全文获取类型
收费全文 | 292篇 |
免费 | 13篇 |
国内免费 | 13篇 |
专业分类
化学 | 55篇 |
力学 | 159篇 |
综合类 | 8篇 |
数学 | 25篇 |
物理学 | 71篇 |
出版年
2023年 | 1篇 |
2022年 | 11篇 |
2021年 | 10篇 |
2020年 | 11篇 |
2019年 | 6篇 |
2018年 | 3篇 |
2017年 | 12篇 |
2016年 | 13篇 |
2015年 | 13篇 |
2014年 | 7篇 |
2013年 | 14篇 |
2012年 | 9篇 |
2011年 | 10篇 |
2010年 | 5篇 |
2009年 | 11篇 |
2008年 | 16篇 |
2007年 | 11篇 |
2006年 | 14篇 |
2005年 | 12篇 |
2004年 | 18篇 |
2003年 | 16篇 |
2002年 | 16篇 |
2001年 | 9篇 |
2000年 | 13篇 |
1999年 | 8篇 |
1998年 | 12篇 |
1997年 | 4篇 |
1996年 | 9篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1989年 | 4篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1984年 | 2篇 |
1979年 | 1篇 |
排序方式: 共有318条查询结果,搜索用时 15 毫秒
1.
In this work the results of the statistical topometric analysis of fracture surfaces of soda-lime-silica glass with and without ionic exchange treatment are reported. In this case, the mechanism of substitution is K+-Na+. atomic force microscopy (AFM) was employed to record the topometric data from the fracture surface. The roughness exponent (ζ) and the correlation length (ξ) were calculated by the variable bandwidth method. The analysis for both glasses (subjected and non-subjected to ionic exchange) for ζ shows a value ∼0.8, this value agrees well with that reported in the literature for rapid crack propagation in a variety of materials. The correlation length shows different values for each condition. These results, along with those of microhardness indentations suggest that the self-affine correlation length is influenced by the complex interactions of the stress field of microcracks with that resulting from the collective behavior of the point defects introduced by the strengthening mechanism of ionic exchange. 相似文献
2.
This paper presents an enhanced version of the elasto-plastic model for partially saturated soil first proposed by Bolzon,
Schrefler and Zienkiewicz in 1996, “BSZ” model, which uses the effective stress tensor and suction as independent stress variables.
It is recalled that the effective stress tensor proposed by Lewis and Schrefler in 1982 is thermodynamically consistent and,
compared with other choices of stress tensors, results particularly suitable for partially saturated soil mechanics. A hydraulic
constitutive relationship and a hydraulic hysteresis are introduced in the model, to take into account the irreversible deformation
during cyclic drying and wetting until structural collapse. For this reason the plastic rate of strain is split into the sum
of two components: one depending on the effective stress tensor and the other one on suction. This is the new feature of the
BSZ model. This enhanced model is then cast into a thermodynamical framework at macroscopic level and it is shown that it
is possible to derive the constitutive law from the Helmholtz free energy and a dissipation function, both for associative
and non- associative plasticity. Finally the model predictions have been compared with experimental data for Sion slime, with
particular emphasis on the deviatoric part, and model predictions of hysteretic behaviour have been investigated in case of
a wetting and drying cycle on compacted betonite–kaolin. 相似文献
3.
4.
P. Ubbriaco 《Journal of Thermal Analysis and Calorimetry》1996,47(1):7-16
A lime-pozzolan cement was used to make pastes containing different quantities of MSW fly ash. After setting, the pastes were cured in water at room temperature from 1 h to 260 days. The hydration characteristics and the nature of the hydration products of the various pastes were studied by simultaneous TG/DSC thermal analysis and X-ray diffractometry. The MSW fly ash was found to induce a slowing of the hydration process in lime-pozzolan pastes, and after some days an evident acceleration of hydration reactions occurred. Sulphate and chloride in the MSW fly ash yield hydration products forming a cementitious matrix.The author is grateful to D. Calabrese for assistance with the thermal and XRD analyses. 相似文献
5.
