Rational Design of a Near-infrared Fluorescent Material with High Solid-state Efficiency,Aggregation-induced Emission and Live Cell Imaging Property

Near-infrared(NIR) fluorescent materials with high photoluminescent quantum yields(PLQYs) have wide application prospects. Therefore, we design and synthesize a D-A type NIR organic molecule, TPATHCNE, in which triphenylamine and thiophene are utilized as the donors and fumaronitrile is applied as the acceptor. We systematically investigate its molecular structure and photophysical property. TPATHCNE shows high T_gof 110℃ and T_d of 385℃ and displays an aggregation-induced emission(AIE) property. A narrow optical bandgap of 1.65 eV is obtained. The non-doped film of TPATHCNE exhibits a high PLQY of 40.3% with an emission peak at 732 nm, which is among the best values of NIR emitters. When TPATHCNE is applied in organic light-emitting diode(OLED), the electroluminescent peak is located at 716 nm with a maximum external quantum efficiency of 0.83%. With the potential in cell imaging, the polystyrene maleic anhydride(PMSA) modified TPATHCNE nanoparticles(NPs) emit strong fluorescence when labeling HeLa cancer cells, suggesting that TPATHCNE can be used as a fluorescent carrier for specific staining or drug delivery for cellular imaging. TPATHCNE NPs fabricated by bovine serum protein(BSA) are cultivated with mononuclear yeast cells, and the intense intracellular red fluorescence indicates that it can be adopted as a specific stain for imaging.     

基于快速神经网络架构搜索的鲁棒图像水印网络算法

为解决深度学习在图像水印算法中计算量大且模型冗余的问题，提高图像水印算法在抵抗噪声、旋转和剪裁等攻击时的鲁棒性，提出基于快速神经网络架构搜索（neural architecture search，NAS）的鲁棒图像水印网络算法。通过多项式分布学习快速神经网络架构搜索算法，在预设的搜索空间中搜索最优网络结构，进行图像水印的高效嵌入与鲁棒提取。首先，将子网络中线性连接的全卷积层设置为独立的神经单元结构，并参数化表示结构单元内节点的连接，预先设定结构单元内每个神经元操作的搜索空间；其次，在完成一个批次的数据集训练后，依据神经元操作中的被采样次数和平均损失函数值动态更新概率；最后，重新训练搜索完成的网络。水印网络模型的参数量较原始网络模型缩减了92%以上，大大缩短了模型训练时间。由于搜索得到的网络结构更为紧凑，本文算法具有较高的时间性能和较好的实验效果，在隐藏图像时，对空域信息的依赖比原始网络更少。对改进前后的2个网络进行了大量鲁棒性实验，对比发现，本文算法在CIFAR-10数据集上对抵抗椒盐噪声和旋转、移除像素行（列）等攻击优势显著；在ImageNet数据集上对抵抗椒盐高斯噪声、旋转、中值滤波、高斯滤波、JPEG压缩、裁剪等攻击优势显著，特别是对随机移除行（列）和椒盐噪声有较强的鲁棒性。     

n型IBC太阳电池选择性发射极工艺研究

为提升n型叉指背接触(IBC)太阳电池的光电转换效率,采用丝网印刷硼浆和高温扩散的方式形成选择性发射极结构,研究了硼扩散和硼浆印刷工艺对电池发射极钝化性能和接触性能的影响。实验结果表明,在硼扩散沉积时间和退火时间一定的条件下,硼扩散通源(BBr₃)流量为100 mL/min,沉积温度为830 ℃,退火温度为920 ℃时,发射极轻掺杂(p⁺)区域的隐开路电压达到710 mV,暗饱和电流密度为12.2 fA/cm²。发射极局部印刷硼浆湿重为220 mg时,经过高温硼扩散退火,重掺杂(p⁺⁺)区域的隐开路电压保持在683 mV左右,该区域方块电阻仅46 Ω/□,金属接触电阻为2.3 mΩ·cm². 采用该工艺方案制备的IBC电池最高光电转换效率达到24.40%,平均光电转换效率达到24.32%,相比现有IBC电池转换效率提升了0.28个百分点。     

