全文获取类型
收费全文 | 5004篇 |
免费 | 854篇 |
国内免费 | 549篇 |
专业分类
化学 | 3492篇 |
晶体学 | 49篇 |
力学 | 315篇 |
综合类 | 29篇 |
数学 | 593篇 |
物理学 | 1929篇 |
出版年
2024年 | 2篇 |
2023年 | 113篇 |
2022年 | 91篇 |
2021年 | 115篇 |
2020年 | 211篇 |
2019年 | 153篇 |
2018年 | 158篇 |
2017年 | 143篇 |
2016年 | 219篇 |
2015年 | 215篇 |
2014年 | 297篇 |
2013年 | 334篇 |
2012年 | 433篇 |
2011年 | 484篇 |
2010年 | 358篇 |
2009年 | 323篇 |
2008年 | 325篇 |
2007年 | 320篇 |
2006年 | 285篇 |
2005年 | 248篇 |
2004年 | 193篇 |
2003年 | 136篇 |
2002年 | 142篇 |
2001年 | 113篇 |
2000年 | 96篇 |
1999年 | 118篇 |
1998年 | 99篇 |
1997年 | 97篇 |
1996年 | 88篇 |
1995年 | 68篇 |
1994年 | 82篇 |
1993年 | 54篇 |
1992年 | 52篇 |
1991年 | 54篇 |
1990年 | 32篇 |
1989年 | 52篇 |
1988年 | 32篇 |
1987年 | 23篇 |
1986年 | 11篇 |
1985年 | 10篇 |
1984年 | 6篇 |
1983年 | 8篇 |
1982年 | 4篇 |
1981年 | 6篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有6407条查询结果,搜索用时 31 毫秒
1.
The authors consider the short time existence for Ricci-Bourguignon flow on manifolds with boundary. If the initial metric has constant mean curvature and satisfies some compatibility conditions, they show the short time existence of the Ricci-Bourguignon flow with constant mean curvature on the boundary. 相似文献
2.
Pu Lin Peifu Luo Yating Guo Honglong Qiu Min Wang Guoming Huang 《Particle & Particle Systems Characterization》2021,38(10):2100113
In this study, the synthesis of TaN nanosheets and their application in theranostic agents is reported. After coating polyethylene glycol (PEG) on the TaN nanosheets, the as-synthesized PEG-modified TaN nanosheets (TaN-PEG) show good stability and biocompatibility. Because of their high absorbance in the near-IR region, TaN-PEG can be utilized as photoacoustic imaging contrast agents for tumor imaging. Moreover, TaN-PEG has significant photothermal conversion performance, exhibiting effective laser-induced tumor ablation capability. The TaN-PEG possessing excellent photoacoustic contrast effect and photothermal properties thus have great promise in theranostic applications, especially imaging-guided cancer treatment. 相似文献
3.
In this paper, we develop a simplified hybrid weighted essentially non-oscillatory (WENO) method combined with the modified ghost fluid method (MGFM)
[31] to simulate the compressible two-medium flow problems. The MGFM can turn
the two-medium flow problems into two single-medium cases by defining the ghost
fluids state in terms of the predicted the interface state, which makes the material
interface “invisible”. For the single medium flow case, we adapt between the linear
upwind scheme and the WENO scheme automatically by identifying the regions of
the extreme points for the reconstruction polynomial as same as the hybrid WENO
scheme [55]. Instead of calculating their exact locations, we only need to know the
regions of the extreme points based on the zero point existence theorem, which is
simpler for implementation and saves computation time. Meanwhile, it still keeps
the robustness and has high efficiency. Extensive numerical results for both one
and two dimensional two-medium flow problems are performed to demonstrate the
good performances of the proposed method. 相似文献
4.
Daniel Chiew Judy Qiu Sirimon Treepongkaruna Jiping Yang Chenxiao Shi 《Entropy (Basel, Switzerland)》2021,23(4)
Yang and Qiu proposed and reframed an expected utility–entropy (EU-E) based decision model. Later on, a similar numerical representation for a risky choice was axiomatically developed by Luce et al. under the condition of segregation. Recently, we established a fund rating approach based on the EU-E decision model and Morningstar ratings. In this paper, we apply the approach to US mutual funds and construct portfolios using the best rating funds. Furthermore, we evaluate the performance of the fund ratings based on the EU-E decision model against Morningstar ratings by examining the performance of the three models in portfolio selection. The conclusions show that portfolios constructed using the ratings based on the EU-E models with moderate tradeoff coefficients perform better than those constructed using Morningstar. The conclusion is robust to different rebalancing intervals. 相似文献
5.
