新型2-(芳氨基乙基氨基)苯甲醇的合成及其杀菌活性

2-氨基苯甲醇及其衍生物是一类很重要的具有双官能团的化合物,在有机化学和药物合成中具有广泛的用途。本文主要提供了一种简单、有效合成2-(芳氨基乙基氨基)苯甲醇类化合物的方法,同时测定了目标化合物的杀菌活性。溴乙酰芳胺与2-氨基苯甲醇经N-烷基化反应生成2-[(2-羟甲基苯基)氨基]乙酰芳胺类化合物3,然后经LiAlH4还原生成了一系列结构新颖的2-(芳氨基乙基氨基)苯甲醇类化合物5a~5i,产率为76%~95%。用IR、~1H NMR、~(13)C NMR和元素分析等对产物结构进行了表征。目标化合物的杀菌活性结果表明,在测试浓度下,大部分显示中等至良好的活性,化合物5e对辣椒疫霉病菌的抑制活性达73.0%。     

Rapid Fabrication of Three-Dimensional Woodpile Photonic Crystals by Means of Two-Photon Photopolymerization

Two-photon photopolymerization （TPP） of femtosecond laser is a promising method to fabricate three-dimensional woodpile photonic crystals （PCs）. We build micro-fabricatlon system based on the principle of TPP. Three- dimensional woodpile PCs consisting of in-plane rod distances ranging from 1000nm to 2000nm are fabricated by focusing femtosecond laser in photosensitive liquid resin ORMOCER. The properties of the PCs are also discussed, and fundamental photonic band gaps in middle-infrared range are measured, whose in-plane rod distances are 1500nm and 2000 nm. Three-dimenslonal woodpile PC devices with desired defects, such as cross-waveguide and micro-laser structures, are introduced easily by TPP. We fabricate the three-dimensional woodpile PCs in the liquid resin at the fast scanning speed of 120μm/s.     

折线裂纹和两相材料界面的相互作用

利用螺位错基本解建立了和界面相交的折线裂纹的Cauchy型积分方程，根据奇异积分方程理论，得出了确定折线裂纹和界面交点处的奇性应力指数的特征方程，以及交点处各角形域内的奇性应力，利用所得的交点处的奇性应力定义了折线裂纹和界面交点处的应力强度因子，对所得积分方程进行数值求解，可得裂纹端点以及裂纹和界面交点处的应力强度因子。     

与两相材料界面接触的裂纹对SH波的散射

利用积分变换方法得出了两相材料中作用简谐集中力时的格林函数．根据所得的格林函数并利用Betti-Rayleigh互易定理得出了与界面接触裂纹的散射波场．裂纹的散射波场可分解为两部分，一部分为奇异的散射场，另一部分为有界的散射场．利用分解后的散射场，可得裂纹在SH波作用下的超奇异积分方程．根据裂纹散射场的奇异部分和Cauchy型奇异积分的性质得出了裂纹和界面接触点处的奇性应力指数和接触点角形域内的奇性应力．利用所得的奇性应力定义了裂纹和界面接触点处的动应力强度因子．对所得超奇异积分方程的数值求解可得裂纹端点和接解点处的应力强度因子。     

纳米GeSb2Te4薄膜在大气环境中的摩擦性能研究

采用摩擦力显微镜考察了磁控溅射纳米GeSb2Te4薄膜在大气环境中的微观摩擦性能,利用JKRS理论分析了针尖同GeSb2Te4薄膜接触时的粘附力和表面能之间的关系.结果表明:当湿度较大时,粘附力较大;而当湿度较小时,粘附力较小;当针尖表面能一定时,粘附力的微小变化可以导致GeSb2Te4薄膜的表面能产生较明显变化;随着扫描范围逐渐减小,摩擦力变化趋于稳定;不同扫描速度下法向力和摩擦力保持较好线性关系,但不同扫描速度下的平均摩擦力随扫描速率变化而呈现非线性变化;为了更好地分析探针和样品表面的微观摩擦机制,宜选择扫描范围为0.1～0.5μm或更小.     

