Experimental study and numerical modeling of brittle fracture of carbonate rock under uniaxial compression

The brittle carbonate rock taken from the Tarim Oilfield is tested in laboratory under uniaxial compression. The acoustic emission (AE) is used to monitor the microcracking activity in rock during the experiment. Moreover, the 3D tomograms of carbonate rock after uniaxial compression are obtained by using CT imaging technology, which indicates that microcracks mutually interconnect and eventually form macroscopic fractures after failure. The PFC2D is used to model the behavior of brittle rock including microcracks propagation. The stress–strain curve and cracks distribution in rock model are obtained from the PFC simulation. The numerical results agree with the experimental test well.     

Determining the role of the underlying orbital‐dependence of PBE0‐DH and PBE‐QIDH double‐hybrid density functionals

We study the orbital‐dependence of three (parameter‐free) double‐hybrid density functionals, namely the PBE0‐DH, the PBE‐QIDH models, and the SOS1‐PBE‐QIDH spin‐opposite‐scaled variant of the latter. To do it, we feed all their energy terms with different sets of orbitals obtained previously from self‐consistent density functional theory calculations using several exchange‐correlation functionals (e.g., PBE, PBE0, PBEH&H), or directly with HF‐PBE orbitals, to see their effect on selected datasets for atomization and reaction energies, the latter proned to marked self‐interaction errors. We find that the PBE‐QIDH double‐hybrid model shows a great consistency, as the best results are always obtained for the set of orbitals corresponding to its hybrid scheme, which prompts us to recommend this model without any other fitting or reparameterization. © 2017 Wiley Periodicals, Inc.     

闪长岩单轴加载过程中声发射和弹性波速度变化规律的研究

为研究闪长岩在单轴加载过程中的声发射和各向波速变化规律,在单轴阶段加载和循环阶段加载条件下,对闪长岩岩样破裂过程中的声发射累计数、不同应力水平不同方向的波速、切线模量、轴向应变速率进行了研究。实验结果表明:(1)随着应力水平的增高,声发射事件数不断增加,在高应力水平(约80%峰值强度)时,声发射累计数急剧增多,随后切线模量出现震荡变化。(2)在加载过程中,压密程度及裂纹扩展方向对波速产生了巨大的影响,导致不同方向波速在不同的应力水平呈现出不同的变化规律,由此可以推测破裂面位置和破裂模式。在较高应力水平下(约60%峰值强度),平行于加载方向的波速趋于稳定,而垂直于加载方向的波速则持续下降,故用垂直于加载方向传播的波速预测岩石的破坏更具可靠性。(3)随着应力的增加,应变速率有逐渐减小的趋势,但临近岩石破裂时无异常变化出现,说明利用变形观测难以预测此类岩石的破坏。以上研究表明,根据纵波波速、声发射累计数和切线模量的变化可以有效预测岩石的破坏。     

纸页受力微损伤演化过程的声发射及多元统计特征

纸页受载后的损伤断裂行为涉及其使用性能,对其损伤断裂过程的研究不仅有助于揭示纸页破坏行为的物理本质,而且有助于对纸页质量及其生产、加工工艺作出更加科学合理的评定。本文基于声发射(Acoustic Emission,AE)实验研究纸页内部微损伤演化过程,给出了评估纸页宏观损伤断裂性能的定量描述方法。首先,根据AE信号与微损伤事件之间存在本质上的关联性,通过采集和观测纸页试样受载过程中的AE信号来研究纸页损伤断裂的基本特征;其次,针对所采集AE信号的数据量大、蕴含信息丰富导致数据分析和处理困难的特点,本文采用多元随机变量的分析方法。利用概率熵和Andrews曲线法等统计分析手段对AE数据展开研究分析,并最终利用一条损伤状态轨迹曲线实现了对纸页微损伤演化过程的完整宏观描述。结果表明,纸页微损伤演化过程呈现明显阶段性变化特征;Andrews曲线的聚类结果有效地区分了不同损伤阶段的相似性和差异性,同时,不同损伤阶段中纸样的微观形貌观测提供了实验性的证据。本文以一种典型的牛皮箱板纸为试件,验证了上述方法的有效性。     

Construction of AE ring system for the C19-diterpenoid alkaloids with a 5β-hydroxyl group

An AE azabicyclic fragment, with a β-hydroxyl group at C-5 and a substituent at C-1, of the C₁₉-diterpenoid alkaloids, was synthesized. The key reactions include an intramolecular Claisen-type condensation, double Mannich reaction, and stereoselective nucleophilic addition of carbonyl group with the assistance of steric effect of 1β-substituent.     

