首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   6487篇
  免费   1153篇
  国内免费   410篇
化学   2395篇
晶体学   77篇
力学   1506篇
综合类   53篇
数学   256篇
物理学   3763篇
  2024年   4篇
  2023年   42篇
  2022年   125篇
  2021年   133篇
  2020年   176篇
  2019年   182篇
  2018年   138篇
  2017年   192篇
  2016年   215篇
  2015年   297篇
  2014年   298篇
  2013年   982篇
  2012年   378篇
  2011年   454篇
  2010年   319篇
  2009年   371篇
  2008年   342篇
  2007年   366篇
  2006年   328篇
  2005年   317篇
  2004年   312篇
  2003年   242篇
  2002年   227篇
  2001年   185篇
  2000年   136篇
  1999年   112篇
  1998年   150篇
  1997年   118篇
  1996年   105篇
  1995年   120篇
  1994年   98篇
  1993年   105篇
  1992年   82篇
  1991年   68篇
  1990年   44篇
  1989年   44篇
  1988年   55篇
  1987年   30篇
  1986年   30篇
  1985年   22篇
  1984年   20篇
  1983年   5篇
  1982年   16篇
  1981年   18篇
  1980年   5篇
  1979年   17篇
  1977年   3篇
  1976年   4篇
  1973年   4篇
  1972年   5篇
排序方式: 共有8050条查询结果,搜索用时 15 毫秒
1.
2.
We used a diamond anvil cell(DAC) to control the deformation of synthesized copper nanorods and silver nanoparticles. And we measured the surface plasmon resonance of copper nanorods and silver nanoparticles, which exhibit redshifts or blueshifts. The surface plasmon resonance shows an abnormal blue shift for both copper nanorods and silver nanoparticles. The solvents of copper nanorods and silver nanoparticles are n-hexane and water, where the pressure loads include quasi-hydrostatic and non-hydrostatic.  相似文献   
3.
采用固相反应法合成了一种Zr Cu Si As型准二维层状锰基化合物Th Mn Sb N.基于X射线粉末衍射的结构精修显示,该化合物属于P4/nmm空间群.其晶胞参数为a=4.1731?, c=9.5160?.电输运测量显示,该化合物电阻率随温度下降缓慢上升,且在16 K附近出现电阻率异常.与此同时,该材料的磁化率在同一温度附近出现异常,显示出类似磁性相变的行为.进一步的比热测量中没有观察到磁相变导致的比热异常.另外,低温下的比热分析显示,该材料的电子比热系数为γ=19.7 m J·mol–1·K–2,远高于其他同类锰基化合物.该结果与电输运测量中观察到的低电阻率行为相符,暗示Th Mn Sb N中费米面附近存在可观的电子态密度.基于对一系列Zr Cu Si As型化合物晶体结构细节的比较,分析了含有萤石型Th2N2层的系列化合物中导电层所受化学压力的不同作用形式.  相似文献   
4.
张劲夫 《力学季刊》2022,43(2):465-469
针对杆件在横向力和轴向压力共同作用下的内力计算问题进行了研究.在考虑杆件变形因素的情形下,推导出了杆件在横向力和轴向压力共同作用下的内力和正应力的计算公式,并与材料力学中未考虑杆件变形因素的对应公式进行了比较,说明了二者之间不同之处.  相似文献   
5.
Cavitation erosion at the high hydrostatic pressure causes the equipment to operate abnormally for the huge economic losses. Few methods can quantitatively evaluate the cavitation erosion intensity. In order to solve this problem, the cavitation erosion on a copper plate was carried out in a spherical cavity focused transducer system at the hydrostatic pressure of 3, 6, and 10 MPa. Meanwhile, the corresponding cavitation threshold, the initial bubble radius, and the microjet velocity in the ultrasonic field are theoretically analyzed to determine the dimension and velocity of microjet based on the following hypotheses: (1) the influence of the coalescence on the bubble collapse is ignored; (2) the dimension of the microjet is equal to the largest bubble size without the influence of gravity and buoyancy. Using the Westervelt equation for the nonlinear wave propagation and the Johnson-Cook material constitutive model for the high strain rate, a microjet impact model of the multi-bubble cavitation was constructed. In addition, through the analogy with the indentation test, an inversion model was proposed to calculate the microjet velocity and the cavitation erosion intensity. The microjet geometric model was constructed from the dimension and velocity of the microjet. The continuous microjet impact was proposed according to the equivalent impact momentum and solved by the finite element method. The relative errors of the pit depth are 4.02%, 3.34%, and 1.84% at the hydrostatic pressure of 3, 6, and 10 MPa, respectively, and the relative error in the evolution of pit morphology is 7.33% at 10 MPa, which verified the reliability of the proposed models. Experimental and simulation results show that the higher the hydrostatic pressure, the greater the pit depth, pit diameter, the pit-to-microjet diameter ratio, and the cavitation erosion intensity, but the smaller the pit diameter-to-depth ratio. The cavitation erosion intensity becomes significant with the ongoing ultrasonic exposure. In addition, a comparison of the cavitation pit morphology in the microjet pulsed and continuous impact modes shows that the continuous impact mode is effective without the elastic deformation caused by the residual stress. Using the cavitation pit morphology at the different hydrostatic pressures, the microjet velocity can be estimated successfully and accurately in a certain range, whose corresponding errors at the lower and upper limit are 5.98% and 0.11% at 3 MPa, 6.62% and 9.14% at 6 MPa, 6.54% and 5.42% at 10 MPa, respectively. Our proposed models are valid only when the cavitation pit diameter-to-depth ratio is close to 1. Altogether, the cavitation erosion induced by multi-bubble collapses in the focal region of a focused transducer could be evaluated both experimentally and numerically. Using the cavitation pit morphology and the inversion model, the microjet velocity in a certain range could be estimated successfully with satisfactory accuracy.  相似文献   
6.