Piyarat Thanakoses Nagat Abd Alla Mostafa Mark T. Holtzapple 《Applied biochemistry and biotechnology》2003,107(1-3):523-546
Using the MixAlco process, biomass can be converted into carboxylic acids, which can be chemically converted into mixed alcohol
fuels. This study focused on the use of countercurrent fermentation to anaerobically convert sugarcane bagasse and chicken
manure to mixed carboxylic acids using a mixed culture of mesophilic microorganisms from terrestrial and marine sources. Bagasse
was pretreated with lime to increase digestibility. The continuum particle distribution model (CPDM) simulated continuous
fermentors based on data collected from batch experiments. This model saves considerable time in determining optimum operating
conditions. For an 80% bagasse/20% chicken manure fermentation with terrestrial inoculum at a volatile solids loading rate
(VSLR) of 7.36 g/(L of liquid·d) and a liquid residence time (LRT) of 8.88 d, total carboxylic acid productivity, total acid
selectivity, and yield were 2.49 g/(L of liquid·d), 0.581 g of total acid/g of VS digested, and 0.338 g of total acid/g of
VS fed, respectively, at a concentration of 18.7 g of total acid/L. At the same VSLR and LRT, fermentation with marine inoculum
gave higher total acid productivity, total acid selectivity, and yield than fermentation with terrestrial inoculum. For an
80% bagasse/20% chicken manure fermentation with marine inoculum at a VSLR of 3.83 g/(L of liquid·d) and an LRT of 12.1 d,
total carboxylic acid productivity, total acid selectivity, and yield were 1.38 g/(L of liquid·d), 0.667 g of total acid/g
of VS digested, and 0.359 g of total acid/g of VS fed, respectively, at a concentration of 16.2 g of total acid/L. 相似文献
6.
Differential thermal analysis and thermogravimetry were used to evaluate the effect of some additives, such as CaSO4, CaCl2 and silica fume amorphous silica from ferrosilicon synthesis on the mechanism and kinetics of reactions occurring in fly
ash-Ca(OH)2 system. The accelerating role of these additives was demonstrated from the data relating to Ca(OH)2 consumption in hydrated pastes, determined by TG measurements.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
7.
DTA/TG and TG/DTG thermal studies and XRD investigations were carried out on pastes of lime-pozzolan binders to examine the
relative hydration process. The binders were prepared with two natural pozzolans and hydrated lime, mixed together in different
proportions. The main hydrated phases formed in the pastes are calcium silicate hydrate (CSH) and mono-carboaluminate. The
growth of CSH was greater for the paste of the pozzolan richer in reactive constituents. For pastes with a higher lime/pozzolan
ratio, a slowing of the formation of CSH was observed, while the formation of monocarboaluminate was more intense. The calcium
hydroxide contents of the pastes obtained by thermogravimetric analysis made it possible to determine the pozzolanic activities
of the two pozzolans under examination. The mortars for the various lime-pozzolan binders displayed characteristic hardening.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
8.
The use of aerosol produced in a nebulization chamber is proposed as an alternative to gas sample capture in flow systems. This paper describes the coupling of a sampling interface with a flow system, for in situ gas monitoring. Aspects related with the behavior of aerosol formation and gas solubilization in liquid drops are discussed. The method is applied to the determination of residual lime in acidic soils. Aliquots of 5.0 ml of 1.0 mol l−1 HCl were mixed with soil samples (1 g). The CO2 released from these samples was captured by a nebulized aerosol and determined conductivity. The analytical curve from 1.0×10−2 to 5.0×10−2 mol kg−1 CaCO3 was ploted applying the matrix matching approach. This proposition, allowed an increase in the sensibility with detection limit of 6.0×10−3 mol kg−1. The precision was good (R.S.D. <3%) for an analytical frequency of 22 determinations per hour. A fair agreement, at 95% confidence level, was found between the results from the proposed method and certified values of the investigated samples. 相似文献
9.
On the basis of the Helmholtz decomposition, a grid‐free numerical scheme is provided for the solution of unsteady flow in hydraulic turbines. The Lagrangian vortex method is utilized to evaluate the convection and stretch of the vorticity, and the BEM is used to solve the Neumann problem to define the potential flow. The no‐slip boundary condition is satisfied by generating vortex sticks at the solid surface. A semi‐analytical regularization technique is applied to evaluate the singular boundary surface integrals of the potential velocity and its gradients accurately. The fast multipole method was extended to evaluate the velocity and velocity gradients induced by the discretized vortex blobs in the Lagrangian vortex method. The successful simulation for the unsteady flow through a hydraulic turbine's runner has manifested the effectiveness of the proposed method. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
10.