微纳跨尺度ZnO结构的紫外发射机理研究

利用气相输运的方法在Si(100)衬底上生长了ZnO的微纳跨尺度结构.扫描电镜照片可以明显地看到样品表面为椎顶六角微米柱-纳米棒的复合结构.样品在室温下的光致发光谱出现了很强的紫外发射峰,没有观察到与杂质或缺陷相关的深能级发射，表明样品有很好的光学质量.通过详细的研究样品的紫外发射谱与温度(83—307K)的依赖关系，发现在室温下样品的近带边发射包含两个部分，分别与自由激子发射和自由载流子到施主(受主)的跃迁(FB跃迁)相关,这个施主(受主)束缚态的离化能为124.6meV. 关键词： ZnO微纳跨尺度结构 光致发光谱 自由载流子到施主(受主)的跃迁 自由激子发射     

激光加热的微塑性成形有限元模拟

针对难成形材料微构件成形困难的特点,提出基于激光双面加热的微塑性成形方法。采用有限元分析软件ABAQUS,建立了基于激光加热的微镦粗圆柱形工件的热力耦合有限元模型,并对激光加热后工件的温度场分布和微塑性成形进行了模拟和应力分析。结果表明,采用激光双面加热的方法可以为微塑性成形建立合适的温度场,激光加热状态下的微塑性成形力明显降低,提高了微塑性材料的成形性能,拓宽了微塑性成形技术的应用范围。     

Three-dimensional photonic crystals containing designed defects achieved with two-photon photopolymerization

Two-photon photopolymerization （TPP） with femtosecond laser is a promising method to fabricate threedimensional （3D） photonic crystals （PCs）. Based on the TPP principle, the micro-fabrication system has been built. The 3D woodpile PCs with rod space of 2000 nm are fabricated easily and different defects are introduced in order to form the cross-waveguide and the micro-laser structure PCs. Simulation results of the optical field intensity distributions using finite-difference time domain （FDTD） method are given, which support the designs and implementation of the PC of two types in theory.     

Microstructure and properties of plastic deformed martensite induced by laser shock processing

Firstly, 45# steel was quenched by the NEL-2500A rapidly axial flow CO2 laser. The experimental parameters were the laser power of 750 W, the laser beam diameter of 4 mm, the scanning velocity of 7 mm/s.The thickness of coating layer was 0.1 mm and the width was 8 mm. Secondly, the martensite induced by laser quench was shocked by Nd:YAG laser. The parameters of laser shock processing were the wavelength of 1.06 μm, the pulse duration of 23 ns, and the output energy of 16-20 J. The laser was focused on a spot of φ7 mm. K9 optical glass was used as confinement. The sample was coated with black paint 86-1 (the thickness is about 0.025 mm). By testing and analysis of samples which were treated by laser quench and laser quench+shock with transmission electron microscope (TEM), it was discovered that the surface layer of martensite was deformed plastically by laser shock processing. In the secondary hardened zones,there were a lot of slender secondary twin crystal martensites, dislocation tangles, and cellular dislocations.Compared with that of the hardened zones through laser quench only, the residual stress and mechanical properties of the secondary hardened zones were improved and increased through laser compound method.     

联合体驱使生长法制备ZnO纳米棒及其表征

在常压环境下采用联合体驱使生长(Aggregation-driven growth)法在镀有ZnO纳米薄膜的医用盖玻片衬底和锌箔上制备了不同直径、高取向、密集生长的ZnO纳米棒阵列结构,发现平均直径与生长时间呈线性关系。X射线衍射(XRD)谱图中出现了较强的(002)峰,表明制备的纳米棒阵列具有高度c轴择优生长取向;高分辨透射电子显微镜(HRTEM)和选区电子花样衍射图谱(SAED)结果表明我们得到的单根纳米棒为沿(002)生长的单晶结构。分析确定盖玻片上的纳米棒阵列是以ZnO纳米薄膜缓冲层上的ZnO种子颗粒为成核点生长形成的。