Oxotitanium(IV) complexes of some bis‐unsymmetric Schiff bases: Synthesis,structural elucidation and biomedical applications

A number of oxotitanium(IV) complexes of the type TiOL with bis‐unsymmetric dibasic tetradentate Schiff base (LH₂) containing ONNO donor atoms have been synthesized. Mono‐Schiff base (OPD‐HNP) was prepared by the condensation of 1:3 molar ratio of 2‐hydroxy‐1‐naphthaldehyde (HNP) with o‐phenylenediamine (OPD). Dibasic unsymmetric tetradentate diamine Schiff bases were prepared by the reaction of OPD‐HNP with 2‐hydroxyacetophenone, 2‐hydroxypropeophenone, benzoylacetone, acetylacetone and ethylacetoacetate. Further, titanylacetylacetonate was reacted with these ligands to obtain their metal complexes. On the basis of analytical and physiochemical data, the formation of complexes as TiOL was suggested having square pyramidal geometry. Quantum mechanical approach also confirmed this geometry. The assessment of the synthesized ligands and their complexes showed that some behave as good inhibitors of mycelial growth against selected phytopathogic fungi but weak inhibitors against some selected bacteria. A few of them also showed antioxidant properties.     

周期激励下的前包钦格呼吸神经元的簇振荡现象研究

研究周期激励作用下的非自治前包钦格呼吸神经元模型,结果表明当外界激励频率与系统固有频率存在着量级差距时,系统可以产生典型的簇放电模式.由于激励频率远小于系统的固有频率,因此将整个周期激励项视为慢变参数,从而可以利用稳定性分析理论研究慢变参数变化下的平衡点的分岔类型,进一步应用快慢动力学分析方法给出簇模式产生的动力学机理.本文的结果说明外界激励对神经元的动力学行为有着重要影响,为进一步揭示呼吸节律的产生机制提供了重要帮助.     

群集建筑中大跨裙摆屋盖风荷载特性的数值模拟研究

以苏州太平金融大厦为工程背景,针对其大跨裙摆屋盖的风荷载作用,首先采用RNG k-ε模型模拟分析了其平均风压分布规律,以及风向变化对屋盖表面风荷载体型系数的影响;其次,引入干扰因子IF,探讨了周边建筑对大跨裙摆屋盖风荷载的气动干扰作用。结果表明:0°风向下,走廊上方屋盖两侧区域出现“上吸下顶”的叠加作用;90°风向下屋盖北侧飘带末端区域受到狭道风效应出现正压集中现象;风向变化对大跨裙摆屋盖的风荷载体型系数分布影响较大;且周围建筑物对大跨裙摆屋盖的气动干扰效应明显,主要表现为风压“遮挡效应”,而局部区域表现为风压“放大效应”。     

Photoinduced Pyramidal Inversion Behavior of Phosphanes Involved with Aggregation-Induced Emission Behavior

Aggregation-induced emission (AIE) is a fascinating phenomenon because of the applications of luminescent materials in the aggregated state, which exploit the large structural changes of the molecules in the excited state. Recently, it was reported that triphenylphosphane derivatives show AIE behavior in which they undergo potentially large structural changes in the excited state. Inspired by this report, photoinduced pyramidal inversion behavior of phosphanes was investigated. In photochemical experiments, the prepared P-stereogenic phosphanes exhibited photoracemization in dilute solution, and a negative correlation was observed between the photoracemization and the AIE phenomenon. Theoretical computations revealed that the inversion barrier in the excited state was much smaller than that in the ground state. This is the first report on the photoinduced pyramidal inversion behavior of phosphanes, which will provide new and unexplored applications.     

杭州大剧院风压分布的风洞试验研究

杭州大剧院外观造型新颖独特，由一个近似为椭球的双曲面屋盖和一个倒置的圆锥面玻璃幕墙相交形成大剧院的主体建筑的外轮廓．本文结合该主体结构的抗风设计要求，制作了1：200刚性模型进行结构表面脉动风压平均风压分布的风洞试验研究，详细介绍了风洞试验及数据处理方法，讨论了在不同风向角下椭球面屋盖和圆锥面玻璃幕墙的风压分布．为了便于整体结构设计，本文根据结构的实际情况对椭球面和圆锥面进行分块并给出相应的分块风压数据，最后根据各风向角下的风压分布特征给出了整体结构抗风设计的最不利风向角．     

波纹钢屋盖结构板件相关屈曲的试验研究与分析

拱型波纹钢屋盖结构的受力机理异常复杂，波纹、加工制作过程中产生的变形和残余应力等初始缺陷在理论分析中很难精确定量描述。论文对波纹钢屋盖结构梯形截面板组进行了轴心和偏心压力作用下稳定承载能力的试验研究，并与理论结果进行了比较分析，试验与理论结果吻合较好。试验结果表明波纹板组具有较高的局部屈曲承载能力，但几乎无屈曲后承栽能力，与平板板组屈曲特性相比有显著差异。     

开槽对大跨悬挑平屋盖结构风荷载的影响

本文结合一大跨悬挑平屋盖模型的风洞试验研究，分析了此类结构屋盖的平均局部体型系数和极值局部体型系数的分布特性；并根据其风压的分布特性，提出在悬挑屋盖承受较大负压的屋檐和角点附近这些遇强风易发生破坏的部位采取开槽气动抗风措施，进一步研究了该气动抗风措施对大跨悬挑平屋盖结构风荷载的影响，试验结果显示，它们可以有效地削减屋盖风敏感处的风荷载值，使平均局部体型系数大约降低50％，极值局部体型系数大约降低25％，所得的这些结果对于结构的抗风设计有一定的指导意义。     

不连续岩石梁的失稳解析

本文根据不连续岩石梁的物理力学特性提出了无拉力岩石梁的力学解析模型。根据Ｆｒｅｅｂｏｄｙ法及Ｃａｓｔｉｇｌｉａｎｏ定量导出了不连续梁各物理量的求解方程式。进而采用挠度增量δｍａｘ＾ｉ＋１＝δｍａｘ＾ｉ＋Δδ↑－的逐次解析方法，求解了不连续梁的失稳问题，得出了与Ｆ．Ｄ．Ｗｒｉｇｈｔ的试验值相吻合的结果。探讨了不连续岩石梁在不同荷载条件下的失稳特性。     

坚硬顶板爆破切顶在沿空留巷中的应用研究

当煤层上方为坚硬顶板时,在工作面回采期间容易出现大面积悬顶,导致巷旁充填体出现大变形破坏,极大威胁采煤安全.为解决这一问题,以某矿1205工作面沿空留巷为工程背景,分析了爆炸围岩裂隙范围和坚硬顶板破断特征,建立了切顶卸压围岩结构力学模型,研究表明,相邻炮孔爆炸后,炮孔间裂隙互相贯穿,降低了顶板强度,同时当切顶角为15°时,巷道稳定性较好.工程实践结果表明:采用爆破切顶技术后,顶板下沉量减小了62.3%,较好地保证了围岩稳定性.