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1.
Circularly polarized luminescence (CPL) has attracted attention as a next-generation light signal because of its carrying more information compared with normal and linearly polarized lights as well as its potential wide application in information fields. Recently, much attention has been paid to small organic molecules-based CPL emitters because of easy synthesis, fine structural modification at molecular level, and tunable wide range emission wavelength. This review highlights the development of small organic molecules-based CPL emitters in the past 5 years (2017–2021). The progress suggests that small organic molecules-based CPL emitters provide a simple and efficient way to generate CPL. 相似文献
2.
从头发的结构和组成出发分析头发形状和颜色改变的可能性,剖析烫发、染发的化学原理,阐释先烫发后染发的本质原因,从化学视角辨证地看待烫发、染发的利弊。 相似文献
3.
Yosselin Huentupil Patricio Chung Néstor Novoa A. Hugo Klahn Manuela E. Medina Jonathan Cisterna Iván Brito Andrés Rivera Rodrigo López-Muñoz Rodrigo Arancibia 《应用有机金属化学》2020,34(9):e5788
In the research of new compounds with multifunctional applications, heterobinuclear palladium (II) complexes based on organometallic dithiocarbazates (DTCZs) have been isolated. The organometallic DTCZ ligands of the general formula [{(η5-C5H4)-CH=NNHC(S)SCH3}]MLn [MLn = Re (CO)3 ( 2a ); Mn (CO)3 ( 2b ); FeCp ( 2c )] were prepared by the reaction between formyl organometallic precursors ( 1a−c ) with S-methyldithiocarbazate. Subsequently, a two-step reaction of 2a−c with: (i) K2[PdCl4] and (ii) PPh3 yielded heterobinuclear complexes [Pd{MLn(η5-C5H4)-CH=NNHC(S)SCH3}–(Cl)(PPh3)] [MLn = Re (CO)3 ( 3a ); Mn (CO)3 ( 3b ); FeCp ( 3c )]. All compounds were characterized by conventional spectroscopic techniques (infrared spectroscopy, nuclear magnetic resonance spectroscopy, mass spectrometry and elemental analysis). In addition, the molecular structures of 2a , 2c and 3c were determined by single-crystal X-ray diffraction. The new palladium (II) complexes ( 3a−c ) were evaluated as antiproliferative agents against non-small cell lung cancer cells (H1299 cells). Complexes 3a and 3b containing cyrhetrenyl- and cymantrenyl-DTCZ ligands, respectively, were more active than their ferrocenyl analogue 3c . The activity was associated with the electron-withdrawing properties of the (η5-C5H4)M (CO)3 moieties and their better lipophilicity than that of the ferrocenyl analogue. In addition, we studied the capacity of metalloligands ( 2a−c ) and palladium (II) complexes ( 3a−c ) to remove methylene blue in water under UV–visible light irradiation. The results established that the complexes showed moderate efficiency and were less active than their corresponding free ligands. 相似文献
4.
ABSTRACTA novel BODIPY-based dye with highly emissive character was configured by Sonogashira coupling and routinely characterized by NMR and MS technology. The emission of dye was investigated in solution/film/solid and shows intensive emission. In solution, the emission peak appeared around 510 nm with little influence by the polar environment. The terthiophene plays an effective antenna effect, harvesting the light and transferring the energy to BODIPY. The pseudo Stoke's shift enlarged to ~170 nm in solution. In film, the emission peak shifted to 563 nm in polycarbonate matrix. And it shifted further to 585 nm in solid due to the highly twisted structure, which avoided closely regular-tight packing. The dye rendered an intense fluorescence, good optothermal stability, and high fluorescence quantum yield (0.55). The solid emission showed highly red emission with Commission Internationale de L'Eclairage (CIE) coordinates of (X = 0.69, Y = 0.31). Thus, the synthesized dye is idea candidate for emitting materials. 相似文献
5.