采用自主设计搭建的雾化辅助化学气相沉积系统设备,开展了Ga2O3薄膜制备及其特性研究工作。通过X射线衍射研究了沉积温度、系统沉积压差对Ga2O3薄膜结晶质量的影响。结果表明,Ga2O3在425~650 ℃温度区间存在物相转换关系。随着沉积温度从425 ℃升高至650 ℃,薄膜结晶分别由非晶态、纯α-Ga2O3结晶状态向α-Ga2O3、β-Ga2O3两相混合结晶状态改变。通过原子力显微镜表征探究了生长温度对Ga2O3薄膜表面形貌的影响,从475 ℃升高至650 ℃时,薄膜表面粗糙度由26.8 nm下降至24.8 nm。同时,高分辨X射线衍射仪测试表明475 ℃、5 Pa压差条件下的α-Ga2O3薄膜样品半峰全宽仅为190.8″,为高度结晶态的单晶α-Ga2O3薄膜材料。  相似文献   
7.
Modern convection-based supports differ substantially in pore size, porosity, and microstructure topology. Due to such variability, it is challenging to evaluate the contribution of a particular microstructure topology on flow resistance. We demonstrated that the flow resistance parameter (ϕ $\phi $) introduced decades ago can be used as a criterion to evaluate the effect of microstructure topology on a pressure drop when the pore size is used as a characteristic support dimension. Furthermore, the ϕ $\phi $ value of simple cubic packing was calculated over the entire range of open porosity and compared to the ϕ $\phi $ values determined for pressure drop models derived for particular convection-based supports and experimental values of various convection-based supports from the literature. It was shown that different convection-based supports become clustered into distinct groups when plotted according to their ϕ $\phi $ and open porosity values, allowing their discrimination.  相似文献   
8.
曾彦  梁浩  管诗雪  王俊普  梁文嘉  黄梦阳  彭放 《中国物理 B》2022,31(1):16104-016104
Structural stability in terms of the decomposition temperature in LiMn2O4 was systematically investigated by a series of high-temperature and high-pressure experiments.LiMn2O4 was found to have structural stability up to 5 GPa at room temperature.Under ambient pressure,the compound decomposed at 1300℃.The decomposition temperature decreased with increasing pressure,yielding more complex decomposed products.Below the decomposition temperature,the crystal structure of LiMn2O4 varied with pressure.The presented results in this study offer new insights into the thermal and pressure stability of LiMn2O4 materials as a cathode for lithium-ion batteries that can operate under extreme conditions.Therefore,these findings may serve as a useful guide for future work for improving lithium-ion batteries.  相似文献   
9.
Yukai Zhuang 《中国物理 B》2022,31(8):89101-089101
Iron oxides are widely found as ores in Earth's crust and are also important constituents of its interiors. Their polymorphism, composition changes, and electronic structures play essential roles in controlling the structure and geodynamic properties of the solid Earth. While all-natural occurring iron oxides are semiconductors or insulators at ambient pressure, they start to metalize under pressure. Here in this work, we review the electronic conductivity and metallization of iron oxides under high-pressure conditions found in Earth's lower mantle. We summarize that the metallization of iron oxides is generally controlled by the pressure-induced bandgap closure near the Fermi level. After metallization, they possess much higher electrical and thermal conductivity, which will facilitate the thermal convection, support a more stable and thicker D$\prime\prime$ layer, and formulate Earth's magnetic field, all of which will constrain the large-scale dynamos of the mantle and core.  相似文献   
10.
设计了一种新型边孔型保偏光子晶体光纤,在包层中对称地引入两个大空气孔,纤芯区域与大空气孔之间仅有一层小空气孔。由平面应变假设将该模型进行二维简化,利用有限元法对该光纤的二维模型进行数值分析,通过计算不同温度和静压力下的双折射频移以研究其温度和静压力传感特性。研究表明,在较大静压力和温度范围内,该保偏光子晶体光纤无需掺杂任何应力材料就可以实现?2.1353 GHz/MPa的静压力灵敏度且具有温度不敏感性,其温度灵敏度仅为+0.1542 MHz/℃。另外,还对该光子晶体光纤的光学特性进行了分析,其满足单模传输条件、具有较小的限制性损耗和较大的有效模场面积。由于具有体积小、与其他光纤兼容度强、静压力灵敏度高、温度不敏感的特性,其在温度变化不定、静压力改变区间较大的环境中静压力精确测量的优势比较明显,较好的光学特性使其在油井、土木的监测应用等方面有着重要参考价值。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号