首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   225篇
  免费   13篇
  国内免费   15篇
化学   195篇
力学   29篇
综合类   2篇
数学   11篇
物理学   16篇
  2023年   2篇
  2022年   4篇
  2021年   6篇
  2020年   8篇
  2019年   4篇
  2018年   4篇
  2017年   3篇
  2016年   5篇
  2015年   11篇
  2014年   9篇
  2013年   8篇
  2012年   7篇
  2011年   13篇
  2010年   12篇
  2009年   16篇
  2008年   9篇
  2007年   21篇
  2006年   14篇
  2005年   13篇
  2004年   16篇
  2003年   14篇
  2002年   11篇
  2001年   7篇
  2000年   3篇
  1999年   2篇
  1998年   2篇
  1997年   6篇
  1996年   2篇
  1995年   3篇
  1993年   2篇
  1992年   3篇
  1991年   2篇
  1990年   1篇
  1988年   1篇
  1987年   1篇
  1986年   1篇
  1985年   2篇
  1984年   1篇
  1981年   1篇
  1980年   1篇
  1979年   2篇
排序方式: 共有253条查询结果,搜索用时 15 毫秒
1.
A novel solid-phase microextraction coating of phosphorous-containing titanium oxide composite was developed using titanium fiber as a support and a titanium source by hydrothermal oxidation in a phosphoric acid solution containing hydrogen peroxide. The morphology of the fiber coatings was controlled by the conditions of the hydrothermal oxidation reaction. The oriented nanofiber coating was employed to extract several types of representative aromatic analytes. The experimental results demonstrated that the as-prepared fiber exhibited excellent extraction efficiency toward polycyclic aromatic hydrocarbons. Combined with high-performance liquid chromatography with ultraviolet detection, main extraction conditions were optimized, including pH, ionic strength, extraction temperature, stirring rate, extraction time and desorption time. The established method presented good linearity from 0.05 to 200 μg/L with limit of detection ranging from 0.012 to 0.126 μg/L. This convenient and green procedure was suitable for the selective extraction and determination of typical polycyclic aromatic hydrocarbons in environmental water samples. The relative recoveries of 85.8–112% were obtained for the determination of target polycyclic aromatic hydrocarbons in water samples spiked with 5.0 and 15.0 μg/L. Moreover, the as-prepared fiber showed at least 210 extraction/desorption cycles due to its high mechanical and chemical stability.  相似文献   
2.
Efficient conversion of lignin to aromatic hydrocarbons via depolymerization and subsequent hydrodeoxygenation is important. Previously, we found that NbOx species played a key role in the activation and cleavage of C–O bonds in lignin and its model compounds. In this study, commercial niobic acid (HY-340), niobium phosphate (NbPO-CBMM) and lab-made layered niobium oxide (Nb2O5-Layer) were chosen as supports to study the effect of Brönsted and Lewis acids on the activation of C–O bonds in lignin conversion. A variety of Ru-loaded, Nb-based catalysts with different Ru particle sizes were prepared and applied to the conversion of p-cresol. The results show that all the Ru/Nb-based catalysts produce high mole yields of C7–C9 hydrocarbons (82.3–99.1%). What's more, Ru/Nb2O5-Layer affords the best mole yield of C7–C9 hydrocarbons and selectivity for C7–C9 aromatic hydrocarbons, of up to 99.1% and 88.0%, respectively. Moreover, it was found that Lewis acid sites play important roles in the depolymerization of enzymatic lignin into phenolic monomers and the cleavage of the C–O bond of phenols. Additionally, the electronic state and particle size of Ru are significant factors which influence the selectivity for aromatic hydrocarbons. A partial positive charge on the metallic Ru surface and a smaller Ru particle size are beneficial in improving the selectivity for aromatic hydrocarbons.  相似文献   
3.
为了揭示中墩斜支承对连续箱梁力学性能的影响,本文考虑约束扭转和竖向挠曲耦合作用,建立了斜支承连续箱梁的力法方程,并获得了内力和变形的解析式。选取斜支承两跨连续箱梁为数值算例,分别计算了竖向对称和偏心均布荷载作用下的内力和变形,并用ANSYS软件计算了控制截面的弯矩。计算结果表明,本文方法计算的弯矩与ANSYS计算值吻合良好;与常规的连续箱梁相比,在竖向对称均布荷载作用下,斜支承连续箱梁的挠度减小不显著,而在竖向偏心均布荷载作用下,斜支承连续箱梁的挠度有显著变化,斜交角为45°时,挠度改变量可达到25%以上;无论是在竖向对称还是偏心均布荷载作用下,斜支承连续箱梁的扭转角均大于常规连续箱梁的扭转角,二次扭矩和双力矩都仅在斜支承点附近的局部范围出现较大值。  相似文献   
4.
In order to improve the performance and durability of polymer electrolyte fuel cells (PEFCs), various improvements in the microstructures of cathode catalyst layers (CLs) were initiated in the early 1990s. More recent advances in CL materials are highlighted, including carbon supports for improved accessibility of Pt nanoparticles (NPs), adsorption of ionomer on the Pt surface, high-oxygen-permeability ionomers, corrosion resistance of mesoporous and microporous carbons, and conductive ceramic supports with a fused-aggregate network structure. These approaches are summarized as stepwise improvements. The influences of the support structure on the distribution of Pt NPs and ionomer are reviewed, as well as their effects on performance and durability. These approaches for carbon supports are extended to conductive ceramic supports and the unique advantages are discussed.  相似文献   
5.
