人教版高中化学教科书“研究与实践”栏目分析与实施策略*

对人教版高中化学教科书新设计的“研究与实践”栏目的主题内容、功能价值进行分析,就如何充分发挥该栏目的教学功能和价值,发展学生的化学学科核心素养,提出了创设教学情境线索、开发为研究性学习课题、开发为校本选修课程、开发为STEM课程等实施策略。     

Experimental and theoretical investigation of CO2 and air bubble rising velocity through kerosene and distilled water in bubble column

This paper concerns with developing of parameters which influence terminal velocities of air and CO₂ bubbles in distilled water and kerosene pools. The objective of this study is to validate and correct the formulas that were developed by previous investigators for prediction of terminal velocities. The investigation revealed that the terminal velocity of a single rigid spherical bubble in Newtonian fluids can be developed by balancing of mechanical forces acting on the bubble. However, for large bubbles, because of deforming of the bubble which is a result of interfacial tension, the effect of surface tension should be considered in the terminal velocity prediction formula. By using PSO algorithm and plotting experimental data of terminal velocity against the size of gas bubbles, the suitable equation for each of systems was chosen. Results showed that Jamialahmadi model is more practical for terminal velocity prediction. Jamialahmadi model requires a modification to be utilized for air-kerosene, CO₂-kerosene, air- distilled water and CO₂-distilled water systems. The developed PSO algorithm model is accurate for prediction of experimental data with an average R² value of 0.9722.     

基于概率加权共轭梯度算法的混凝土超声波层析成像

在混凝土层析成像中,为了提高反演的准确性和计算效率,针对共轭梯度算法提出一种加权算法——概率加权共轭梯度算法.新算法不同于常规的加权算法,权重是加在成像单元上而不是方程上.为取得较好的权重因子和较好的迭代初始值,采用IART算法的权重和迭代初始值的选取方法.模拟算例和混凝土试验均表明这种加权算法的可行性.     

Guidelines for tuning the macropore structure of monolithic columns for high‐performance liquid chromatography

The ability to control the external porosity and to tune the dimensions of the macropore size on multiple length scales provides the possibility of tailoring the monolithic support structure towards separation performance. This paper discusses the properties of conventional polymer–monolithic stationary phases and its limitations regarding the effects of morphology on kinetic performance. Furthermore, guidelines to improve the macropore structure are discussed. The optimal monolithic macropore structure is characterized by high external porosity (while maintaining ultra‐high‐pressure stability), high structure homogeneity, polymer globule clusters in the submicron range, and macropores with a diameter tuned toward speed (small diameter in the 100–500 nm range using short beds) or efficiency (larger macropores in the range of 500 nm–1 μm allowing the use of longer column formats). Finally, promising approaches to control the morphology are discussed.     

冻融循环周次对陶粒混凝土动态力学性能影响的实验研究

为了研究冻融循环周次对陶粒混凝土动态力学性能的影响,对含有页岩陶粒体积分数为0%、15%、30%、45%的陶粒混凝土试样分别进行0、10、20、30和40次的冻融循环后SHPB动态压缩实验.实验表明:陶粒混凝土的动态力学性能随着冻融循环周次增加而弱化,动态压缩强度随着应变率的增加而增大,并给出了冻融循环周次对陶粒混凝土动态压缩强度的变化规律.     

D3h‐Symmetric Porphyrin‐Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One‐Nanometer‐Sized Cavity

The one‐step synthesis of D_3h‐symmetric cyclic porphyrin trimers 1 composed of three 2,2′‐[4,4′‐bis(methoxycarbonyl)]bipyridyl moieties and three porphyrinatozinc moieties was achieved from a nickel‐mediated reductive coupling of meso‐5,15‐bis(6‐chloro‐4‐methoxycarbonylpyrid‐2‐yl)porphyrinatozinc. Although cyclic trimers 1 were obtained as a mixture that included other cyclic and acyclic porphyrin oligomers, an extremely specific separation was observed only for cyclic trimers 1 when using columns of silica gel modified with pyrenylethyl, cyanopropyl, and other groups. Structural analysis of cyclic trimers 1 was carried out by means of NMR spectroscopy and X‐ray crystallography. Treatment of an η³‐allylpalladium complex with a cyclic trimer gave a tris(palladium) complex containing three η³‐allylpalladium groups inside the space, which indicated that the bipyridyl moieties inside the ring could work as bidentate metalloligands.     

