Catalytic properties of mesoporous materials supported heteropoly acids for Baeyer-Villiger oxidation of cyclic ketones

Three mesoporous molecular sieves loaded silicotungstic acids, named HSiW/SBA-15, HSiW/MCM-41, HSiW/MCM-48, were prepared and characterised by XRD, FT-IR, TEM and SEM. The catalytic performance of the prepared materials for the Baeyer-Villiger oxidation of cyclic ketones was carried out in the presence of 30%H₂O₂ under mild conditions. These loading materials were proved to be efficient and reusable catalysts, they all exhibited excellent catalytic performance for the Baeyer-Villiger oxidation of cyclic ketones with 30% H₂O₂ as oxidant. Many cyclic ketones were efficiently converted to the corresponding lactones with up to 90% conversions and high selectivities under the optimum reaction conditions.

Cyclic ketones were efficiently oxidised by mesoporous materials sopported silicotungstic acid to the corresponding lactones with 30%H₂O₂ as oxidant. All of the catalysts showed promising recyclability in the reactions.     

基于集对分析联系数的区间数型多属性决策投影模型及其在基坑支护方案评价中的应用

多属性决策时因掌握的信息有限,加之问题本身的复杂性、不确定性以及人类思维的模糊性,其属性的精确值往往难以获取,常用区间数形式表示针对多属性决策中各指标区间数不能直接进行大小比较的问题,提出一种基于集对分析联系数的区间数型多属性决策投影模型.模型用备择方案在理想方案上的投影进行集结,根据区间数的误差分布形式,沟通区间数与联系数的关系,根据a+bi型联系数大小比较法则,综合评价方案优劣.以某大厦基坑支护拟用的4种方案优化选择为例,说明方法的应用与模糊优化理论模型和灰色物元分析优化模型进行了对比,得到的结果一致.     

大型多支承变刚度回转窑支承载荷分配问题

回转窑是冶金、水泥、耐火材料生产中的核心设备，是一种重载、大扭矩、多支点、静不定运行系统，由于其载荷和刚度分布复杂、各支承存在偏移，作用在它托轮上的支承载荷分配严重不均。本文针对回转窑载荷和刚度分布的特点，建立支承载荷求解的力学模型和线性方程组，导出支承载荷分配与支承偏差的关系式；用该方法对现场回转窑进行计算，得出该窑支承载荷分配的线性公式和一些分析结论，为生产中回转窑的状态分析、优化调控提供依据。     

The isometric extension problem between unit spheres of two separable Banach spaces

In this article, we use some analytic and geometric characters of the smooth points in a sphere to study the isometric extension problem in the separable or reflexive real Banach spaces. We obtain that under some condition the answer to this problem is affirmative.     

圆宝山隧道炭质板岩大变形段初期支护结构受力特性研究

为了准确掌握丽香铁路圆宝山隧道炭质板岩大变形段初期支护结构受力特性,结合深埋炭质板岩隧道大变形特点,通过调查分析发现炭质板岩具有显著的各向异性特征,在地下水、高地应力及施工扰动等复杂因素作用下表现出显著的蠕变特性,从而导致隧道发生大变形。同时,对圆宝山隧道展开围岩变形及初期支护受力监测,监测结果表明,薄层炭质板岩段围岩的变形速率、变形量整体上较中厚层炭质板岩段围岩大,且达到稳定所需的时间更长;围岩压力与钢拱架应力基本呈从拱顶到拱脚减小的趋势,且围岩压力最大值出现在拱肩,而钢拱架应力最大值分布位置不固定,常见分布位置为两侧拱墙上下,这与钢拱架因发生扭曲而设置横支撑基本吻合;变更支护参数后,围岩的时效特性有明显改善,尤以薄层炭质板岩段围岩最为明显,同时围岩压力分布更加均匀,钢拱架出现拉应力现象不再集中。基于上述研究成果,选择I18型工字钢焊制钢架、设置间距为0.6m、喷射厚为27cm的C25混凝土作为初期支护,同时采用"弱爆破、短进尺"的掘进方式,以达到控制深埋炭质板岩隧道围岩变形的目的。     

大空间三向组合平板网架研究

利用中心节点、交叉梁、三角形拉杆和空心板所构成承力单元的组合以及内部支承柱的自由布置,本文提出了一种新型大空间三向组合平板网架结构。相关的TDGS分析系统针对原型试验取得了较好的模拟效果。通过引入柱的局部影响区域这一全新概念,系统总结了加入内部支承柱前后网架结构的内力和变形规律,进而为进一步的工程应用提供了可行性建议。     

断陷盆地层滑带的发育特征及矿山开发条件下的再变形分析

层滑带在华北断陷盆地中具有普遍性,是影响地下矿山工程围岩稳定的重要因素之一。本文以鲁西矿区为例,阐述了断陷盆地层滑带的发育特征及其形成机制,进行了开挖、运营条件下层滑带再变形分析,并指出了层滑带发育区巷道设计及维护中应注意的某些问题。     

社会资本、地方感对民族村寨旅游中居民支持态度的影响

社区居民是民族村寨旅游能否可持续发展的核心要素,他们既是民俗旅游资源的重要载体,又因身处旅游地而直接承受着旅游所带来的各种冲击.随着西部民族地区日益将旅游产业作为当地追赶式发展的重要引擎,对社区居民旅游态度的研究便具有了极强的理论和现实意义.以社会资本和地方感作为理论基点,以贵州省黔东南西江苗寨和黎平肇兴侗寨作为实证案例,采用层次回归法,从社区中"人-人"关系和"人-地"关系入手探索居民对旅游发展持积极态度的前导因素,并就民族社区社会资本、地方感的培育和提升提出了相关建议,以期为西部民族地区的旅游发展、规划提供有益咨询.     

Why a mosquito leg possesses superior load-bearing capacity on water: Experimentals

Mosquitoes possess the striking ability to walk on water because each of their legs has a huge water supporting force(WSF) that is 23 times their body weight.Aiming at a full understanding of the origins of this extremely large force,in this study,we concentrate on two aspects of it:the intrinsic properties of the leg surface and the active control of the initial stepping angle of the whole leg.Using a measurement system that we developed ourselves,the WSFs for the original leg samples are compared with those whose surface wax and microstructures have been removed and with those of a different stiffness.The results show that leg f exibility plays a dominant role over surface wax and microstructures on the leg surface in creating the supporting force.Moreover,we discuss the dependence relationship between the maximum WSF and the initial stepping angle,which indicates that the mosquito can regulate this angle to increase or decrease the WSF during landing or takeoff.These finding are helpful for uncovering the locomotion mechanism of aquatic insects and for providing inspiration for the design of microfluids miniature boats,biomimetic robots,and microsensors.     

浅埋偏压连拱隧道现场监测与结构受力分析研究

针对浅埋偏压连拱隧道结构受力的复杂性,结合石红高速大中山1#连拱隧道的实际情况,选择典型断面埋设监控量测设备对隧道施工过程中围岩变形和结构受力进行适时监测,并结合有限元分析软件MIDAS,对中隔墙空间受力特征进行研究.得出了支护结构在偏压作用下和施工扰动下的受力状态和变形特征.结果表明,在浅埋偏压条件下,减少支护结构受力的不均对于保证隧道结构稳定的重要性以及运用监控量测与数值模拟相互印证的方法可以更准确地分析隧道结构的稳定性,更好地指导施工.