Surface of room temperature ionic liquid [bmim][PF6] studied by polarization- and experimental configuration-dependent sum frequency generation vibrational spectroscopy

Understanding and control of the surface properties such as molecular orientations are of great importance in numerous applications of ionic liquids. However, there remain discrepancies among the previous experimental and theoretical studies on the surface orientation and structures of room temperature ionic liquids(RTIL) systems. In this article, the orientation of 1-butyl-3-methylimidazolium([bmin]) cation at the air/liquid interface of a characteristic RTIL, 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][PF6]), was investigated by the sum frequency generation vibrational spectroscopy(SFG-VS). Detailed polarization and experimental configuration analyses of the SFG-VS spectra showed the possibility of a small spectral splitting in the CH3 symmetric stretching region, which can be further attributed to the probable existence of multiple orientations for the interfacial [bmim] cations. In addition, the(N)–CH3 vibrations were absent, ruling out the prediction by several recent molecular dynamics simulations which state that portions of the [bmim] cations orient with a standing-up(N)–CH3 group at the ionic liquid surface. Hence, new realistic theoretical models have to be developed to reflect the complex nature of the ionic liquid surface.     

Practical Synthesis of 2-Iodosobenzoic Acid (IBA) without Contamination by Hazardous 2-Iodoxybenzoic Acid (IBX) under Mild Conditions

We report a convenient and practical method for the preparation of nonexplosive cyclic hypervalent iodine(III) oxidants as efficient organocatalysts and reagents for various reactions using Oxone^® in aqueous solution under mild conditions at room temperature. The thus obtained 2-iodosobenzoic acids (IBAs) could be used as precursors of other cyclic organoiodine(III) derivatives by the solvolytic derivatization of the hydroxy group under mild conditions of 80 °C or lower temperature. These sequential procedures are highly reliable to selectively afford cyclic hypervalent iodine compounds in excellent yields without contamination by hazardous pentavalent iodine(III) compound.     

FINITE ELEMENTAN ALYSIS FOR THE UNSTEADY NEARSHORECIR CULATION DUE TO WAVE－CURRENT INTER－ACTION（I）──NUMERICAL MODEL

ＦＩＮＩＴＥＥＬＥＭＥＮＴＡＮＡＬＹＳＩＳＦＯＲＴＨＥＵＮＳＴＥＡＤＹＮＥＡＲＳＨＯＲＥＣＩＲＣＵＬＡＴＩＯＮＤＵＥＴＯＷＡＶＥ－ＣＵＲＲＥＮＴＩＮＴＥＲ－ＡＣＴＩＯＮ（Ｉ）——ＮＵＭＥＲＩＣＡＬＭＯＤＥＬＷｕＷｅｉ－ｘｉｏｎｇ（吴伟雄）（Ｔｏｎｇｊ...     

一种新颖的光纤应力传感器

基于模体积失配效应与微弯原理，提出了一种新颖的强度型光纤应力传感器，其传输光功率变化与应力之间近似为线性关系，重复性好，无迟滞现象     

用曲线大窗口平滑散斑条纹图的方法研究

提出一种计算条纹方向的简单算法,以及通过条纹方向图获得沿条纹方向的曲线窗口并对散斑条纹图进行曲线大窗口滤波的方法．实验表明此方法较好地消除了散斑条纹图的噪声,同时尽量减小了对条纹结构的损害．为从单幅散斑条纹图中应用条纹中心线法或全灰度法进一步提取相位场的后处理,奠定了良好的基础．     

纳米二氧化硅水溶胶成膜特性研究

研究了纳米SiO2水溶胶的固液二相流成膜特性．结果表明，水溶胶中的Si02固体颗粒的粒径及质量分数对粘度的影响较小，对成膜能力和承载能力的影响较大；在薄膜润滑阶段，固体颗粒的粒径和质量分数对润滑状态的稳定性具有一定的影响，随着速度的增加，液体膜厚度逐渐增大，固体颗粒对液体润滑膜稳定性及性能的影响逐渐减弱；在弹流润滑阶段，固体颗粒的影响很小。     

中心裂纹圆盘应力强度因子的测试误差分析

本文在中心裂纹圆盘应力强度因子解析解的基础上,利用一阶微分法则,给出了与裂纹相对长度和加载角相关的应力强度因子(K 和K )的4个误差传递函数。这4个误差传递函数关于裂纹相对长度和加载角均是非线性的,它们既是误差分析的基础,又是合理确定裂纹相对长度和加载角的基础。分析结果表明,加载角的误差Δθ除了对纯 型K 的误差几乎没有影响,对纯 型K 影响较小外,对复合型K 、K 的误差均有较大影响。最后,本文建议裂纹相对长度的取值范围为0.4～0.6;还建议在复合型断裂试验时,必须依据对K 、K 的总体精度要求来严格控制加载角的精度。     

EFFECTS OF FINELY DISPERSED METALLIC PALLADIUM ON MICROSTRUCTURE AND PROPERTIES OF NANOCOMPOSITES PRODUCED BY SOL-GEL TECHNIQUE

Nanosized palladium particles were incorporated into mesoporous silica matrix to obtain nanocomposites using the sol-gel technique. Effects of the finely dispersed metallic palladium on the microstructure and properties of the nanocomposites were investigated. By means of X-ray diffraction and optical absorption, it was found that palladium particles were 5-9 nm in diameter and their uniform dispersion in the mesoporous silica depended on both the content of the palladium and the structural features of the silica matrix. The results showed that the mixing method of preparation led to wider size distribution of the nanosized particles as compared to the immersion method, but dispersed degree was reduced. Although the incorporation of nanosized palladium particles could not substantially induce significant structural changes of the matrix, the apparent red-shifted optical absorptions for the nanocomposites were observed as compared to the parent monolithic silica, particularly with increase in palladium loading and calcination temperature.     

SYNTHESIS AND CHARACTERIZATION OF SURFACE-HYPERBRANCHED MAGNETITE NANOPARTICLE FOR BOVINE SERUM ALBUMIN IMMOBILIZATION

A hyperbranched polyamidoamine polymer was synthesized on the surface of magnetite nanoparticles to enhance bovine serum albumin (BSA) immobilization efficiency. The amount of immobilized bovine serum albumin (BSA) on the surface-hyperbranched magnetite nanoparticle was up to 2.5 times as much as that of magnetite nanoparticle modified with only amino silane.     

受控结构风振响应分析的广义虚拟激励法

基于复模态分析和虚拟激励法．提出了用于具有密集频率和非经典阻尼受控结构风振响应分析的广义虚拟激励法。该法可以考虑任意风谱和空间相关性以及模态耦合效应，且计算效率很高。不同于SRSS法．该算法包含了全部参振模态之间和全部激励点之间的相关性．在理论上是精确解。