Growth and characterization of two-dimensional crystals for communication and energy applications

This review article covers the growth and characterization of two-dimensional (2D) crystals of transition metal chalcogenides, h-BN, graphene, etc. The chemical vapor transport method for bulk single crystal growth is discussed in detail. Top-down methods like mechanical and liquid exfoliation and bottom-up methods like chemical vapor deposition and molecular beam epitaxy for mono/few-layer growth are described. The optimal characterization techniques such as optical, atomic force, scanning electron, and Raman spectroscopy for identification of mono/few-layer(s) of the 2D crystals are discussed. In addition, a survey was done for the application of 2D crystals for both creation and deterministic transfer of single-photon sources and photovoltaic systems. Finally, the application of plasmonic nanoantenna was proposed for enhanced solar-to-electrical energy conversion and faster/brighter quantum communication devices.     

复合材料失效判据有效性验证方法研究

为系统地验证复合材料失效判据计算精度和有效性范围,给出了4种材料体系、6种铺层形式的层合板在单轴、双轴载荷下的失效试验数据,用以评估复合材料失效判据在单向层合板失效包线、多向层合板初始失效包线、多向层合板最终失效包线、层合板变形及层合板的破坏特性等五个方面的预测能力。并根据验证方法和有效性评估策略对失效判据计算精度进行量化考核,给出了失效判据在五个层面上的计算精度。     

多层网络级联失效的预防和恢复策略概述

现实生活中,与国计民生密切相关的基础设施网络大多不是独立存在的,而是彼此之间相互联系或依赖的,于是用于研究这些系统的多层网络模型随之产生.多层网络中的节点在失效或者遭受攻击后会因"层内"和"层间"的相互作用而产生级联效应,从而使得失效能够在网络层内和层间反复传播并使得失效规模逐步放大.因此,多层网络比单个网络更加脆弱.多层网络级联失效产生的影响和损失往往是非常巨大的,所以对多层网络级联失效的预防和恢复的研究具有重大意义.就多层网络级联失效的预防而言,主要包含故障检测,保护重要节点,改变网络耦合机制和节点备份等策略.就多层网络发生级联失效后的恢复策略而言,主要包含共同边界节点恢复、空闲连边恢复、加边恢复、重要节点优先恢复、更改拓扑结构、局域攻击修复、自适应边修复等策略.     

Concise synthesis of dopexamine dihydrochloride via benzyl protecting protocol

Benzyl protecting protocol was first employed in two routes for the concise synthesis of dopexamine dihydrochloride.This protecting group could be cleanly removed under mild condition and no unacceptable ion was brought to the final product.The total yield of route I was 43.8% from phenylacetic acid,while it was 54.1% of route II from 2-(3,4-bis(benzyloxy)phenyl)acetic acid.The titration purity of the final product was more than 99.5%,while any single or total impurities met the known standard of the drug by HPLC analysis.The measured residual palladium met an acceptable limit(<1 ppm) as an API for injection.     

循环孔隙水压下混凝土常规三轴压缩损伤破坏特性分析

本文进行了孔隙水压不同循环次数(0次,10次,50次,100次和200次)以及不同应变速率下(10~(-5)/s,10~(-4)/s,10~(-3)/s和10~(-2)/s)混凝土常规三轴压缩试验,分析了混凝土峰值应变的变化规律、应力-应变曲线及损伤特性。结果表明:相同循环次数孔隙水压下,峰值应变随应变速率增加,整体呈现出增加的趋势;而相同应变速率下,峰值应变随孔隙水压循环次数的变化规律并不明显;在中低应变速率(10~(-5)~10~(-3)/s)下,混凝土的损伤变化受孔隙水压循环次数影响较大;当循环次数达到200次时,孔隙水压作用对混凝土产生较大的损伤。通过对循环孔隙水作用下混凝土动态损伤破坏机理的分析可知:混凝土的破坏过程实际上是内部裂纹不断形成、扩展、贯通,材料损伤不断产生、累积的过程;当损伤达到一定程度,混凝土发生宏观破坏,失去承载力。     

Extended Open-Chain Polyenides as Versatile Delocalized Anion Ligands for Metal Chain Clusters

Although small cyclic- and open-chain unsaturated hydrocarbon anions such as cyclopentadienide and open-chain pentadienide are used as the strongly electron-donating auxiliary ligands for metal complexes, more extended π-conjugated unsaturated hydrocarbon anions have rarely been used in coordination chemistry, despite their potential ability to serve as the multiply bridging π-ligands for metal clusters. This work reports isolation of metal chain clusters bearing the multi-dentate, open-chain extended unsaturated hydrocarbon anion ligands. The extended open-chain π-conjugated polyenyl ligands could effectively stabilize oxidized palladium chains, including an unprecedented [Pd₄]⁴⁺ chain.     