高径比对砂岩单轴压缩声发射特性的影响研究

岩石尺寸效应对声发射特性的影响对于利用声发射技术监测岩石失稳破坏具有重要的实践意义。本文选择不同高径比的长石细砂岩试样开展单轴压缩声发射试验,探讨尺寸效应对岩石声发射事件数、振铃计数、峰值频率等声发射特性参数的影响。研究结果表明:根据岩石试件撞击数的增长速率,将试件破坏阶段分为突变期、平静期、爆发期三个阶段,随着岩石试件高径比增加,声发射的撞击数相应增加,增加趋势与试件高径比的增加呈近似线性相关关系;随着岩石试件高径比的减小,振铃计数突变期时间占比相应减小,平静期振铃计数也相应减小;岩石试件的加载破坏的峰值频率主要呈现高频和低频两个集中分布区,随着高径比减小,岩石试件加载破坏的峰值频率逐渐由低频区向高频区过渡,同时峰值频率的离散性也在增加。试验成果丰富了岩石声发射特性的基础数据,并可为实际工程中声发射技术的实践应用提供参考。     

An experimental study on fracture mechanical behavior of rock-like materials containing two unparallel fissures under uniaxial compression

Strength and deformability characteristics of rock with pre-existing fissures are governed by cracking behavior. To further research the effects of pre-existing fissures on the mechanical properties and crack coalescence process, a series of uniaxial compression tests were carried out for rock-like material with two unparallel fissures.In the present study, cement, quartz sand, and water were used to fabricate a kind of brittle rock-like material cylindrical model specimen. The mechanical properties of rock-like material specimen used in this research were all in good agreement with the brittle rock materials. Two unparallel fissures(a horizontal fissure and an inclined fissure) were created by inserting steel during molding the model specimen.Then all the pre-fissured rock-like specimens were tested under uniaxial compression by a rock mechanics servocontrolled testing system. The peak strength and Young's modulus of pre-fissured specimen all first decreased and then increased when the fissure angle increased from 0?to 75?.In order to investigate the crack initiation, propagation and coalescence process, photographic monitoring was adopted to capture images during the entire deformation process.Moreover, acoustic emission(AE) monitoring technique was also used to obtain the AE evolution characteristic of prefissured specimen. The relationship between axial stress, AE events, and the crack coalescence process was set up: when a new crack was initiated or a crack coalescence occurred, thecorresponding axial stress dropped in the axial stress–time curve and a big AE event could be observed simultaneously.Finally, the mechanism of crack propagation under microscopic observation was discussed. These experimental results are expected to increase the understanding of the strength failure behavior and the cracking mechanism of rock containing unparallel fissures.     

Facile synthesis of 2-(substituted amino)-4<Emphasis Type="Italic">H</Emphasis>-thieno[3,2-<Emphasis Type="Italic">e</Emphasis>]-1,3-thiazin-4-ones

Interaction between 2,5-dichlorothiophene-3-carbonyl isothiocyanate, accessible via 2,5-dichlorothiophene-3-carbonyl chloride, and model heterocyclic amines produced the respective 2,5-dichloro-N-(substituted aminocarbonothioyl)thiophene-3-carboxamides. Upon heating, the deprotonated form of the latter underwent intramolecular cyclization to deliver the corresponding 2-(substituted amino)-4H-thieno[3,2-e]-1,3-thiazin-4-ones. The structures of these new bicyclic derivatives and their acyclic precursors are based on microanalytical and spectral (IR, MS, and NMR) data. Correspondence: Rajab Abu-El-Halawa, Chemistry Department, Faculty of Science, Al al-Bayt University, Mafraq, Jordan.     

光纤Sagnac传感器对材料频率特性的实验研究

不同的材料由于物理性质不同,在断裂时会产生不尽相同的声发射信号。光纤声发射传感器以其频带宽,抗电磁干扰,灵敏度高,体积小等优点在声发射（AE）信号探测方面有着广泛的应用前景。本文采用光纤Sangac传感器,对不同材料断裂过程的声发射信号进行检测,通过快速傅立叶变换分析其频谱。实验得知同一种材料断裂的声发射信号具有相同的...