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1.
In this present work iodobenzenediacetate (PIDA) has been found to be the key reagent in absence or presence of catalytic amount of molecular iodine (I2)/zinc chloride (ZnCl2) to construct quinazoline scaffold from 2-aminobenzylamine and a variety of easily available aldehydes, aryl and aliphatic amines, aliphatic and aryl alcohols and nitriles. This protocol provides mild and robust conditions along with great versatility to synthesize 2-substituted quinazolines from diverse starting materials in good to excellent yields. The developed protocol is also well applicable to reactants containing ease to oxidation prone functional groups. 相似文献
2.
Friction plays a key role in the efficiency and stability of the slip-controlled torque converter clutches. The effects of
friction on the dynamics and stability of a slip-controlled torque converter clutch system using a bifurcation-analysis-based
approach is presented in this paper. A three degree-of-freedom nonlinear driveline model with integral feedback action to
control the clutch slip speed has been utilized for this study. The clutch interface friction is dependent on the slip speed
and is a function of the static friction constant, μ
0, the low velocity friction constant μ
1, and the low velocity exponential rate, γ. Using one-parameter numerical continuation, local Hopf bifurcations of the subcritical type are observed as the friction
parameters μ
1 and γ were varied at low slip speeds. The continuation results are verified using simulations of the full nonlinear model. Stick-slip
and undesirable oscillations of the model inertia elements are observed for certain parameter values. As the slip speed is
increased, the bifurcation instability occurs at an increasingly higher value of μ
1 signifying an improved tolerance of negative friction gradient at higher slip speeds. Smaller exponential rates γ are tolerated at higher slip speeds before the bifurcation instability occurs. For the range of parameter values considered,
no bifurcations occur for a slip speeds higher than 3.4 and 4.5 rad/s with μ
1 and γ as the continuation parameters, respectively. These values of slip speeds are much lower than the system’s first mode of
torsional vibration of 16 Hz (≈100 rad/s). 相似文献
3.
V. I. Gulyaev P. Z. Lugovoi M. A. Belova I. L. Solov’ev 《International Applied Mechanics》2006,42(6):692-698
The quasistatic stability of a rotating drillstring under longitudinal force and torque is analyzed. Constitutive equations
are derived, and a technique to solve them is proposed. It is shown that the buckling mode of the drillstring is helical within
a section subjected to compressive forces
__________
Translated from Prikladnaya Mekhanika, Vol. 42, No. 6, pp. 101–109, June 2006. 相似文献
4.
5.
摆式积分陀螺加速度计的外环干扰力矩包括仪表外环轴的摩擦力矩和交叉轴加速度引起的交变力矩。作者分析了引起摆式积分陀螺加速度计外环干扰力矩的主要原因,提出一种在高精度三轴测试转台上分离摆式积分陀螺加速度计外环干扰力,测试摆式积分陀螺加速度计精度的试验方法。该试验采用三轴转台中环转动速度随动摆式积分陀螺加速度计外环进动角速度,同时摆式积分陀螺加速度计陀螺摆的输出轴在整个试验中保持水平,从而分离仪表外环干扰力的方案。通过对试验数据进行分析,得出外环干扰力的存在影响了摆式积分陀螺加速度计测试精度,为改善摆式陀螺加速度计工艺以提高摆式陀螺加速度计的测试精度提供了依据。 相似文献
6.
静压气体球轴承支承球形转子的干扰力矩分析 总被引:4,自引:0,他引:4
中心小孔供气单向受载球面气体轴承可以用于球形转子的静平衡测量。对作用于转子上的干扰力矩进行估算是平衡装置设计的重要部分。本在一定假设条件下推导了由粘性剪切应力和气膜支撑力引起的作用于转子上的干扰力矩。干扰力矩以轴承包角、中心气室张角、气膜压力、转子转速、转子旋转轴位置、失中度、转子非球表示。以干扰力矩最小为准则分析了这些参数的影响,结论有助于静平衡装置的优化设计以及对精度的进一步分析。 相似文献
7.
In the present work, a further numerical simulation of the starting flow around a flat plate normal to the direction of motion
in a uniform fluid has been made by means of the discrete vortex method. The secondary separation occurring at rear surface
of the plate is explored, and predicted approximately using Thwait's method. The calculated results show that in the early
stages of the flow secondary separation does occur. The evolution of flow field, the vortex growing process and the characteristics
of secondary vortices have been described. The time dependent drag coefficients, the vorticity shed from the edges and rear
surface, and the separation positions are calculated as well as the distributions of velocity and pressure on the plate. In
the case of flow normal to the plate, the calculated secondary vortices are weak. Their existence will change the local velocity
distributions and affect pressure distributions. However, the effect on drag coefficient is negligible. 相似文献
8.
Eva Lucaccini Matteo Briganti Dr. Mauro Perfetti Dr. Laure Vendier Dr. Jean‐Pierre Costes Dr. Federico Totti Prof. Dr. Roberta Sessoli Prof. Dr. Lorenzo Sorace 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(16):5552-5562
The magnetic behaviour of a Dy(LH)3 complex (LH? is the anion of 2‐hydroxy‐N′‐[(E)‐(2‐hydroxy‐3‐methoxyphenyl)methylidene]benzhydrazide) was analysed in depth from both theoretical and experimental points of view. Cantilever torque magnetometry indicated that the complex has Ising‐type anisotropy, and provided two possible directions for the easy axis of anisotropy due to the presence of two magnetically non‐equivalent molecules in the crystal. Ab initio calculations confirmed the strong Ising‐type anisotropy and disentangled the two possible orientations. The computed results obtained by using ab initio calculations were then used to rationalise the composite dynamic behaviour observed for both pure DyIII phase and YIII diluted phase, which showed two different relaxation channels in zero and non‐zero static magnetic fields. In particular, we showed that the relaxation behaviour at the higher temperature range can be correctly reproduced by using a master matrix approach, which suggests that Orbach relaxation is occurring through a second excited doublet. 相似文献
9.
Ida‐Marie Hyvik Branislav Jansik Kasper Kristensen Poul Jrgensen 《Journal of computational chemistry》2013,34(15):1311-1320
Using the three‐level energy optimization procedure combined with a refined version of the least‐change strategy for the orbitals—where an explicit localization is performed at the valence basis level—it is shown how to more efficiently determine a set of local Hartree–Fock orbitals. Further, a core–valence separation of the least‐change occupied orbital space is introduced. Numerical results comparing valence basis localized orbitals and canonical molecular orbitals as starting guesses for the full basis localization are presented. The results show that the localization of the occupied orbitals may be performed at a small computational cost if valence basis localized orbitals are used as a starting guess. For the unoccupied space, about half the number of iterations are required if valence localized orbitals are used as a starting guess compared to a canonical set of unoccupied Hartree–Fock orbitals. Different local minima may be obtained when different starting guesses are used. However, the different minima all correspond to orbitals with approximately the same locality. © 2013 Wiley Periodicals, Inc. 相似文献
10.