首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   926篇
  免费   214篇
  国内免费   255篇
化学   942篇
晶体学   35篇
力学   143篇
综合类   9篇
数学   54篇
物理学   212篇
  2024年   1篇
  2023年   15篇
  2022年   34篇
  2021年   41篇
  2020年   77篇
  2019年   45篇
  2018年   49篇
  2017年   39篇
  2016年   61篇
  2015年   76篇
  2014年   62篇
  2013年   106篇
  2012年   51篇
  2011年   56篇
  2010年   39篇
  2009年   48篇
  2008年   68篇
  2007年   63篇
  2006年   54篇
  2005年   57篇
  2004年   50篇
  2003年   74篇
  2002年   47篇
  2001年   27篇
  2000年   23篇
  1999年   18篇
  1998年   21篇
  1997年   27篇
  1996年   14篇
  1995年   9篇
  1994年   8篇
  1993年   4篇
  1992年   6篇
  1991年   4篇
  1990年   2篇
  1989年   5篇
  1988年   2篇
  1987年   2篇
  1986年   3篇
  1985年   2篇
  1984年   1篇
  1982年   1篇
  1979年   1篇
  1973年   1篇
  1957年   1篇
排序方式: 共有1395条查询结果,搜索用时 16 毫秒
1.
Yuejun Ding 《中国物理 B》2022,31(6):68201-068201
Na-ion batteries (NIBs) are regarding as the optimum complement for Li-ion batteries along with the rapid development of stationary energy storage systems. In order to meet the commercial demands of cathodes for NIBs, O3-type Cu containing layered oxide Na0.90Cu0.22Fe0.30Mn0.48O2 with good comprehensive performance and low-cost element components is very promising for the practical use. However, only part of the Cu3+/Cu2+ redox couple participated in the redox reaction, thus impairing the specific capacity of the cathode materials. Herein, Mg2+-doped O3-Na0.90Mg0.08Cu0.22Fe0.30Mn0.40O2 layered oxide without Mn3+ was synthesized successfully, which exhibited improved reversible specific capacity of 118 mAh/g in the voltage range of 2.4-4.0 V at 0.2 C, corresponding to the intercalation/deintercalation of 0.47 Na+ (0.1 more than that of Na0.90Cu0.22Fe0.30Mn0.48O2). This work demonstrates an important strategy to obtain advanced layered oxide cathodes for NIBs.  相似文献   
2.
Herein, we report a facile method for synthesizing MoCo-layered double hydroxide (LDH) nanosheets employing Prussian blue analog (PBA) as the precursor. The introduction of Mo in Co-LDH modulates the electronic structure, increases the number of active sites and electrochemical surface area to improve the hydrogen evolution, oxygen evolution, and overall water splitting activity. As a result, PBA-derived Mo0.25Co0.75-LDH nanosheets demonstrated 10 mA cm?2 current density at only 220 mV and 115 mV overpotentials for OER and HER, respectively. The overall water splitting was attained at 1.52 V cell voltage for 10 mA cm?2 current density.  相似文献   
3.
介绍了大学有机化学“强理念、重思维、活课堂、共育人、乐钻研”五维度教学新策略的内涵与实践。以线下教学为主,腾讯会议和慕课为辅助,践行“有机化学是科学也是艺术”的教学理念;采用多循环“疑探式”教学方式,辨析亲电试剂和亲核试剂的多样性;注重培养学生多种科学思维的综合运用;强化“文献预习”“练习讲解”“综合作业”“师生互动”等多个教学环节,加深学生对知识的理解与应用,提升学生在课堂中的参与度,着重培养学生的科学思维和人文素养、自主学习与团队合作精神。  相似文献   
4.
功率密度高、倍率性能优异和循环性能好等特性使得超级电容器在储能领域显示了巨大的应用前景。尽管二维层状材料剥离形成的纳米片层不仅可为电化学反应提供独特的纳米级反应空间,而且由其组装的层状纳米电极材料具有化学和结构上的氧化还原可逆性及纳米片层水平方向上离子或电子快速传输通道。但是,纳米片层组装电极材料在纳米片层垂直方向上离子或电子传输存在障碍,对于超级电容器功率密度和能量密度的提高及实现快速能量储存非常不利。因此,如何通过改善离子或电子的快速传输,实现超级电容器大功率密度下的高能量密度是超级电容器电极材料发展的方向之一。本文主要综述了二维层状材料剥离成纳米片层,纳米片层孔洞化策略及组装孔洞化材料在超级电容器电极材料中的应用。纳米层孔洞化技术是改善层状电极材料在纳米片层垂直方向离子或电子传输的有效手段,为实现高比电容下的高倍率性能超级电容器电极材料制备提供了方法学。最后,对开发大功率密度下的高能量密度超级电容器电极材料提出了展望。  相似文献   
5.