双激光脉冲打靶形成Gd等离子体的极紫外光谱辐射

高端芯片制造所需要的极紫外光刻技术位于我国当前面临35项"卡脖子"关键核心技术之首.高转换效率的极紫外光源是极紫外光刻系统的重要组成部分.本文通过采用双激光脉冲打靶技术实现较强的6.7 nm极紫外光输出.首先,理论计算Gd¹⁸⁺—Gd²⁷⁺离子最外层4d壳层的4p-4d和4d-4f能级之间跃迁、以及Gd¹⁴⁺—Gd¹⁷⁺离子最外层4f壳层的4d-4f能级之间跃迁对波长为6.7 nm附近极紫外光的贡献.其后开展实验研究,结果表明,随着双脉冲之间延时的逐渐增加,波长为6.7 nm附近的极紫外光辐射强度呈现先减弱、后增加、之后再减弱的变化趋势,在双脉冲延时为100 ns处产生的极紫外光辐射最强.并且,在延时为100 ns处产生的光谱效率最高,相比于单脉冲激光产生的光谱效率提升了33%.此外,发现双激光脉冲打靶技术可以有效地减弱等离子体的自吸收效应,获得的6.7 nm附近极紫外光谱宽度均小于单激光脉冲打靶的情形,且在脉冲延时为30 ns时刻所产生的光谱宽度最窄,约为单独主脉冲产生极紫外光谱宽度的1/3.同时...     

Effect of the alkyl chain of quaternary ammonium cationic surfactants on corrosion inhibition in hydrochloric acid solution

In this study, the effect of the alkyl chain of quaternary ammonium cationic surfactants on corrosion inhibition in hydrochloric acid (HCl) solution was investigated by using dodecyl trimethyl ammonium chloride (DTAC), tetradecyl trimethyl ammonium chloride (TTAC), cetyl trimethyl ammonium chloride (CTAC), and octadecyl trimethyl ammonium chloride (OTAC) as corrosion inhibitors to uncover their structure–efficiency relationships. The effect of the alkyl chain of quaternary ammonium cationic surfactants on corrosion inhibition in HCl solution was studied under different conditions, such as corrosion inhibitor concentration, temperature, and acidity, and this was done using the weightlessness method. The results obtained show that these inhibitors have high corrosion inhibition effect on A₃ steel, and the corrosion inhibition efficiency is dependent on the length of the alkyl chain. At the same concentration, the longer the alkyl chain, the weaker the corrosion inhibition effect. When the temperature was 50 °C and the concentration of corrosion inhibitor was 70 mg/L, the corrosion inhibition efficiency order of the four cationic surfactants was DTAC > TTAC > CTAC > OTAC. Besides, the experimental results obtained show that the adsorption of the inhibitor on the A₃ steel surface conforms to the Langmuir type isotherm, and then the corresponding adsorption thermodynamic parameters were obtained according to these parameters. It was observed that ΔH, ΔS, and E_a increased with increase in the length of the alkyl chain. The adsorption of the inhibitor on the steel surface is an exothermic, spontaneous, entropy process.     

Polyepoxysuccinic acid with hyper-branched structure as an environmentally friendly scale inhibitor and its scale inhibition mechanism

In order to improve the scale inhibition efficiency of existing polyepoxysuccinic acid (PESA) and to study the impact of their molecular structure on scale inhibition efficiency, a series of PESA with linear and hyper-branched structure have been designed and synthesized through co-polymerization reaction with glycidyl and epoxy succinate. The scale inhibition behavior of PESA with linear and hyper-branched structure against CaCO₃ and CaSO₄ scales was evaluated using static scale inhibition method, and their ability to retard deposition of CaCO₃ was also examined. The experimental results showed that, for CaCO₃ and CaSO₄, the PESA with hyper-branched structure provides a scale inhibiting efficiency as high as 95.9% and 94.3%, respectively, at an inhibitor concentration of 15?mg/L. In addition, the processes of crystal nucleation, growth and crystal morphology have been analyzed. The experimental results show that the PESA with hyper-branched structure not only prolongs the induction period of CaCO₃ crystal nucleation, but also reduces the number of crystal nuclei and changes the size and morphology of the CaCO₃ crystal. Moreover, the FTIR, SEM and XRD analyses showed that the PESA with hyper-branched structure can induce the irregularity of growing CaCO₃ crystal, destroy the formation of crystals and change the polymorphs of calcium scale crystal. This conclusion indicates that the prepared PESA with hyper-branched structure has great potential for applying in the treatment of industrial water.     

