Hard X-ray one dimensional nano-focusing at the SSRF using a WSi2/Si multilayer Laue lens

The multilayer Laue lens (MLL) is a novel diffraction optics which can realize nanometer focusing of hard X-rays with high efficiency. In this paper, a 7.9 μm-thick MLL with the outmost layer thickness of 15 nm is designed based on dynamical diffraction theory. The MLL is fabricated by first depositing the depth-graded multilayer using direct current (DC) magnetron sputtering technology. Then, the multilayer sample is sliced, and both cross-sections are thinned and polished to a depth of 35-41 μm. The focusing property of the MLL is measured at the Shanghai Synchrotron Facility (SSRF). One-dimensional (1D) focusing resolutions of 205 nm and 221 nm are obtained at E=14 keV and 18 keV, respectively. It demonstrates that the fabricated MLL can focus hard X-rays into nanometer scale.     

Completeness of system of root vectors of upper triangular infinite-dimensional Hamiltonian operators appearing in elasticity theory

This paper deals with a class of upper triangular infinite-dimensional Hamiltonian operators appearing in the elasticity theory.The geometric multiplicity and algebraic index of the eigenvalue are investigated.Furthermore,the algebraic multiplicity of the eigenvalue is obtained.Based on these properties,the concrete completeness formulation of the system of eigenvectors or root vectors of the Hamiltonian operator is proposed.It is shown that the completeness is determined by the system of eigenvectors of the operator entries.Finally,the applications of the results to some problems in the elasticity theory are presented.     

弹性理论中上三角无穷维Hamilton算子根向量组的完备性

考虑弹性力学中一类上三角无穷维Hamilton算子.首先,给出此类Hamilton算子特征值的几何重数和代数指标,进而得到代数重数.其次,根据Hamilton算子特征值的代数重数确定其特征(根)向量组完备的形式,得到此类Hamilton算子特征(根)向量组的完备性是由内部算子特征向量组决定.最后,将所得结果应用到弹性力学问题中.     

基于声光折射的聚焦超声焦点声压检测

提出了一种基于声光折射对聚焦超声焦点声压进行非侵入式检测的方法。当一束直径小于声波长的平行光束入射穿过聚焦超声的焦点时,通过研究焦点声压与光线偏转的具体关系,建立了光线最大偏转距离与焦点声压变化的关系模型,从而计算出焦点峰值声压。为了对理论模型进行验证,采用凹球面型聚焦换能器进行实验研究。通过与采用光纤水听器测量的结果进行对比,证明理论模型的可行性。结果表明实验得到的光斑图像与理论分析的结果一致,且用该方法测得的焦点峰值声压与光纤水听器测量的结果相比,相对误差小于15%,证明该方法具有可行性,能够定量检测焦点峰值声压。模型的提出也为将声光折射效应用于整个聚焦声场的定量检测提供了实验依据和理论依据。     

基于同步辐射的快速扫描X射线微束荧光成像方法

在上海光源硬X射线微聚焦光束线站(BL15U1)上, 基于EPICS软件平台, 集成运动控制, 光强探测, 荧光探测等功能, 实现了"飞行"模式 (on-the-fly) X射线扫描微束荧光成像方法. 用"飞行"扫描X射线荧光成像法获得了标准镍网, 以及微量元素Cu, Zn,K, Fe在样品老鼠脾内的分布图像, 结果显示该方法不但在速度上有了极大的提高, 而且获得的元素分布图像具有高质量. 关键词： 快速扫描X射线微束荧光成像 同步辐射 微量元素分布     

Symplectic eigenvector expansion theorem of a class of operator matrices arising from elasticity theory

This paper deals with the completeness of the eigenvector system of a class of operator matrices arising from elasticity theory, i.e., symplectic eigenvector expansion theorem. Under certain conditions, the symplectic orthogonality of eigenvectors of the operator matrix is demonstrated. Based on this, a necessary and sufficient condition for the completeness of the eigenvector system of the operator matrix is given. Furthermore, the obtained results are tested for the free vibration of rectangular thin plates.     

