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Comparison of monomethoxy‐, dimethoxy‐, and trimethoxysilane anchor groups for surface‐initiated RAFT polymerization from silica surfaces 下载免费PDF全文
Dennis Huebner Vanessa Koch Bastian Ebeling Jannik Mechau Judith Elisabeth Steinhoff Philipp Vana 《Journal of polymer science. Part A, Polymer chemistry》2015,53(1):103-113
The immobilization of reversible addition–fragmentation chain transfer (RAFT) agents on silica for surface‐initiated RAFT polymerizations (SI‐RAFT) via the Z‐group approach was studied systematically in dependence of the functionality of the RAFT‐agent anchor group. Monoalkoxy‐, dialkoxy‐, and trialkoxy silyl ether groups were incorporated into trithiocarbonate‐type RAFT agents and bound to planar silica surfaces as well as to silica nanoparticles. The immobilization efficiency and the structure of the bound RAFT‐agent film varied strongly in dependence of the used solvent (toluene vs. 1,2‐dimethoxyethane) and the anchor group functionality, as evidenced by atomic force microscopy, transmission electron microscopy, dynamic light scattering, and UV/Vis spectroscopy. Surface‐initiated RAFT polymerizations using functionalized silica nanoparticles revealed that grafted oligomers, which often occur in SI‐RAFT, are not formed within the crosslinked structures that originate from the immobilization, and that RAFT‐agent films that show less aggregation during the immobilization are more efficient during SI‐RAFT in terms of polymer grafting density. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 103–113 相似文献
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针对架空输电线路铁塔中常用的四地脚螺栓塔脚板进行了抗拉承载力试验和理论计算方法研究。首先,选取8个试件进行塔脚板抗拉承载力试验研究,分析塔脚底板板厚及有无加劲板对塔脚板抗拉承载力的影响;其次,通过有限元模拟塔脚板的应力分布情况,并结合“塑性分析,弹性设计”的思想,提出了一种基于屈服线理论的四地脚螺栓塔脚板抗拉承载力计算公式;最后,与试验结果、有限元仿真结果、已有技术规定中的计算结果进行了对比。结果表明:建议公式与试验结果和仿真结果较为吻合,相关技术规定中的计算结果偏于保守,验证了本文建议公式的精确性;底板厚度和加劲板的作用对塔脚板承载力影响较大。研究结果可为输电铁塔四地脚螺栓塔脚板结构设计提供参考。 相似文献
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为了进一步改善超声喷丸强化质量,提升工件表面残余应力和显微硬度的均匀性,对压电振子阵列型超声喷丸强化加工系统进行了改进,提出了在强化加工过程中辅助工件往复运动的方法。对改进后的压电振子阵列型超声喷丸强化加工原理进行了阐述,分析了激振片的振动特性并进行了结构尺寸优化,应用Abaqus对工件往复运动下超声喷丸强化过程进行了仿真研究,分析了在不同的工件往复运动频率下,工件表面残余应力分布情况。实验测试了在不同喷丸强化时间及工件往复运动频率下超声喷丸强化加工质量,探究了喷丸时间和工件往复运动频率对工件表面显微硬度的影响。结果表明:在压电振子阵列型超声喷丸强化过程中辅助工件往返运动,可以有效提高工件表面残余应力和显微硬度分布的均匀性,工件表面强化质量得到提升。 相似文献
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???????????????????????????о? 总被引:6,自引:0,他引:6
利用模拟装置实现了卡瓦与套管在地面上的实验,使用电测的方法测量胀卡时套管外表面的应变.由实验数据获得计算网格节点处的应变,同时利用单位咬合力作用套管的有限元结果进行数值法计算,获得卡瓦各咬合齿对套管咬合力的分布,为卡瓦的优化设计提供了可靠数据. 相似文献
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We study the full counting statistics of transport electrons through a semiconductor two-level quantum dot with Rashba spin–orbit (SO) coupling, which acts as a nonabelian gauge field and thus induces the electron transition between two levels along with the spin flip. By means of the quantum master equation approach, shot noise and skewness are obtained at finite temperature with two-body Coulomb interaction. We particularly demonstrate the crucial effect of SO coupling on the super-Poissonian fluctuation of transport electrons, in terms of which the SO coupling can be probed by the zero-frequency cumulants. While the charge currents are not sensitive to the SO coupling. 相似文献
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Rene F. Roller Ankita Malik Maria A. Carillo Monika Garg Antonella Rella Marie‐Kristin Raulf Bernd Lepenies Peter H. Seeberger Daniel Varn Silva 《Angewandte Chemie (International ed. in English)》2020,59(29):12035-12040
Glypiation is a common posttranslational modification of eukaryotic proteins involving the attachment of a glycosylphosphatidylinositol (GPI) glycolipid. GPIs contain a conserved phosphoglycan that is modified in a cell‐ and tissue‐specific manner. GPI complexity suggests roles in biological processes and effects on the attached protein, but the difficulties to get homogeneous material have hindered studies. We disclose a one‐pot intein‐mediated ligation (OPL) to obtain GPI‐anchored proteins. The strategy enables the glypiation of folded and denatured proteins with a natural linkage to the glycolipid. Using the strategy, glypiated eGFP, Thy1, and the Plasmodium berghei protein MSP119 were prepared. Glypiation did not alter the structure of eGFP and MSP119 proteins in solution, but it induced a strong pro‐inflammatory response in vitro. The strategy provides access to glypiated proteins to elucidate the activity of this modification and for use as vaccine candidates against parasitic infections. 相似文献
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