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1.
为探究水牛角的结构性能关系,基于上海同步辐射光源搭建了高分辨原位CT系统,对水牛角角鞘进行初始表征和准静态压缩下的实时表征,并通过Top-Hat方法提取了角鞘内孔洞三维形貌。结果显示,水牛角角鞘孔隙率在1%左右,椭圆柱状孔洞沿牛角生长方向排列成线,首尾相连却并未连通,均匀分布在波浪状片层之间。孔洞特征椭球的轴长分布满足对数正态分布,长轴和短轴的长度均值分别为7μm和3μm。原位CT结果表明,角鞘在屈服之后,初始孔洞首先扩张而形成微裂纹,随后微裂纹沿着片层界面由外向内发生桥接,片层发生局部屈曲和层间开裂,形成宏观裂纹,导致角鞘内裂纹密度急剧上升。片层之间不仅存在大量纤维黏接(提高了层间拉伸/剪切强度),而且孔洞互不连通,这些因素抑制了层间裂纹的快速传播,使得各处裂纹只能独立缓慢发展而无法贯通样品。波浪状片层使裂纹传播路径更加曲折,层间屈曲增加了片层摩擦耗能。这些机制使得牛角表现出加工硬化,也是牛角在纵向方向呈现优良韧性的主要原因。 相似文献
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There is a need to understand the ultrasound-induced changes in the interactions between proteins and phenolic compounds at different pH. This study systematically explored the role of high-intensity ultrasound pre-treatment on the binding mechanisms of β-lactoglobulin (β-LG) to two common phenolic compounds, i.e., (−)-epigallocatechin-3-gallate (EGCG) and chlorogenic acid (CA) at neutral and acidic pH (pH 7.2 and 2.4). Tryptophan fluorescence revealed that compared to proteins sonicated at 20% and 50% amplitudes, 35%-amplitude ultrasound pre-treatment (ULG-35) strengthened the binding affinities of EGCG/CA to β-LG without altering the main interaction force. After phenolic addition, ULG-35 displayed a similar but a greater extent of protein secondary and tertiary structural changes than the native protein, ascribed to the ultrasound-driven hydrophobic stacking among interacted molecules. The dominant form of β-LG (dimer/monomer) played a crucial role in the conformational and interfacial properties of complexes, which can be explained by the distinct binding sites at different pH as unveiled by molecular docking. Combining pre-ultrasound with EGCG interaction notably increased the foaming and emulsifying properties of β-LG, providing a feasible way for the modification of bovine whey proteins. These results shed light on the understanding of protein–phenolic non-covalent binding under ultrasound and help to develop complex systems with desired functionality and delivery. 相似文献
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采用基于密度泛函理论的第一性原理赝势平面波方法对Sc、Ce单掺和共掺后CrSi2的几何结构、电子结构、复介电函数、吸收系数和光电导率进行了计算。结果表明:Sc、Ce掺杂CrSi2的晶格常数增大,带隙变小。本征CrSi2的带隙为0.386 eV,Sc、Ce单掺及共掺CrSi2的禁带宽度分别减小至0.245 eV、0.232 eV、0.198 eV,费米能级均向低能区移动进入价带。由于Sc的3d态电子和Ce的4f态电子的影响,Sc、Ce掺杂的CrSi2在导带下方出现了杂质能级。掺杂后的CrSi2介电函数虚部第一介电峰峰值增加且向低能方向移动,说明Sc、Ce掺杂使得CrSi2在低能区的光跃迁强度增强,Sc-Ce共掺时更明显。Sc、Ce掺杂的CrSi2吸收边在低能方向发生红移,在能量大于21.6 eV特别是在位于31.3 eV的较高能量附近,本征CrSi2几乎不吸收光子,Sc单掺和Sc-Ce共掺CrSi2吸收光子的能力有所增强,并在E=31.3 eV附近形成了第二吸收峰。说明掺杂Sc、Ce改善了CrSi2对红外和较高能区光子的吸收。在小于3.91 eV的低能区掺杂后的CrSi2光电导率增加。在20.01 eV<E<34.21 eV时,本征CrSi2光电导率为零,但Sc、Ce掺杂后的体系不为零,掺杂拓宽了CrSi2的光响应范围。研究结果为CrSi2基光电器件的应用与设计提供了理论依据。 相似文献
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《Operations Research Letters》2021,49(4):548-552
In this paper, we employ an asymptotic assumption to show that the maximum of finitely many convex polynomials is an asymptotically well behaved function. We also give two examples to illustrate our main result. As an application, we reproduce some known results appeared recently in the literature. 相似文献
7.