解吸附电晕束电离质谱法快速检测中成药及保健食品中非法添加的β-受体阻滞剂

建立了新型的解吸附电晕束离子源耦合离子阱质谱法(DCBI-MS),在无需复杂的样品前处理及色谱分离的条件下,可快速检测降血压中成药及保健食品中非法添加的7种β-受体阻滞剂阿替洛尔、比索洛尔、美托洛尔、普萘洛尔、盐酸塞利洛尔、盐酸贝凡洛尔和卡维地洛.采用一级质谱快速筛选和二级质谱确证的方法对目标化合物进行了定性和半定量测定.各目标物的检出限均低于0.1 mg/L,在0.5～100 mg/L浓度范围内线性关系良好.实验获得的7种β-受体阻滞剂的裂解规律为芳氧丙醇胺类化合物的质谱检测提供了参考依据.通过与高效液相色谱-电喷雾离子化质谱法(HPLC-ESI/MS)对比表明,DCBI-MS方法的检测结果可靠.对9种市售样品进行检测,有1批次中成药检出含有未标示的卡维地洛.结果表明,DCBI-MS法测定单个样品的时间不超过1 min,分析速度快,可以在大批量复杂基质样品中β-受体阻滞剂的筛查和药品品质的在线监测中发挥重要作用.     

纤维二糖与葡萄糖催化转化制备乙二醇(英文)

选用纤维二糖作为探针分子,探索纤维素催化转化制备乙二醇过程的反应路径.分别考察了纤维二糖和葡萄糖在双组分催化剂H2WO4和Ru/C下的催化反应活性.结果表明,乙二醇不仅来自于纤维二糖水解产物葡萄糖的逆羟醛缩合作用,同时也可以来自于纤维二糖的直接逆羟醛缩合过程.而且,纤维二糖的直接逆羟醛缩合作用对糖苷键的水解也有一定的促进作用.比较发现,钨基催化剂作用下纤维二糖的逆羟醛缩合反应活性比葡萄糖要低,因此乙醇醛可以缓慢产生并在Ru/C催化剂上迅速加氢生成乙二醇.使得以纤维二糖作为原料比以葡萄糖作为原料时获得更高的乙二醇收率.     

基于MoO3/Ag/MoO3透明阳极的顶发射OLED的模拟计算与制备

运用传输矩阵法和正交分析法模拟计算出MoO₃/Ag/MoO₃透明电极的最佳厚度,采用镀膜实验验证模拟计算的准确性,制备了一系列不同MoO₃膜厚度和Ag膜厚度的透明电极。然后,制备了一系列顶发射有机电致发光器件:铝/氟化锂(LiF)/三(8-羟基喹啉)铝(Alq₃)/N,N'-二苯基-N,N'-(1-萘基)-1,1'-联苯-4,4'-二胺/三氧化钼(MoO₃)/银(Ag)/三氧化钼(MoO₃),来进一步验证模拟计算运用在器件制备中的准确性。MoO₃(10 nm)/Ag(10 nm)/MoO₃(25 nm)在532 nm处的透射率达到最大值88.256%,以该透明电极制备的器件与参考器件相比,性能有了明显提高,最大亮度和最大效率分别为20 076 cd/m²和4.03 cd/A,提高了18.5%和56%。器件性能的提高归因于顶发射OLED器件透射率的提高和MoO₃对空穴注入能力的提升。     

The mean first passage time of a three-level atomic optical bistable system subjected to noise

The transient properties of a three-level atomic optical bistable system in the presence of multiplicative and additive noises are investigated. The explicit expressions of the mean first-passage time (MFPT) of the transition from the high intracavity intensity state to the low one are obtained by numerical computations. The impacts of the intensities of the multiplicative noise D M and the additive noise D A , the intensity of correlation between two noises λ , and the intensity of the incident light y on the MFPT are discussed, respectively. Our results show: (i) for the case of no correlation between two noises (λ = 0.0), the increase in D M and D A can lead to an increase in the probability of the transition to the low intracavity intensity state, while the increase in y can lead to a retardation of the transition; and (ii) for the case of correlation between two noises (λ = 0.0), the increase in λ can cause an increase in the probability of the transition, and the increase in D A can cause a retardation of the transition firstly and then an increase in the probability of the transition, i.e., the noise-enhanced stability is observed for the case of correlation between two noises.