Syntheses,Crystal Structures and Antibacterial Activities of Schiff Base Ligand and Its Nickel(Ⅱ) Complex

A complex [NiL2] was synthesized, in which L, or to be exact, a Schiff base ligand(HL), was derived from the condensation of 1-phenyl-3-methyl-4-phenylacetyl-5-pyrazolone(PMPAP) with L-phenylalanine methyl ester. They were characterized by IR and single-crystal X-ray diffraction. Green block crystals of both ligand and its complex were grown at room temperature. The ligand, which consists of two individual fragments, crystalizes in the P1 space group(a = 5.6268(5), b = 10.6892(11) and c = 19.4869(18) ). The complex crystalizes in the P21 space group(a = 21.4076(18), b = 9.4792(8) and c = 25.287(2) ), which consists of a nickel six-coordinated compound. Every fragment is a distorted octahedron with four oxygen and two nitrogen atoms. The Schiff base ligand(HL) and its complex have been tested in vitro to evaluate their antibacterial activity against bacteria Escherichia Coli and Bacillus subtilis. It is found that the complex has higher activity than the corresponding free Schiff base ligand(HL) against the same bacterial.     

π相移光纤光栅对超声波致非均匀应变场的传感特性

π相移光纤光栅用于水中超声传感时,超声波沿光纤轴向入射和垂直光纤入射时的传感波形及幅度显著不同。针对这一现象,本文建立了基于光学传递矩阵的光纤光栅声传感理论模型,计算了超声波分别沿轴向和沿垂直方向入射时π相移光纤光栅中的非均匀应变场分布,进而分析了光谱偏移,揭示了两种入射角度下π相移光纤光栅的传感特性与声传播导致的应变场分布相关,并通过实验进行了验证。结果表明,两种入射角度产生的不同的非均匀应变场分布对π相移光纤光栅的传感特性影响明显。超声波垂直入射时的传感波形和幅度均优于轴向入射,且π相移处对传感有显著作用。当入射位置远离π相移处时,垂直入射的响应也明显降低。本研究可为π相移光纤光栅超声传感的机理分析提供参考。     

π相移光纤光栅水听器的超声波传感指向特性

π相移光纤光栅因具有较短的有效光栅传感长度,近年来成为了超声传感领域的研究热点.本研究旨在探究π相移光纤光栅作为水听器应用时对超声波的指向性特性.选取π相移光纤光栅作为超声传感单元,先基于分层介质的声传播理论计算出水中超声波入射时光纤纤芯的应变,再运用基于光学耦合模方程的传递矩阵法计算反射光谱得到光波长偏移.将角度-频率空间分为三个区域,计算了声波频率在1—10 MHz时不同角度下的应变结果和光波长偏移响应特性,并开展了实验研究.结果表明,理论和实验结果具有较高的一致性,π相移光纤光栅在超声波垂直光纤入射时响应最大,随声波入射方向与光纤法向间夹角的增加,π相移光纤光栅的声响应先急剧下降,后在水中直达声波和光纤中导波叠加时出现极大值.此外,π相移光纤光栅的声响应随声波频率增加而降低.本研究对π相移光纤光栅在超声传感中的实际应用具有重要意义.     

弯梁斜跨拱桥合理恒载状态研究

弯梁桥和拱桥相互协作形成的弯梁斜跨拱桥,充分结合了弯梁桥的行车舒适性与拱桥易于布索的特点,大幅度提高了弯梁的跨越能力。本文首先综合斜拉桥索力调整和拱桥合理拱轴线设计方面的经验,研究弯梁斜跨拱桥合理恒载状态的实用设计方法;然后提出了约束松弛的二次规划算法和基于刚度矩阵减少重分析的策略,提高计算的收敛性和求解速度;最后经实桥分析指出设计中应注意的问题,为弯梁斜跨拱桥的应用提供依据。