This study presents a simple and green dispersive micro‐solid phase extraction method for preconcentration of acidic quinolones from honey prior to high performance liquid chromatography determination. A two‐dimensional nanostructured zinc‐aluminum layered double hydroxide was synthesized and used as the sorbent for dispersive micro‐solid phase extraction. Its different characteristics from conventional sorbents is that it is dissolvable in acidic solution (pH < 4). After the extraction, the analyte elution step was omitted and thus the use of organic solvents was avoided. The key parameters influencing the extraction efficiency such as the amount of sorbent, pH of sample solution, vortex time, type and volume of acidic solution were investigated and optimized. The method exhibited low limits of detection (3.0?5.0 ng/g), good linearity (10?2000 ng/g) with coefficients of determinations higher than 0.9991, acceptable precision (RSD<9.1%) and accuracy (RE<5.8%). The proposed method is fast, efficient, eco‐friendly, and suitable for the determination of acidic quinolones in honey samples.  相似文献   
6.
Graphene oxide (GO) has triggered significant attention as a new type of self‐assembly membrane material. However, the low filtration flux and unstable performance of GO membrane limit its practical application. Hence, in this work, layered double hydroxides (LDHs), as a 2D material with double‐layer channel structure and positive electricity, were self‐assembled with GO at weight ratio of 7:3 by electrostatic interaction. Then, the GO/LDH hybrids combined with polydopamine (PDA) to obtain stable and high‐flux GO‐based membranes through vacuum filtration and the structure and morphology of as‐prepared samples were characterized by FT‐IR, XRD, XPS, and SEM. Furthermore, the separation performance and surface electronegativity of membranes were tested via pure water flux, rejection efficiency, recycle experiments, and zeta potential. Results revealed that the stability and flux of composite membrane were enhanced significantly compared with neat GO‐based membrane. Further, the dye rejection rate of methylene blue (MB) is higher than Congo red (CR) and rhodamine B (Rh B) and reached to 99.8%.  相似文献   
7.
针对注水开发的多层砂岩油藏分层动态分析难度大等问题,在常规井层开发指标计算基础上,结合动、静态劈分方法,综合考虑渗透率、孔隙度、地层系数、含水饱和度、位置系数、措施系数及注水量系数,提出了一种既可将油、水井作为统一整体,又可对小层、方向流动分量开发指标进行定量计算的体现渗流力学本质的方法。用大庆油田N2-O1井组的产液剖面资料进行验证。结果表明,所提方法的计算结果与测量结果吻合度较高,精度平均值达75.11%。用该方法计算开发指标,适用性强,能较真实地反映各小层、各方向的产液情况,对现场应用具有指导意义。  相似文献   
8.
The experimental achievement of phosphorene, which exhibits superior electronic, physical, and optical properties has spurred recent interest in other Group 15 elemental 2D nanomaterials such as arsenene, antimonene, and bismuthene. These unique and superior properties of the pnictogen nanosheets have spurred intensive research efforts and led to the discovery of their diversified potential applications; for instance, optical Kerr material, photonic devices, pnictogen-decorated microfibers, high-speed transistors, and flexible 2D electronics. Previous studies have mainly been dedicated to study the synthesis, properties, and applications of the heavy pnictogens nanosheets; however, the toxicological behaviour of these nanosheets has yet to be established. Herein, the cytotoxicity study of pnictogen nanosheets (As, Sb, and Bi) was conducted over 24 h of incubation with various concentrations of test materials and adenocarcinoma human lung epithelial A549 cells. After the treatment period, the remaining cell viabilities were obtained through absorbance measurements with WST-8 and MTT assays. These findings demonstrate that the toxicity of pnictogen nanosheets decreases down Group 15, whereby arsenic nanosheets are considered to be the most toxic, whereas bismuth nanosheets induce low cytotoxicity. The findings of this study constitute an important initial step towards enhancing our understanding of the toxicological effects of pnictogen nanosheets in light of their prospective commercial applications.  相似文献   
9.
Layered materials can be grown on various substrates through van der Waals epitaxy (vdWE) regardless of lattice mismatch. The atomistic study of the film-substrate interface in vdWE is becoming increasingly important due to their expected applications as two-dimensional (2D) materials. In this contribution, we have grown GaSe thin films on Ge(111) substrates by molecular beam epitaxy and studied the GaSe/Ge(111) interface using high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM). Cross-sectional HAADF-STEM observations revealed that the grown layers adopt predominantly the expected wurtzite-like structure and stacking, but layers with zinc-blende-like structure, similar to Ga2Se3 but apparently different, and other layer stacking sequences, exist locally near the film-substrate interface. These results demonstrate that even in vdWE, structural changes can occur in the grown layers adjacent to the substrate, highlighting the importance of such interface for synthesizing and applying ultimately thin 2D materials.  相似文献   
10.
This review provides an update on the implementation of emerging materials as sorbents for sample preparation in combination with chromatographic separation. We have focused on recent applications of metal–organic frameworks, layered double hydroxides, porous carbons obtained from polymers or biomass precursors, and silicates (clays and zeolites). The review is directed toward the strategies followed by the authors to engineer suitable supports enabling the application of materials with unconventional size and shape as high‐performance sorbents to explore new boundaries in sample pretreatment in manual or automated modes.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号