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The effect of pH and associated ionic strength on the primary yields in the radiolysis of pressurised water has been assessed by diffusion-kinetic calculations for temperatures in the range 100–300°C. Account has been taken for ionic strength I up to 0.1 mol kg−1, assuming that the counter ions of H+ in acid solutions and of OH in base solutions have unit charge. In acid solutions, the H+ ions react with e aq. The decrease in G(e aq) and the increase in G(H) with decreasing pH becomes substantial for [H+] ≥ 1 × 10−4 m, but the primary yields of oxidising species are almost constant. In alkaline solutions, the OH anions affect the spur chemistry of radiation-generated protons and hydroxyl radicals for [OH] ≥ 1 × 10−4 m. The scavenging of H atoms and hydrogen peroxide becomes significant for [OH] ≥ 1 × 10−2 m. The total yields G(OH) + G(O) and G(H2O2) + G(HO2 ) are independent of base concentration below 0.01 m. In more alkaline solutions, G(OH) + G(O) increases, whereas G(H2O2) + G(HO2 ) decreases with increasing [OH]. Calculations showed the substantial yield of the reaction O + e aq in 0.1 m base solution. Spur chemistry in alkaline hydrogenated water is not affected by the presence of H2 if less than 0.001 m of hydrogen is added.  相似文献   
2.
This article presents an idea to remove the inequality in maximum fillet stresses developed between pinion and gear of a step up gear drive. This uniform fillet strength of the gear drive can be achieved by using nonstandard pinion and gear with appropriate addendum modifications generated by nonstandard basic racks of respective tooth thickness not equal to 0.5πm at the pitch circle. The influence of gear parameters such as gear ratio, pressure angle, addendum factor, pinion teeth number, and addendum modifications on the maximum fillet stress on the nonstandard pinion and gears of different tooth thickness has been analyzed through finite element method and finally the optimum value of rack tooth thickness coefficients (k pc and k gc ) are suggested for the given gear drive (defined by i) that improves the fillet capacity in bending. This study has been extended for various drives like S std , S o , S +, and S ? drives.  相似文献   
3.
The behavior of the copolymer poly(ethylene-co-vinyl acetate), with different amounts of vinyl acetate (VA) (2, 4.5, 9 and 19 w/w%, respectively), has been studied by performing positron lifetime measurements as a function of temperature. An overall reduction of the ortho-positronium formation probability I3 with increasing VA content is observed. The copolymers with 2, 4.5 and 9 w/w% VA show a V-shaped I3 evolution with temperature, caused by positron irradiation induced ionization, whereas the copolymer with 19 w/w% VA has become practically inert to self-irradiation effects.  相似文献   
4.
局部冲刷的三维数值模拟可预测水力冲刷的破坏程度和破坏机制,进而提供更加合理的工程措施以减轻或避免局部冲刷造成的工程破坏。基于有限体积法和非结构化的计算网格构建了以水动力学模型、泥沙冲淤和河床变形方程为基础的三维局部冲刷数值模型。水动力学模型中的湍流模型为剪切应力SST k-ω输运模型,泥沙冲淤以底床切应力大小和分布为基础,水沙模型的耦合采用单向弱耦合方式。首先,通过ANSYS-FLUENT软件数值计算水动力学模型后,将水力特性数据单向传递至泥沙模块,并应用UDF函数二次开发实现泥沙模型的数值计算。利用动网格技术重构因河床地形更新引起的变形网格。与动床圆柱冲刷和丁坝局部冲刷的试验结果进行比较,验证了局部冲刷数值模型的可靠性。从平衡冲深时的冲刷深度和冲坑内水流特性等结果的对比可以看出,该数值模型成功地模拟出最终冲刷地形和形态,并能捕捉不同时刻的三维地形变化。根据数值模型的建立及应用结果分析主要得到以下结论,以切应力观点为基础开发该模型时,具有简易性和较强的可靠性;单元体泥沙通量的重构和床面坡度等因素均影响模型的精度;FLUENT软件提供的动网格技术能较好重构小变形网格,但是重构因地形变化引起的大变形网格时略显不足。  相似文献   
5.
The available sources and procedures for determination of AGMA geometry factor J are tables, charts and semi-analytical methods. When computerized gear design is considered, usage of tables requires a number of interpolations; usage of charts requires curve fitting; and usage of semi-analytical methods needs a numerical algorithm and may have convergence problems. As an alternative to these, polynomial equations for direct calculation of AGMA geometry factor J are derived for external spur gears. Thus, it is made possible to evaluate the J factor easily and with minimum process time. J factors are determined being independent of the highest point of single tooth contact (HPSTC). Derived equations can be used to calculate the tooth root stresses corresponding to loads acting on any point on the involute tooth profile. Thus, cases where the center distance is increased for providing backlash or for operating the gears at a desired exact center distance can easily be handled by determining the corresponding new HPSTC. A computer program is developed to demonstrate the usage of the derived equations. The method can also be used for determination of the J factors for gears with non-standard proportions.  相似文献   
6.
丁坝结构广泛应用于水利工程中,用以调整水流和护滩固堤,维护优良的水道通航条件。针对单丁坝局部水流,基于非结构网格,采用有限体积法(FVM ),建立了三维自由表面水流模型,湍流模型采用S‐A一方程模型。针对非淹没、正挑单丁坝,开展了系列 Fr数条件下的水流模拟。重点分析丁坝局部流动结构,探讨丁坝坝根处局部涡系演化等特征,研究了丁坝下游回流区长度和宽度的变化,总结了丁坝引起的剪切流的沿程变化特征。  相似文献   
7.
In this paper the philosophy of mathematical phenomenological mapping has been applied to the non-linear dynamics of spur gears and radial ball bearings. The spur gear pair dynamics and rolling element bearing dynamics are analyzed separately, but with a tendency to reduce the both of the systems to the same mathematical model. The different reasonable assumptions are taken in every of these analyzes, but they do not have significant influence to the accuracy of the results. The systems are reduced to the single degree of freedom dynamics model. The total gear stiffness and ball bearing stiffness are recognized as the main influent factor of vibration behavior of these machine elements. Therefore, the special attention was paid to the new approach and procedure for stiffness solving and related problems. A single spur gear pair dynamics is solved and the results for total gear stiffness and vibration are shown. The conclusions emphasize the importance of described parallel analyzes in order to reduce the calculation time in solving different phenomena with usage of the principle of mathematical phenomenology.  相似文献   
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