Local thermal conductivity of polycrystalline AlN ceramics measured by scanning thermal microscopy and complementary scanning electron microscopy techniques

The local thermal conductivity of polycrystalline aluminum nitride (AlN) ceramics is measured and imaged by using a scanning thermal microscope (SThM) and complementary scanning electron microscope (SEM) based techniques at room temperature.The quantitative thermal conductivity for the AlN sample is gained by using a SThM with a spatial resolution of sub-micrometer scale through using the 3ω method.A thermal conductivity of 308 W/m·K within grains corresponding to that of high-purity single crystal AlN is obtained.The slight differences in thermal conduction between the adjacent grains are found to result from crystallographic misorientations,as demonstrated in the electron backscattered diffraction.A much lower thermal conductivity at the grain boundary is due to impurities and defects enriched in these sites,as indicated by energy dispersive X-ray spectroscopy.     

无氨法制备GaN纳米线及其光电性能研究

采用等离子体增强化学气相沉积(PECVD)方法,在无氨与1050℃的条件下通过气液固(V-L-S)机理成功制备出六方纤锌矿结构单晶GaN纳米线其拉曼测试结果表明,所制备的纳米线存在较大的表面无序度并表现出明显的小尺寸效应样品光致发光表明其具有典型的纳米线光谱特征,另外,无氨法制备的纳米线也具有较好的场发射特性.     

去氢枞酸类成核剂改性聚丙烯的非等温结晶动力学研究

对以去氢枞酸盐为成核剂的聚丙烯非等温结晶动力学进行了研究，用修正Avrami方程的Jexiorny法和莫志深法进行处理。结果表明：修正Avrami方程的Jeziorny方法和莫志深法都适用于去氢枞酸类成核剂改性的聚丙烯的非等温结晶动力学。在同样的降温速率下纯聚丙烯的t1/2比成核聚丙烯的t1／2要长，当降温速率为20K/min时，纯聚丙烯和成核聚丙烯的t1/2分别为0．78min和0．51min。同时从莫志深法得到的F(T)结果可以看出，达到相同的结晶度时纯聚丙烯所需的降温速率要大于成核聚丙烯所需的降温速率，说明成核剂的加入提高了聚丙烯的结晶速率。从Jeziorny法求出的纯聚丙烯和成核聚丙烯的Avrami指数分别为4．46和2．77，表明成核剂改变了聚丙烯的结晶成核和生长方式。     

地面和埋置爆炸土中地冲击作用分区数值模拟及试验研究

为研究爆炸条件下土中应力波的时空分布,基于黄土中接触爆炸和半埋爆炸试验,验证了ANSYS/AUTODYN软件建立的计算模型,并在此基础上开展了土中爆炸地冲击效应研究。结果表明:随着土介质深度的增加,感生地冲击峰值减小,而直接地冲击峰值增大,最终,压力和竖向应力时程曲线中的2个峰值减少为1个峰值,据此特征可将土中应力波场分为3个区域,即地表区、近地表区和中心区;当装药比例埋深为?0.05～0.075 m/kg1/3时,随着装药比例埋深的增大,中心区迅速扩大,地表区迅速缩小,近地表区逐渐扩大;当装药比例埋深为0.1～0.4 m/kg1/3时,地冲击作用区的分布趋于稳定;爆炸耦合进入空气和土介质中的动能受炸药类型影响,但在一定范围内,地冲击作用区角度与地面空气冲击波超压冲量和直接地冲击应力冲量之比呈线性相关关系。     

Local thermal conductivity of polycrystalline AlN ceramics measured by scanning thermal microscopy and complementary scanning electron microscopy techniques

The local thermal conductivity of polycrystalline aluminum nitride (AlN) ceramics is measured and imaged by using a scanning thermal microscope (SThM) and complementary scanning electron microscope (SEM) based techniques at room temperature. The quantitative thermal conductivity for the AlN sample is gained by using a SThM with a spatial resolution of sub-micrometer scale through using the 3ω method. A thermal conductivity of 308 W/m·K within grains corresponding to that of high-purity single crystal AlN is obtained. The slight differences in thermal conduction between the adjacent grains are found to result from crystallographic misorientations, as demonstrated in the electron backscattered diffraction. A much lower thermal conductivity at the grain boundary is due to impurities and defects enriched in these sites, as indicated by energy dispersive X-ray spectroscopy.     