A solution (10%, w/v) of whey protein soluble aggregates (WPISA) was pretreated with high-intensity ultrasound (HUS, 20 kHz) for different durations (10–40 min) before incubation with transglutaminase (TGase) to investigate the effect of HUS on the structural, physicochemical, rheological, and gelation properties of TGase cross-linked WPISA. Sodium dodecyl sulfate polyacrylamide gel electrophoresis (SDS-PAGE) results showed that HUS increased the amounts of high-molecular-weight polymers/aggregates in WPISA after incubation with TGase. HUS significantly increased (P < 0.05) the degree of TGase-mediated cross-linking in WPISA, as demonstrated by a reduction in free amino group contents. HUS significantly increased (P < 0.05) the particle size, intrinsic fluorescence intensity, and surface hydrophobicity of TGase cross-linked WPISA, but had no significant impact (P > 0.05) on the zeta-potential or total free sulfhydryl group content of TGase cross-linked WPISA. The apparent viscosity and the consistency index of TGase cross-linked WPISA were significantly increased by HUS (P < 0.05), which indicated that HUS facilitated the formation of more high-molecular-weight polymers. HUS significantly increased (P < 0.05) the water holding capacity and gel strength of glucono-δ-lactone (GDL)-induced TGase cross-linked WPISA gels. The results indicated that HUS could be an efficient tool for modifying WPISA to improve its degree of TGase-mediated cross-linking, which would lead to improved rheological and gelation properties. 相似文献
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Haicun Yang Shuipi Cai Yu Jiang Zheng Cao Wenzhong Ma Fanghong Gong Guoliang Tao Chunlin Liu 《Journal of polymer science. Part A, Polymer chemistry》2022,60(10):1571-1587
The commonly used multi-center initiation methods always lead to the formation of quantities of homopolymer in the surface tailoring based on reverse atom transfer radical polymerization (ATRP) and reversible addition-fragmentation chain-transfer (RAFT) polymerization. In this study, a monocenter redox pair constructed of silica bearing tert-butyl hydroperoxide groups and ascorbic acid (SiO2-TBHP/AsAc) was applied to substitute the commonly used initiation method of R-supported RAFT grafting polymerization. All the propagating radicals were restricted on the surface of solid particles during the whole procedure theoretically, resulting in a higher grafting efficiency of 95.1% combined with the “controllable” feature at 10 h. This redox pair was also used to initiate the reverse ATRP in miniemulsion successfully with a grafting efficiency of 86.3% at 10 h. The grafting efficiency obtained under this monocenter initiation method was significantly higher than that of the frequently reported surface modification by reverse ATRP and RAFT polymerization. In addition, the high-efficient surface tailoring was traced and confirmed by nuclear magnetic resonance, Fourier transform infrared, X-ray photoelectron spectroscopy, thermogravimetric analysis, transmission electron microscopy, and other analysis tests. The advantage of this monocenter redox pair will open a new avenue for the potential “high-efficient” surface tailoring of various materials. 相似文献
10.
Yuejun Ding 《中国物理 B》2022,31(6):68201-068201
Na-ion batteries (NIBs) are regarding as the optimum complement for Li-ion batteries along with the rapid development of stationary energy storage systems. In order to meet the commercial demands of cathodes for NIBs, O3-type Cu containing layered oxide Na0.90Cu0.22Fe0.30Mn0.48O2 with good comprehensive performance and low-cost element components is very promising for the practical use. However, only part of the Cu3+/Cu2+ redox couple participated in the redox reaction, thus impairing the specific capacity of the cathode materials. Herein, Mg2+-doped O3-Na0.90Mg0.08Cu0.22Fe0.30Mn0.40O2 layered oxide without Mn3+ was synthesized successfully, which exhibited improved reversible specific capacity of 118 mAh/g in the voltage range of 2.4-4.0 V at 0.2 C, corresponding to the intercalation/deintercalation of 0.47 Na+ (0.1 more than that of Na0.90Cu0.22Fe0.30Mn0.48O2). This work demonstrates an important strategy to obtain advanced layered oxide cathodes for NIBs. 相似文献