周伟兵  郝育新 《力学季刊》2021,42(4):718-730
双稳态层合板作为一种柔性可变体结构,为实现振动状态下的构型调控,将对其开展固有振动特性的 研究.本文以四角点简支约束的矩形非对称铺设双稳态板作为研究对象,运用最小势能原理、一阶剪切变形理 论、以及冯卡门几何非线性位移应变关系,得到双稳态板的两种稳态构型.首次给出了适合于四点简支的6参 数构型函数与17参数构型函数,研究对比发现对于稳态构型采用17参数的构型函数结果相对更精确;对于应 用线性位移应变关系的基于任一稳态构型下振动固有特性而言,这两种构型函数得到的结果基频相差2 %,其 它阶次频率相差也不大.随后采用6参数构型函数得到的稳态构型研究了几何尺寸、铺层数分别对两种稳态构 型固有振动特性的影响.本研究对于进一步研究该类结构动态跳变机理具有重要意义.  相似文献   
6.
Magnetic hyperthermia (MH) shows great potential in clinical applications because of its very localized action and minimal side effects. Because of their high saturation magnetization values, reduced forms of iron are promising candidates for MH. However, they must be protected in order to overcome their toxicity and instability (i. e., oxidation) under biological conditions. In this work, a novel methodology for the protection of iron nanoparticles through confinement within graphitic carbon layers after thermal treatment of preformed nanoparticles supported on carbon is reported. We demonstrate that the size and composition of the nascent confined iron nanoparticles, as well as the thickness of their protective carbon layer can be controlled by selecting the nature of the carbon support. Our findings reveal that a higher nanoparticle–carbon interaction, mediated by the presence of oxygen-containing groups, induces the formation of small and well-protected α-Fe-based nanoparticles that exhibit promising results towards MH based on their enhanced specific absorption rate values.  相似文献   
7.
利用试验及数值模拟技术研究了ITER 极向场磁体支撑U 型韧性夹的焊接变形规律,模拟和实际测量的比较验证了模拟的准确性,从而得到了U 型夹焊缝变形的基本规律,并改进现有夹具类型。基于验证好的热力边界条件以及优化的夹具,对三种焊接方案的U 型韧性夹的焊接变形进行了计算,从而提出了极向场磁体支撑制造的优化方案。优化后的焊接方案将焊接变形控制在0.6mm 以内。  相似文献   
8.
传统的基于关联规则的挖掘算法采用的是统一的最小支持度,但是在实际的事务数据库中数据项的重要性是不同的。针对目前多支持度和增量式关联规则更新维护的局限性,提出一种基于多支持度的增量式关联规则挖掘算法。允许用户根据不同项的重要性设置权值,有利于发现更多有趣的规则。采用矩阵的向量内积策略,结合动态剪枝,无需多次扫描事务数据库,不生成庞大候选集。实验结果验证了算法的有效性。  相似文献   
9.
Significant progress has been made in the last few years toward synthesizing highly dispersible inorganic catalysts for application in the electrodes of direct methanol fuel cells. In addition, research toward achieving an efficient catalyst supporting matrix has also attracted much attention in recent years. Carbon black- (Vulcan XC-72) supported Platinum and Platinum-Ruthenium catalysts have for long served as the conventional choice as the cathode and the anode catalyst materials, respectively. Oxygen reduction reaction at the cathode and methanol oxidation reaction at the anode occur simultaneously during the operation of a direct methanol fuel cell. However, inefficiencies in these reactions result in a generation of mixed potential. This, in turn, gives rise to reduced cell voltage, increased oxygen stoichiometric ratio, and generation of additional water that is responsible for water flooding in the cathode chamber. In addition, the lack of long-term stability of Pt-Ru anode catalyst, coupled with the tendency of Ru to cross through the polymer electrolyte membrane and eventually get deposited on the cathode, is also a serious drawback. Another source of potential concern is the fact that the natural resource of Pt and the rare earth metal Ru is very limited, and has been predicted to become exhausted very soon. To overcome these problems, new catalyst systems with high methanol tolerance and higher catalytic activity than Pt need to be developed. In addition, the catalyst-supporting matrix is also witnessing a change from traditionally used carbon powder to transition metal carbides and other high-performance materials. This article surveys the recent literature based on the advancements made in the field of highly dispersible inorganic catalysts for application in direct methanol fuel cells, as well as the progress made in the area of catalyst-supporting matrices.  相似文献   
10.
吴奎  邵珠山  秦溯 《力学学报》2020,52(3):890-900
高地应力深埋软岩隧道大变形问题已成为隧道工程建设领域的突出难题. 根据高地应力深埋软岩隧道的变形特征, 基于"围岩能量吸收、变形释放"的让压支护是解决软岩隧道大变形问题的有效方法. 针对流变岩体中深埋圆形隧道在让压支护作用下的力学响应问题, 通过引入分数阶微积分理论, 采用Abel黏壶元件建立了改进的分数阶Burgers蠕变模型来表征围岩的时效变形. 此外, 通过在让压支护不同变形阶段引入刚度修正系数, 克服了传统支护未能考虑围岩变形释放的问题. 据此, 本文推导了在考虑支护延迟安装影响下, 不同变形阶段围岩与让压支护相互作用的解析解. 为了验证理论研究的正确性, 对一算例进行了不同解答及工程结果的比对, 吻合较好. 最后, 参数研究结果表明: 围岩与让压支护间的相互作用受蠕变本构模型分数阶阶数影响较大. 隧道的位移或支护压力与让压位移、支护刚度修正系数间存在线性比例关系, 但由于刚度修正系数仅保持在较小的变化范围内, 隧道的位移或支护压力变化并不显著.   相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号