subset. Our propositions performed remarkably well when applied to four datasets related to food and pharmaceutical products. Copyright © 2016 John Wiley & Sons, Ltd.     

基于长波长光激发的光敏剂和载体在肿瘤光动力治疗中的应用

光动力疗法是近年来兴起的一种新型的微创性治疗肿瘤的方法,目前已经成功地应用于临床上多种恶性肿瘤治疗中,并取得了良好的效果。然而,由于生物组织对可见光的吸收和散射,使得光线无法穿透组织到达身体内的目标区域,所以该疗法更适用于浅表肿瘤的治疗。长波长光尤其是近红外光具有良好的组织穿透深度,其在治疗组织深处的肿瘤方面具有显著的优势。基于长波长光激发的光敏剂及载体在实体肿瘤的治疗领域已经取得了丰硕的研究成果。本文将从光敏剂的研发、双光子激光的使用、上转换纳米粒子的引入等方面简要概述近十年来用于光动力治疗中的组装体系,以及长波长激发光在光动力治疗方面的发展趋势。     

基于改进免疫遗传算法的近红外光谱变量选择方法

该文在免疫遗传算法（IGA）的基础上,提出一种改进免疫遗传算法（iIGA）用于近红外光谱波长变量的选择。该算法舍去了原算法中固定抗体相似度阈值的思想,取而代之的是抗体相似度阈值自适应,同时引入精英保留策略和贪心算法思想,使得算法朝着正确的方向进行局部性探优。将该算法在玉米的淀粉和蛋白质含量数据集上进行实验测试,建立偏最小二乘（PLS）分析模型,并与IGA、遗传算法（GA）以及全谱方法进行了对比。结果表明,在玉米淀粉含量的预测上,iIGA相较于原IGA算法,预测集均方根误差（RMSEP）从0.312 0降至0.298 0,预测集预测精度提升4.5%;在玉米蛋白质含量的预测上,RMSEP从0.124 4降至0.110 3,预测集预测精度提升11.3%。分别对预测淀粉和蛋白质模型的RMSEP值进行显著性检验,F值分别为165.22和182.05,P值分别为9.5 × 10－23和4.5 × 10－24,P值均小于0.05,因此,iIGA能显著提升模型预测精度。     

相关分析与谱分析在表面形貌研究中的应用

本文通过对表面形貌进行相关分析与谱分析,提出了相对波度和有效波度、相对波长和有效波长的概念,并且指出相关分析与谱分析是研究表面形貌润滑效应的有力工具。作者认为,当相对波度为有效波度时,应当同时考虑波长和幅值的摩擦学效应;当相对波度为高频的粗糙度时,只需考虑表面形貌的幅值效应。     

A Complete Solution to Spectrum Problem for Five‐Vertex Graphs with Application to Traffic Grooming in Optical Networks

A G‐design of order n is a decomposition of the complete graph on n vertices into edge‐disjoint subgraphs isomorphic to G. Grooming uniform all‐to‐all traffic in optical ring networks with grooming ratio C requires the determination of graph decompositions of the complete graph on n vertices into subgraphs each having at most C edges. The drop cost of such a grooming is the total number of vertices of nonzero degree in these subgraphs, and the grooming is optimal when the drop cost is minimum. The existence spectrum problem of G‐designs for five‐vertex graphs is a long standing problem posed by Bermond, Huang, Rosa and Sotteau in 1980, which is closely related to traffic groomings in optical networks. Although considerable progress has been made over the past 30 years, the existence problems for such G‐designs and their related traffic groomings in optical networks are far from complete. In this paper, we first give a complete solution to this spectrum problem for five‐vertex graphs by eliminating all the undetermined possible exceptions. Then, we determine almost completely the minimum drop cost of 8‐groomings for all orders n by reducing the 37 possible exceptions to 8. Finally, we show the minimum possible drop cost of 9‐groomings for all orders n is realizable with 14 exceptions and 12 possible exceptions.