微量水对碳纳米管形貌的影响及其机理研究

利用介质阻挡放电等离子体化学气相沉积技术，在蒸镀有25nm Ni催化剂层的Si基片上，以CH₄和H₂作为反应气体，在973K下制备了碳纳米管，并研究了微量水的引入对碳纳米管形貌的影响.场发射扫描电子显微镜结果表明，不加水时，制备出的碳纳米管直径不均匀，分布在40—90nm之间，呈链节状的结构；加入少量水时，制备出的碳纳米管直径比较均匀，集中在70nm左右，表面为瘤状结构；当水的流量进一步增加时，得到的碳纳米管表面光滑，出现了枝状结构.原位测量了加水前后等离子体区的发射光谱，分析了微量水的引入对于碳纳米管形貌变化的影响机理. 关键词： 碳纳米管 介质阻挡放电 水 发射光谱     

双辉光放电静电场数值模拟及场分布边角效应分析

根据双辉光放电3个电极极板上的电势,利用边界元积分方程建立以面电荷密度为未知量的离散方程,通过求解线性方程组计算3个电极极板上面电荷的不均匀分布.由极板上的不均匀面电荷分布计算在真空状态下空间任意一点的电势和电场的空间分布,利用数值解对真空状态下双辉光离子渗金属实验装置场分布边角效应进行了分析.     

Silicon Dioxide Coating Deposited by PDPs on PET Films and Influence on Oxygen Transmission Rate

A silicon dioxide film is deposited on the polyethyleneterephtMate （PET） by a penning discharge plasma source at ambient temperature in a high vacuum chamber. Hexamethyldisiloxane and oxygen are adopted as precursor and reactive reagent to grow a nano-scale silicon dioxide layer on polymer surfaces. For the chemical structure analysis X-ray photoelectron spectroscopy is performed to demonstrate the content of Si, 0 and C elements. It is noticed that a higher silicon concentration is contained if Ar plasma is used for pretreatment. X-ray diffraction analysis shows that a micro-crystal silicon dioxide is formed by peak patterns at 25,84° and 21.8°. The barrier properties examined by oxygen transmission rate show that the permeation parameter of the 12-μm-thick PET film drastically decreases from 135 cc/m^2 per day for the control one to O. 713 cc/m^2 per day for the as-deposited one after Ar plasma treatment. The surface morphology related to the barrier properties of SiOx-coated polymers os also investigated by scanning electron microscopy and atomic force microscopy.     

国内中学化学作业研究综述

从作业功能、作业类型、作业设计、作业评价等4个方面介绍了近年来国内中学化学作业的研究情况,希望有助于促进中学化学作业的设计与布置,促进化学教学的有效性。     

苦参配方颗粒的高效液相色谱指纹图谱研究及定量分析

研究了苦参配方颗粒的指纹图谱和含量测定。采用高效液相色谱法,在C18柱上以乙腈-磷酸氢二钠水溶液(20 mmol/L,磷酸调pH 7.1)进行梯度洗脱,柱温35℃,检测波长220 nm,用指标成分氧化苦参碱、氧化槐果碱和苦参碱进行了定位,并在同一色谱条件下同时测定了它们的含量。确定了15个共有峰,其中7、8和11号峰分别为氧化苦参碱、氧化槐果碱和苦参碱。10批样品平均相似度为0.99以上,三个成分的含量分别为:氧化苦参碱50.0~79.8 mg/g;氧化槐果碱13.5~18.1 mg/g;苦参碱16.5~30.1 mg/g。结果表明:指纹图谱与指标成分含量测定相结合,可提高苦参配方颗粒的内在质量控制水平。