A High‐Efficiency All‐Fiber Laser Operated in High‐Order Mode using Ring‐Core Yb‐Doped Fiber

An all‐fiber laser generating a cylindrical vector beam is proposed and demonstrated using a home‐made ring‐core Yb‐doped fiber (RC‐YDF). In the RC‐YDF, not only annular doping but also ring‐type beam pump is realized. This is believed to be the first report describing the realization of annular doping and ring‐type beam pump in active fiber simultaneously, which can enhance the efficiency for high‐order mode oscillation. This laser operates in the high‐order mode stably with a slope efficiency of as high as 55.7%. Cylindrical vector modes can be obtained easily through adjusting the polarization controller. This work may have great potential for providing high‐efficiency and high‐power cylindrical vector beam and vortex beam sources.     

一类改进最大熵方法的可调参数分析

在结构可靠性分析中,引入含可调参数的转换函数能对传统的最大熵方法进行改进,获得更高的失效概率预测精度。但是,此可调参数的最佳取值很难确定。针对这一问题,引入概率守恒方程,从功能函数转换前后所得概率密度函数出发,建立其最大熵值的变化关系,给出转换前后最大熵值之差的理论形式。通过对三种典型单调非线性转换函数开展算例研究,发现功能函数转换前后的最大熵值之差与转换函数的最佳可调参数值有关。改变可调参数值驱使最大熵值之差变化的同时,改进最大熵方法能遍历到更好的失效概率估计值。     

A Dynamic Anomaly Detection Approach Based on Permutation Entropy for Predicting Aging-Related Failures

Software aging is a phenomenon referring to the performance degradation of a long-running software system. This phenomenon is an accumulative process during execution, which will gradually lead the system from a normal state to a failure-prone state. It is a crucial challenge for system reliability to predict the Aging-Related Failures (ARFs) accurately. In this paper, permutation entropy (PE) is modified to Multidimensional Multi-scale Permutation Entropy (MMPE) as a novel aging indicator to detect performance anomalies, since MMPE is sensitive to dynamic state changes. An experiment is set on the distributed database system Voldemort, and MMPE is calculated based on the collected performance metrics during execution. Finally, based on MMPE, a failure prediction model using the machine learning method to reveal the anomalies is presented, which can predict failures with high accuracy.     

基于单元破裂的岩石裂纹扩展模拟方法

传统离散元方法在处理破裂问题时, 采用界面上的准则进行判断, 裂纹只能沿着单元边界扩展. 当物理问题存在宏观或微观裂隙时, 在界面上应用准则具有其合理性; 而裂纹沿着单元边界扩展, 使得裂纹路径受网格影响较大, 扩展方向受到限制. 针对上述情况, 可以基于单元破裂的方式, 构建连续- 非连续单元法, 并应用于岩石裂纹扩展问题的模拟. 该方法在连续计算时, 将单元离散为具有物理意义的弹簧系统, 在局部坐标系下由弹簧特征长度、面积求解单元变形和应力, 通过更新局部坐标系和弹簧特征量, 可进一步计算块体大位移、大转动, 连续问题计算结果与有限元一致, 同时提高了计算效率. 在此基础上, 引入最大拉应力与莫尔-库伦的复合准则, 判断单元破裂状态和破裂方向, 并采用局部块体切割的方式, 在单元内形成初始裂纹. 裂纹两侧相应增加新的计算节点, 同时引入内聚力模型描述裂纹两侧的法向、切向作用与张开度及滑移变形之间的关系. 按此方式, 裂纹尖端处的扩展路径可穿过单元内部和单元边界, 在扩展方向的选取上更为准确. 最后, 通过三点弯曲梁、单切口平板拉伸、双切口试样等典型数值试验, 模拟裂纹在拉伸、压剪等各种应力状态下的扩展问题, 并对岩石单轴压缩试验的破坏过程进行模拟, 分析裂纹形成与应力-应变曲线各阶段之间的对应关系. 结果表明: 连续-非连续单元法通过单元内部破裂的方式, 可以显示模拟裂纹萌生、扩展、贯通直至形成宏观裂缝的过程.