全文获取类型
收费全文 | 8126篇 |
免费 | 835篇 |
国内免费 | 905篇 |
专业分类
化学 | 2672篇 |
晶体学 | 72篇 |
力学 | 1258篇 |
综合类 | 166篇 |
数学 | 3487篇 |
物理学 | 2211篇 |
出版年
2024年 | 9篇 |
2023年 | 123篇 |
2022年 | 186篇 |
2021年 | 266篇 |
2020年 | 302篇 |
2019年 | 239篇 |
2018年 | 269篇 |
2017年 | 289篇 |
2016年 | 321篇 |
2015年 | 283篇 |
2014年 | 370篇 |
2013年 | 689篇 |
2012年 | 385篇 |
2011年 | 536篇 |
2010年 | 403篇 |
2009年 | 500篇 |
2008年 | 535篇 |
2007年 | 516篇 |
2006年 | 479篇 |
2005年 | 424篇 |
2004年 | 366篇 |
2003年 | 347篇 |
2002年 | 344篇 |
2001年 | 225篇 |
2000年 | 230篇 |
1999年 | 192篇 |
1998年 | 174篇 |
1997年 | 124篇 |
1996年 | 115篇 |
1995年 | 89篇 |
1994年 | 106篇 |
1993年 | 64篇 |
1992年 | 61篇 |
1991年 | 51篇 |
1990年 | 39篇 |
1989年 | 26篇 |
1988年 | 25篇 |
1987年 | 21篇 |
1986年 | 19篇 |
1985年 | 22篇 |
1984年 | 25篇 |
1983年 | 7篇 |
1982年 | 15篇 |
1981年 | 10篇 |
1980年 | 10篇 |
1979年 | 12篇 |
1978年 | 11篇 |
1977年 | 7篇 |
1971年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有9866条查询结果,搜索用时 15 毫秒
1.
We propose to reduce the (spectral) condition number of a given linear system by adding a suitable diagonal matrix to the system matrix, in particular by shifting its spectrum. Iterative procedures are then adopted to recover the solution of the original system. The case of real symmetric positive definite matrices is considered in particular, and several numerical examples are given. This approach has some close relations with Riley's method and with Tikhonov regularization. Moreover, we identify approximately the aforementioned procedure with a true action of preconditioning. 相似文献
2.
In this article a coupled version of the improved divergence‐free‐condition compensated method will be proposed to simulate time‐varying geometries by direct forcing immersed boundary method. The proposed method can be seen as a quasi‐multi‐moment framework due to the fact that the momentum equations are discretized by both cell‐centered and cell‐face velocity. For simulating time‐varying geometries, a semi‐implicit iterative method is proposed for calculating the direct forcing terms. Treatments for suppressing spurious force oscillations, calculating drag/lift forces, and evaluating velocity and pressure for freshly cells will also be addressed. In order to show the applicability and accuracy, analytical as well as benchmark problems will be investigated by the present framework and compared with other numerical and experimental results. 相似文献
3.
Photo-catalytic elimination of organic contaminants plays a significant role in wastewater treatment. Developing a highly efficient photo-catalyst is one of the leading research topic. Herein, we reported the fabrication of a novel nanoporous NiO@SiO2 photo-catalyst by a simple ion-exchange method to eliminate the reactive dyes. The synthesized NiO@SiO2 catalyst exhibited fast photo-degradation and excellent adsorption capability and could efficiently remove Red FN-3GL dye from wastewater, due to a high loading of NiO and a large specific surface area, abundant electron-withdrawing groups, as well as narrow bandgap energy. In addition, the NiO@SiO2 photo-catalyst also displayed a high capability to remove reactive dyes over a wide range of pH values (pH 3–9). The prominent adsorption and photo-degradation of dyes were strongly dependent on the surface charge of the catalyst and the generation of hydroxyl radicals (OH?) by the catalyst, respectively. Furthermore, the NiO@SiO2 photo-catalyst also exhibited excellent recyclability, thus demonstrating the feasibility of practical applications in industries. The strategy of covering the metal oxide to nanoporous silica is a promising method for developing active photo-catalysts and applying them in the wastewater treatments. 相似文献
4.
5.
The formation of a line of equally spaced particles at the centerline of a microchannel, referred as “particle ordering,” is desired in several microfluidic applications. Recent experiments and simulations highlighted the capability of viscoelastic fluids to form a row of particles characterized by a preferential spacing. When dealing with non-Newtonian fluids in microfluidics, the adherence condition of the liquid at the channel wall may be violated and the liquid can slip over the surface, possibly affecting the ordering efficiency. In this work, we investigate the effect of wall slip on the ordering of particles suspended in a viscoelastic liquid by numerical simulations. The dynamics of a triplet of particles in an infinite cylindrical channel is first addressed by solving the fluid and particle governing equations. The relative velocities computed for the three-particle system are used to predict the dynamics of a train of particles flowing in a long microchannel. The distributions of the interparticle spacing evaluated at different slip coefficients, linear particle concentrations, and distances from the channel inlet show that wall slip slows down the self-assembly mechanism. For strong slipping surfaces, no significant change of the initial microstructure is observed at low particle concentrations, whereas strings of particles in contact form at higher concentrations. The detrimental effect of wall slip on viscoelastic ordering suggests care when designing microdevices, especially in case of hydrophobic surfaces that may enhance the slipping phenomenon. 相似文献
6.