冻融循环作用下再生混凝土砖砌体通缝受剪试验研究

本文报导了对冻融循环作用下96个再生混凝土砖砌体抗剪试件进行的沿通缝抗剪试验。研究涉及冻融循环对再生混凝土砖砌体抗剪力学性能的影响,对比分析不同胶结材料试件的破坏形态及其抗剪强度,揭示冻融损伤对再生混凝土砖砌体抗剪强度的影响规律,并从微观角度探讨砂浆孔隙变化对砖砌体抗剪承载力的影响,建立再生混凝土砖砌体抗剪强度冻融损伤衰减模型。结果表明:砖砌体抗剪强度受冻融环境影响非常明显,其抗剪强度随冻融循环次数的增加而降低,降低的速度呈现出先慢后快的趋势;粉煤灰的加入有助于改善冻融环境下砖砌体的抗剪能力;对于石灰砂浆抗剪试件,初期的抗剪能力及冻融后的抗剪能力均下降;建立了考虑冻融损伤影响的砖砌体抗剪强度衰减模型,试验数据与计算结果吻合较好。     

Atomic force microscopy study of polypropylene-based self-reinforced composites

Self-reinforced composites are polymeric materials formed by a reinforcement core and a low-melting point skin, which acts as a matrix after the consolidation step. These materials are widely exploited in industrial applications for their mechanical resistance and durability, which are themselves influenced by processing conditions and polymer composition. In the present work, two similar polypropylene-based commercial fabrics were used to evaluate the surface modifications after laminate compaction and after artificial aging using atomic force microscopy. The results were correlated with the chemical and physical-chemical interactions obtained from scanning electron microscopy, transmission electron microscopy, raman and thermal analysis experiments. Single tape consolidated laminate before and after aging displayed different superficial features that can explain the differences in the macroscopic behavior of the two products.     

考虑塑性变形发展程度系数的RC梁开裂弯矩改进计算公式

针对RC梁开裂荷载计算方法尚未统一的现状，首先，结合18根RC梁试验数据对比了已有的6种RC梁开裂弯矩计算公式，发现开裂弯矩理论计算值与试验值的偏差大小和混凝土强度有关；然后，通过提出塑性变形发展程度系数k，推导新的RC梁开裂弯矩计算公式，并进一步基于k值和塑性影响系数计算值γ_k进行改进；最后，选取12根RC试验梁验证改进公式的准确性，证明改进公式的计算值与试验值吻合更好且偏于安全。     

Study of γ‐Fast Neutron Attenuation and Mechanical Characteristics of Modified Concretes for Shielding and Sheltering Purposes

The study of γ‐neutrons attenuation and mechanical characteristics of modified concrete are vital and crucial parameters for the construction of civilian radiological, nuclear shielding, and/or shelters. In this work, fifteen samples of ordinary concretes with five different additives; steel fibers, polypropylene, silica fume, and fly ash, with variation of cement percentages, were prepared and used for performing the mechanical and radiation attenuation investigations. The compressive strength, tensile strength, slump test, bulk density, and water permeability were also carried out for the prepared concrete mixes. Collimated coherent beams from ⁶⁰Co and Pu‐Be fast neutron sources were used to check the radiation penetrability through the syntheized mixed concrete‐additives. Very sensitive and well calibrated gamma‐neutron pulse shape discriminating spectrometer with its electronic componenets and stilbene organic detector and 3′′ × 3′′ NaI scintillation crystal was used to measure the radiation before and after attenuation and transmission. The integrated fast neutron removal macroscopic cross section (Σ_r) and linear attenuation coefficient of total gamma rays (μ) were calculated for all the analysed concrete mixes. The results of measurements, tests, analyses and calculations are given and explained. The investigated modified concrete mixes show good workability and properties from the view point of mechanical loads and γ‐fast neutrons penetrability and resistance. These results can be used for shielding and sheltering design.