Diffusive search with spatially dependent resetting

We consider a stochastic search model with resetting for an unknown stationary target $a\in \mathbb{R}$ with known distribution $\mu$. The searcher begins at the origin and performs Brownian motion with diffusion constant $D$. The searcher is also armed with an exponential clock with spatially dependent rate $r=r\left(\cdot \right)$, so that if it has failed to locate the target by the time the clock rings, then its position is reset to the origin and it continues its search anew from there. Denote the position of the searcher at time $t$ by $X\left(t\right)$. Let $E_0^{\left(r\right)}$ denote expectations for the process $X\left(\cdot \right)$. The search ends at time $T_a=inf\{t\ge 0:X\left(t\right)=a\}$. The expected time of the search is then ${\int }_{\mathbb{R}}\left(E_0^{\left(r\right)}{T}_a\right)\mu \left(da\right)$. Ideally, one would like to minimize this over all resetting rates $r$. We obtain quantitative growth rates for $E_0^{\left(r\right)}{T}_a$ as a function of $a$ in terms of the asymptotic behavior of the rate function $r$, and also a rather precise dichotomy on the asymptotic behavior of the resetting function $r$ to determine whether $E_0^{\left(r\right)}{T}_a$ is finite or infinite. We show generically that if $r\left(x\right)$ is of the order ${\left|x\right|}^{2l}$, with $l>-1$, then $log{E}_0^{\left(r\right)}{T}_a$ is of the order ${\left|a\right|}^{l+1}$; in particular, the smaller the asymptotic size of $r$, the smaller the asymptotic growth rate of $E_0^{\left(r\right)}{T}_a$. The asymptotic growth rate of $E_0^{\left(r\right)}{T}_a$ continues to decrease when $r\left(x\right)\sim \frac{D\lambda }{x^2}$ with $\lambda >1$; now the growth rate of $E_0^{\left(r\right)}{T}_a$ is more or less of the order ${\left|a\right|}^{\frac{1+\sqrt{1+8\lambda }}{2}}$. Note that this exponent increases to $\infty$ when $\lambda$ increases to $\infty$ and decreases to 2 when $\lambda$ decreases to 1. However, if $\lambda =1$, then $E_0^{\left(r\right)}{T}_a=\infty$, for $a\ne 0$. Our results suggest that for many distributions $\mu$ supported on all of $\mathbb{R}$, a near optimal (or optimal) choice of resetting function $r$ in order to minimize ${\int }_{{\mathbb{R}}^d}\left(E_0^{\left(r\right)}{T}_a\right)\mu \left(da\right)$ will be one which decays quadratically as $\frac{D\lambda }{x^2}$ for some $\lambda >1$. We also give explicit, albeit rather complicated, variational formulas for ${inf}_{r\gneqq 0}{\int }_{{\mathbb{R}}^d}\left(E_0^{\left(r\right)}{T}_a\right)\mu \left(da\right)$. For distributions $\mu$ with compact support, one should set $r=\infty$ off of the support. We also discuss this case.     

环境规制强度影响能源效率的门槛效应研究——基于PSTR模型

利用非径向-SBM和CCR模型测算了我国30个省市(暂不包括西藏和港澳台地区)2007-2016年间的环境规制强度以及能源效率,构建面板平滑转移回归模型(PSTR),分析了环境规制强度对我国能源效率的连续非线性变化的影响.研究结果显示,全国环境规制强度对我国能源效率存在非线性效应,二者之间呈倒“U”型关系.环境规制强度小于门槛值0.6376时,环境规制对能源效率产生创新补偿效应,当环境规制强度高于门槛值0.6376时,环境规制对能源效率产生遵循成本效应.而我国东西部地区的环境规制强度与地区能源效率间却存在着与之相反的“U”型效应.