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Yu He Yating Guo Yanbin Yu Peifu Luo Honglong Qiu Guoming Huang 《Particle & Particle Systems Characterization》2021,38(5):2100038
In this study, manganese tellurite (MnTeO3) nanoparticles are developed as theranostic agents for magnetic resonance imaging (MRI)-guided photothermal therapy of tumor. MnTeO3 nanoparticles are synthesized via a simple one-step method. The as-synthesized MnTeO3 nanoparticles with uniform size show good biocompatibility. In particular, MnTeO3 nanoparticles exhibit a high photothermal conversion efficiency (η = 26.3%), which is higher than that of gold nanorods. Moreover, MnTeO3 nanoparticles also have high MRI performance. The longitudinal relaxivity (r1) value of MnTeO3 nanoparticles is determined to be 8.08 ± 0.2 mm −1 s−1, which is higher than that of clinically approved T1-contrast agents Gd-DTPA (4.49 ± 0.1 mm −1 s−1). The subsequent MnTeO3 nanoparticles-mediated photothermal therapy displays a highly efficient ablation of tumor cells both in vitro and in vivo with negligible toxicity. It is demonstrated that MnTeO3 nanoparticles can serve as promising theranostic agents with great potentials for MRI-guided photothermal therapy. 相似文献
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通过熔融退火的方法以及热处理技术制备得到含有Er2WO6,La2WO6晶体的TeO2-WO3-La2O3-Er2O3-Yb2O3微晶玻璃,该玻璃具有优异的上转换发光性能。结果表明,在含银纳米晶的碲酸盐微晶玻璃中,银纳米晶和微晶的析出情况与银纳米晶的引入方式和热处理温度有关。经过390℃下15 min的热处理后,AgCl和AgNO3共掺的碲酸盐微晶玻璃比单掺AgCl或AgNO3的碲酸盐微晶玻璃具有更高的发光强度。银纳米晶与微晶的引入可协同提高碲酸盐玻璃的上转换发光性。 相似文献
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采用熔融法制备了CaO-MgO-Al2O3-SiO2系纳米晶玻璃陶瓷材料。在-190~310℃温度范围,利用显微共聚焦拉曼光谱测量分析了该体系纳米晶玻璃陶瓷硅氧四面体结构的变化规律。结果表明,随着温度的降低具有不同非桥氧键的硅氧四面体结构单元变化并不一致,位于三维硅氧四面体结构边缘的具有二个非桥氧键的硅氧四面体(Q2)和具有三个非桥氧键的硅氧四面体(Q1),以及完全独立于三维硅氧网络结构外的具有四个非桥氧键的硅氧四面体(Q0)受温度影响明显,其拉曼光谱均向高波数移动,键的力常数变强,硅氧键长变短。为丰富外环境对纳米晶玻璃陶瓷材料结构与性能影响的研究提供了实验依据,也为控制该体系纳米晶玻璃陶瓷材料的膨胀系数提供了一定的实验依据。 相似文献
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Spectroscopic properties of Yb~(3+)-doped TeO_2–BaO–BaF_2–Nb_2O_5-based oxyfluoride tellurite glasses 下载免费PDF全文
A series of oxyfluoride glasses with the compositions of 75 mol% TeO2, 10 mol% Nb2O5,(15 mol%-x) BaO, x BaF2(x = 0 mol%, 5 mol%, 10 mol%, 15 mol%) doped with Yb2O3 were prepared by the melt-quenching method. Their emission cross-sections, fluorescence lifetimes, and gain properties were investigated by using the absorption spectra and the fluorescence decay curves. The results show that by substituting BaF2 for BaO, the emission cross-section decreases from 1.37 pm2 to 1.21 pm2, and the fluorescence lifetime increases from 0.71 ms to 0.96 ms. These properties indicate that this oxyfluoride tellurite glass may have potential uses as the Yb2O3-doped gain medium in a solid laser. 相似文献
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Y.B. Saddeek 《哲学杂志》2013,93(1):41-54
The elastic properties and Debye temperatures of xB2O3–70TeO2–(30–x)WO3, (0 ≤ x ≤ 30 mol%) glasses have been investigated using sound velocity measurements at 4 MHz. Ultrasonic and thermal parameters, combined with the results of IR spectroscopic analyses, were employed to explore the effect of B2O3 on the structure of tungsten–tellurite glasses. According to IR analysis, there is competition between WO6 and TeO4 units to form BO4 units, and the vibrations of the tellurite structural units are shifted towards lower wavenumbers on the formation of non-bridging oxygens. It is assumed that B2O3 acts as a modifier by decreasing the glass-transition temperature T g and increasing both the thermal stability and glass formation range of the tellurite glasses. The change in density and molar volume with B2O3 content reveals that the borate units are less dense than the tellurite structural units. The observed compositional dependence of elastic moduli is interpreted in terms of the effect of B2O3 on the coordination number of the tellurite units. A good correlation was observed between experimentally determined elastic moduli and those computed with the Makishima–Mackenzie model. 相似文献
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以铁尾矿和金尾矿为主要原料,采用熔融法制备了添加0~20wt%Fe_2O_3的CaO-MgO-Al_2O_3-SiO_2(CMAS)系纳米晶尾矿微晶玻璃,利用差示扫描量热分析(DSC)、X射线衍射分析(XRD)、红外光谱(IR)、扫描电镜(SEM)和综合力学性能仪等测试手段,研究了Fe_2O_3含量对该体系微晶玻璃显微结构及性能的影响。实验结果表明:随着Fe_2O_3含量的增加,样品的晶化温度和玻璃化转变温度逐渐降低;且Fe_2O_3可促进主晶相透辉石相(Mg_(0.6)Fe_(0.2)Al_(0.2))Ca(Si_(1.5)Al_(1.5))O_6的形成;同时Fe_2O_3能够有效减小透辉石相平均晶粒尺寸;另外,微晶玻璃的密度、显微硬度和耐碱性随晶粒尺寸的减小而增加,而抗折强度和耐酸性随晶粒尺寸的减小而降低。 相似文献
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Low phonon energy Tm3+/Ho3+/Yb3+ triply doped bismuth tellurite glasses exhibiting multicolor upconversion fluorescences have been fabricated and characterized. The multicolor fluorescence composed of three primary colors green, red and blue upconversion emissions from Ho3+ and Tm3+ has been investigated. By adjusting the excitation power, the fluorescence colors can be tuned from multicolor to white color, and the dependence of color tunability on pump power has been presented in the CIE 1931 chromaticity diagram. With the increase in pumping power, the color coordinates move along the down-left direction and hit the equal energy point. The upconversion and color tunability via changing the pump power of infrared excitation in Tm3+/Ho3+/Yb3+ triply doped bismuth tellurite glasses will lead to new breakthrough in the field of three-dimensional solid-state displays and white-light emitting devices. 相似文献
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用高温熔融法制备了Tm3+/Ho3+/Yb3+共掺碲酸盐玻璃(TeO2-ZnO-La2O3)样品,测试了玻璃样品的吸收光谱和上转换发光光谱,分析了上转换发光机理.结果发现:在975 nm波长激光二极管(LD)激励下,制备的碲酸盐玻璃样品可以观察到强烈的红光(662 nm)、绿光(546 nm)和蓝光(480 nm)三基色上转换发光,红光对应于Tm3+离子
关键词:
碲酸盐玻璃
上转换发光
白光
3+/Ho3+/Yb3+共掺')" href="#">Tm3+/Ho3+/Yb3+共掺 相似文献