Yujie Gao Zhiye Qiu Lei Liu Mengmeng Li Bingjie Xu Dan Yu Dongming Qi Jindan Wu 《Journal of polymer science. Part A, Polymer chemistry》2022,60(15):2191-2212
Refractory wounds have always been an important issue to healthcare systems, whose healing process is always delayed by multiple factors, including bacterial infections, chronic inflammation, and excessive exudates, etc. Employing multifunctional wound dressings is recognized as an effective strategy to deal with refractory wounds, which has yielded promising outcomes in recent years. Among these advanced wound dressings, fibrous dressings have gained growing attention due to their unique merits. Such wound dressings have demonstrated great potential in delivering theranostic agents, such as antibacterial agents, anti-inflammatory drugs, growth factors, and diagnostic probes, etc., for the purposes of accelerating wound healing. This paper reviews the development of multifunctional fibrous dressings and their applications in treating refractory wounds. The construction approaches of novel fibrous dressing with capabilities of antibacterial, anti-inflammation, exudate management and diagnosis were also introduced. Furthermore, the existing problems and challenges are also discussed briefly. 相似文献
6.
Tian Jie Yang Weifeng Chen Min Zheng Minfang Chen Ding Qiu Yusheng 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(2):1039-1049
Journal of Radioanalytical and Nuclear Chemistry - This study presents a time-efficient method of analysing 210Pb, 210Bi, and 210Po in natural waters. The optimum pH (1.00), temperature... 相似文献
7.
本文采用基于多体格林函数方法和Bethe-Salpeter方程(GW/BSE)的电子结构计算方法和非绝热动力学模拟研究了两种不同桥连化学键构型(5-6构型和6-6构型)的酞菁锌-富勒烯(ZnPc-C60)给受体复合物的激发态性质及其弛豫过程. 对于6-6构型,ZnPc-C60的最低激发态S1态为光谱明态,即ZnPc的局域激发(LE)态,因此,6-6构型的ZnPc-C60在光激发之后几乎不会发生电荷分离过程. 相比之下,5-6构型的ZnPc-C60的S1态是C60的LE态,为光谱暗态,而作为光谱明态的ZnPc的LE态的能量更高. 而且,在ZnPc和C60的LE态之间还存在若干电荷转移(CT)态. 因此,电荷转移会在从高能的ZnPc的LE态到低能的C60的LE态的弛豫过程中发生. GW/BSE级别的非绝热动力学模拟结果进一步验证了电子结构计算的结论,并给出了相关过程的时间尺度:从ZnPc到C60的超快激发态能量转移过程在前200 fs完成;随后发生的是由C60到ZnPc的超快空穴转移过程. 本工作表明不同的桥连化学键模式(即5-6和6-6构型)可用于调节ZnPc-C60给体-受体复合物的激发态性质及其光电性质. 与此同时,本工作证明了GW/BSE级别的非绝热动力学方法是探索非周期性给体-受体复合物、有机金属配合物、量子点、纳米团簇等复杂体系的光诱导动力学的可靠工具. 相似文献
8.
Qianqian Fan Zirui Liu Feng Qiu Prof. Yong Mao Prof. Qingju Liu Prof. Longzhou Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(63):e202202700
The artificially accurate design of nonmetal electrocatalysts’ active site has been a huge challenge because no pure active species with the specific structure could be strictly controlled by traditional synthetic methods. Species with a multiconfiguration in the catalyst hinder identification of the active site and the subsequent comprehension of the reaction mechanism. We have developed a novel electro-assisted molecular assembly strategy to obtain a pure pentagon ring on perfect graphene avoiding other reconstructed structures. More importantly, the active atom was confirmed by the subtle passivation process as the topmost carbon atom. Recognition of the carbon-defect electrocatalysis reaction mechanism was first downsized to the single-atom scale from the experimental perspective. It is expected that this innovative electro-assisted molecular assembly strategy could be extensively applied in the active structure-controlled synthesis of nonmetal electrocatalysts and verification of the exact active atom. 相似文献
9.
木质素是一种天然芳香族聚合物,约占木质纤维素的30%,是唯一通过裂解C―O醚键和C―C键生产芳香族化学品或液体燃料的可再生芳香族资源。迄今为止,对木质素氢解制备有价值化合物的研究主要集中在相对不稳定的C―O键的裂解上,这限制了木质素氢解的效率。采用水热法和湿浸渍法制备了多功能Pt/NbPWO催化剂。通过破坏碱木质素中的C―O键和C―C键,可以得到产率为18.02%的芳香族单体。该反应不仅可以断裂木质素聚合物中醚键,同时也可以断裂部分关键的C―C键。其氢解机理可能是丰富的Brønsted酸和Lewis酸位点参与了C―C的活化。此外,重点分析载体和Pt物种在Pt/NbPWO催化剂中的协同作用。 相似文献
10.
Dingzhong Li Wensheng Zhang Dr. Longzhi Zhu Prof. Dr. Shuang-Feng Yin Prof. Dr. Nobuaki Kambe Prof. Dr. Renhua Qiu 《ChemistryOpen》2022,11(5):e202200023
An efficient hydrazine substitution of p-nitro-aryl fluorides with hydrazine hydrates catalyzed by FeO(OH)@C nanoparticles is described. This hydrazine substitutions of p-nitro-aryl fluorides bearing electron-withdrawing groups proceeded efficiently with high yield and selectivity. Similarly, hydrogenations of p-nitro-aryl fluorides containing electron-donating groups also smoothly proceeded under mild conditions. Furthermore, with these prepared aryl hydrazines, some phthalazinones, interesting as potential structures for pharmaceuticals, have successfully been synthesized in high yields. 相似文献