Dr. Sirinapa Wongwilawan Dr. Doyun Kim Dr. Thien S. Nguyen Wonki Lim Prof. Dr. Sheng Li Prof. Dr. Cafer T. Yavuz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(72):e202202340
Through accumulation, mercury contamination in aquatic systems still poses serious health risks despite the strict regulations on drinking water and industrial discharge. One effective strategy against this is adsorptive removal, in which a suitably functionalized porous material is added to water treatment protocols. Thiol (SH) group-grafted structures perform commendably; however, insufficient attention is paid to the cost, scalability, and reusability or how the arrangement of sulfur atoms could affect the HgII binding strength. We used an inexpensive and scalable porous covalent organic polymer (COP-130) to systematically introduce thiol functional groups with precise chain lengths and sulfur content. Thiol-functionalized COP-130 demonstrates enhanced wettability and excellent HgII uptake of up to 936 mg g−1, with fast kinetics and exceptionally high selectivity. These Hg adsorbents are easily regenerated with HCl and can be used at least six times without loss of capacity even after treatment with strong acid, a rare performance in the domain of Hg-removal research. 相似文献
7.
在G?del t-模下,研究了模糊选择函数的半序合理性.首先给出了模糊选择函数的合理性条件FA1.然后研究了该条件与模糊选择函数半序合理性之间的关系,得到了半序合理的一个充分条件. 相似文献
8.
Guangtao Duan Takuya Matsunaga Akifumi Yamaji Seiichi Koshizuka Mikio Sakai 《国际流体数值方法杂志》2021,93(1):148-175
Corrective matrix that is derived to restore consistency of discretization schemes can significantly enhance accuracy for the inside particles in the Moving Particle Semi‐implicit method. In this situation, the error due to free surface and wall boundaries becomes dominant. Based on the recent study on Neumann boundary condition (Matsunaga et al, CMAME, 2020), the corrective matrix schemes in MPS are generalized to straightforwardly and accurately impose Neumann boundary condition. However, the new schemes can still easily trigger instability at free surface because of the biased error caused by the incomplete/biased neighbor support. Therefore, the existing stable schemes based on virtual particles and conservative gradient models are applied to free surface and nearby particles to produce a stable transitional layer at free surface. The new corrective matrix schemes are only applied to the particles under the stable transitional layer for improving the wall boundary conditions. Three numerical examples of free surface flows demonstrate that the proposed method can help to reduce the pressure/velocity fluctuations and hence enhance accuracy further. 相似文献
9.
The health monitoring has been studied to ensure integrity of design of engine structure by detection, quantification, and prediction of damages. Early detection of faults may allow the downtime of maintenance to be rescheduled, thus preventing sudden shutdown of machines. In cylinder pressure developed, vibrations and noise emissions data provide a rich source of information about condition of engines. Monitoring of vibrations and noise emissions are novel non-intrusive methodologies for which positioning of various transducers are important issue. The presented work shows applicability of these diagnosis methodologies adopted in case of diesel engines. The effects of changing various fuel injection parameters was analyzed. Scope of using non-intrusive technique has been analyzed by changing locations of microphone. Novelty of this worklies in exploring signal processing methods for various locations around the engine test set up. Various frequency ranges of contributing noise and vibration sources were identified. Time-Frequency analysis showed the onset of various cyclic. Based on the identification of various frequency bands, it is possible to device suitable filters in order to extract more information. 相似文献
10.
随着经济的飞速发展,社会对能源的需求日益扩大,对工业废水的无害化处理也提出了更高的要求。光催化燃料电池 (photocatalytic fuel cell, PFC) 在燃料电池中引入半导体光催化材料作为电极,实现了有机污染物高效降解和同步对外产电的双重功能,在废水无害化与资源化利用方面具有潜在的应用价值。半导体光催化电极是PFC系统高效运行的核心组件,增强其可见光响应和光生载流子分离是提高PFC性能的关键策略。反应器结构设计和运行参数优化也有利于改善PFC性能。本文从PFC基本原理和应用入手,综述了PFC在环境污染物资源化处理中的研究进展,并详细阐述了提高PFC的污染控制性能和产电效率的优化手段,为进一步设计高效稳定的PFC系统并实现其在水污染控制和清洁能源生产中的应用提供理论指导。 相似文献