Ethanol‐Precipitable,Silica‐Passivated Perovskite Nanocrystals Incorporated into Polystyrene Microspheres for Long‐Term Storage and Reusage

Perovskite nanocrystals (PNCs) are emerging luminescent materials due to their fascinating physic‐optical properties. However, their sensitive surface chemistry with organic polar solvents, oxygen, and moisture greatly hinders their developments towards practical applications. Herein we promote silica‐passivated PNCs (SP‐PNCs) by in situ hydrolyzing the surface ligands of (3‐aminopropyl) triethoxysilane. The resultant SP‐PNCs possesses a high quantum yield (QY) of 80 % and are precipitable by polar solvents, such as ethanol and acetone, without destroying their surface chemistry or losing QY, which offers an eco‐friendly and efficient method for separation, purification, and phase transfer of PNCs. Moreover, we further promoted a swelling–deswelling encapsulation process to incorporate the as‐made SP‐PNCs into non‐crosslinked polystyrene microspheres (PMs), which can largely increase the stability of the SP‐PNCs against moisture for long‐term storage.     

Effects of the triple junction types on the grain boundary carbide precipitation in a nickel-based superalloy,a statistical analysis

The morphology evolution of carbide precipitated on grain boundary nearby different triple junctions in grain boundary engineering (GBE) treated nickel-based Inconel Alloy 690 aged at 715°C for different time was investigated by scanning electron microscopy and electron backscatter diffraction. The results show that, the diversity of triple junction types was increased by GBE significantly. The size and morphology of grain boundary carbide were not only affected by the grain boundary character, but also the nearby grain boundary character at the triple junction. The higher Σ values of the nearby grain boundaries, the larger carbide precipitated on the other grain boundary. Based on the experimental results, the effects of grain boundary characters and triple junction types on the carbide precipitation behaviours are discussed.     

Regioisomerism effect (RIE) on optimizing ultralong organic phosphorescence lifetimes

Organic phosphorescence materials demonstrate potential optoelectronic applications due to their remarkably ultralong organic phosphorescence (UOP) lifetime and abundant optical characteristics prior to the fluorescence materials. For a better insight into the intrinsic relationship among regioisomeric molecules, crystalline interactions, and phosphorescence properties, three crystalline dicarbazol-9-yl pyrazine-based regioisomers with para-, meta-, and ortho-convergent substitutions (p-DCzP, m-DCzP, and o-DCzP) were designed and presented gradually increased UOP lifetimes prolonging from 63.14, 127.93 to 350.46 ms, respectively, due to the regioisomerism effect (RIE) which would be an effective strategy for better understanding of structure-property of UOP materials.     

基于加权流量介数中心性的路网脆弱性分析——以无锡市为例

针对当前路网脆弱性研究中缺乏对真实交通状况考量的问题，在复杂网络理论的基础上，结合交通流量信息，提出了基于加权流量介数中心性的路网脆弱性分析方法。首先计算路网拓扑抽象图中各节点的最短路径介数中心性，然后使用流量数据对相应区域最短路径介数中心性加权，综合得到最终的脆弱性指标结果。以无锡市为例，对其实际交通路网脆弱性进行了计算，结果表明，该方法能综合反映静态全局路网结构与动态局部通行信息和现实交通情景下的路网脆弱性。     

企业雇佣下残疾人就业行为研究——基于就业促进政策的演化博弈分析

融合就业是残疾人可持续发展的关键途径。基于演化博弈理论和残疾人就业促进政策,建立残疾人与用人单位(企业)行为交互过程的动态演化模型,用数值实验展示了初始条件改变和决策变量不同取值对系统演化结果的影响。研究发现,残疾人就业行为路径演化系统收敛于良好状态和“锁定”状态两种模式;调控模型中的参数收敛于不同模式的概率发生显著变化或变化不明显,揭示了现实中残疾人就业治理效果不理想的深层次原因;通过提高残疾人的工资待遇、心理收益、为企业创造的价值,减少残疾人的社会补助与就业付出的人力和社会资本,增加残疾人就业法定比例、企业雇佣残疾人的声誉收益、增值税退税优惠(企业符合退税条件)与雇佣残疾人数量,减少企业支持残疾人的就业投入等均能使系统演化到良好状态的概率增加。这为制定灵活有效的残疾人就业制度、政策与措施提供了较大的操作空间,多元主体协同治理,利益共享,良性互动,以跳出不良“锁定”状态,实现残疾人就业行为良序发展,破解就业难题。     

Enhancing hydrogen evolution of MoS2 basal planes by combining single-boron catalyst and compressive strain

MoS₂ is a promising candidate for hydrogen evolution reaction (HER), while its active sites are mainly distributed on the edge sites rather than the basal plane sites. Herein, a strategy to overcome the inertness of the MoS₂ basal surface and achieve high HER activity by combining single-boron catalyst and compressive strain was reported through density functional theory (DFT) computations. The ab initio molecular dynamics (AIMD) simulation on B@MoS₂ suggests high thermodynamic and kinetic stability. We found that the rather strong adsorption of hydrogen by B@MoS₂ can be alleviated by stress engineering. The optimal stress of −7% can achieve a nearly zero value of ΔG_H (~ −0.084 eV), which is close to that of the ideal Pt–SACs for HER. The novel HER activity is attributed to (i) the B– doping brings the active site to the basal plane of MoS₂ and reduces the band-gap, thereby increasing the conductivity; (ii) the compressive stress regulates the number of charge transfer between (H)–(B)–(MoS₂), weakening the adsorption energy of hydrogen on B@MoS₂. Moreover, we constructed a SiN/B@MoS₂ heterojunction, which introduces an 8.6% compressive stress for B@MoS₂ and yields an ideal ΔGH. This work provides an effective means to achieve high intrinsic HER activity for MoS₂.     

产业转移下的海上丝绸之路沿线集装箱港口的投资决策研究

在产业转移背景下,考虑港口服务货运需求与刺激货运需求的双重功效,研究海上丝绸之路沿线产业承接地的港口投资建设问题。首先,在现实交通运输网络中加入虚拟链接构建超级网络,用以刻画制造业的转移、生产和运输过程。其次,建立制造业承接地港口投资决策优化模型,用运输阻抗、地价和工资三个内生变量描述港口投资、产业转移与区域经济之间均衡关系。模型以产业承接地港口收益最大为目标,确定承接地港口的投资规模及费率水平。最后,以斯里兰卡的科伦坡口为例进行数值分析,计算海上丝绸之路沿线港口需求与供给间正向反馈的数量关系及上确界,为优化沿线港口投资实现投资利益最大化提供依据。     

Nonmetal Doping as a Robust Route for Boosting the Hydrogen Evolution of Metal-Based Electrocatalysts

Recently, nonmetal doping has exhibited its great potential for boosting the hydrogen evolution reaction (HER) of transition-metal (TM)-based electrocatalysts. To this end, this work overviews the recent achievements made on the design and development of the nonmetal-doped TM-based electrocatalysts and their performance for the HER. It is also shown that by rationally doping nonmetal elements, the electronic structures of TM-based electrocatalysts can be effectively tuned and in turn the Gibbs free energy of the TM for adsorption of H* intermediates (ΔG_H*) optimized, consequently enhancing the intrinsic activity of TM-based electrocatalysts. Notably, we highlight that concurrently doping two nonmetal elements can continuously and precisely regulate the electronic structures of the TM, thereby maximizing the activity for HER. Moreover, nonmetal doping also accounts for enhancing the physical properties of the TM (i.e. surface area). Therefore, nonmetal doping is a robust strategy for simultaneous regulation of the chemical and physical features of the TM.