Lorenzo Milli Dr. Nicola Zanna Andrea Merlettini Matteo Di Giosia Dr. Matteo Calvaresi Prof. Maria Letizia Focarete Prof. Claudia Tomasini 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(34):12106-12112
We present herein the preparation of four different hydrogels based on the pseudopeptide gelator Fmoc‐l ‐Phe‐d ‐Oxd‐OH (Fmoc=fluorenylmethyloxycarbonyl), either by changing the gelator concentration or adding graphene oxide (GO) to the water solution. The hydrogels have been analysed by rheological studies that demonstrated that pure hydrogels are slightly stronger compared to GO‐loaded hydrogels. Then the hydrogels efficiency to trap the cationic methylene blue (MB) and anionic eosin Y (EY) dyes has been analyzed. MB is efficiently trapped by both the pure hydrogel and the GO‐loaded hydrogel through π–π interactions and electrostatic interactions. In contrast, the removal of the anionic EY is achieved in less satisfactory yields, due to the unfavourable electrostatic interactions between the dye, the gelator and GO. 相似文献
6.
《Arabian Journal of Chemistry》2020,13(2):3633-3638
A new water-insoluble organic dye, namely, 2-((10-decyl-10H-phenothiazin-3-yl)methylene)malononitrile, was synthesized and fully characterized. It was envisioned that photocatalytic decolourization of a dye-containing long chain would pave the way for the photocatalytic remediation of wastewater containing toxic hydrophobic organic pollutants. Two commercially available nanoparticles, ZnO and TiO2, were selected, and their photocatalytic decolourization of the dye from aqueous medium were compared. The black UV light irradiation of the colored samples in the presence of TiO2 (P25) or ZnO resulted in their decolourization and the photocatalytic activity observed for TiO2 (P25) was better than that of ZnO. The kinetic of decolourization indicated that the process was first-order from which the rate constant was calculated. Also, the effect of pHs on the kinetic of decolourization revealed a negligible effect, indicating that the pH, although it affects the catalysts but has no effect on the organic-based hydrophobic dye and thus no effect on the photocatalytic process. 相似文献
7.
Dr. Ekaterina Y. Chernikova Dr. Daria V. Berdnikova Dr. Alexander S. Peregudov Prof. Olga A. Fedorova Dr. Yuri V. Fedorov 《Chemphyschem》2020,21(5):442-449
The photochemical isomerization of a styrylpyridinium dye ( SP ) bearing an unsymmetrically attached benzo-15-crown-5 ether has been studied in aqueous solution in the absence and presence of cucurbit[7]uril (CB[7]). The detailed analysis of the UV/Vis and NMR spectra showes that the isomeric composition of the photostationary mixtures of SP can be modulated by the host-guest complexation with CB[7]. It was found that steric hindrance caused by encapsulation of SP in the host cavity induces the exclusive formation of the anti conformer of Z- SP in contrast with the mixture of both anti and syn conformers obtained during photoisomerization of the dye without CB[7]. Remarkably, the displacement of anti Z- SP from CB[7] does not lead to the transformation of the anti Z-isomer into the syn Z-isomer pointing out the conformational memory of the system. The results provide an interesting example of the supramolecular stereorecognition by the achiral CB[7] host. 相似文献
8.
由于在染料敏化太阳能电池(dye-sensitized solar cell, DSSC)中存在染料弛豫、半导体薄膜中电子与氧化态染料分子发生反应和电子在电解质中与氧化态离子复合等不利反应,利用一个更完善的DSSC载流子传输模型对电池的光电性能进行模拟就显得非常重要。为此,本文基于由多重俘获理论建立的DSSC中的包括电子、染料阳离子、碘化物和三碘化物在内的载流子传输模型,数值模拟得到了不同TiO2薄膜厚度、不同入射光强度与不同染料分子吸收系数下DSSC的J-V曲线。结果表明,随着TiO2薄膜厚度的增加,太阳能电池的短路电流密度增大,开路电压减小,光电转换效率先增大后减小。当DSSC的TiO2薄膜厚度为20 μm时,光电转换效率达到最大值7.41%,同时光电转换效率随入射光强度与染料分子吸收系数的增大均有一定程度提高,其中在吸收系数为4 500 cm-1时,光电转换效率为6.73%。以上结果可以为改进DSSC的光电性能提供理论指导。 相似文献
9.
In recent times, polyaniline (PANI), a conducting polymer, has been studied widely for environmental remediation application due to its controllable electric conductivity with high surface area, which makes it a suitable adsorbent material. But lower mechanical stability of PANI is considered to be a serious drawback for its large-scale industrial application. To improve the mechanical strength of PANI, in this study, hematite nanoparticles were impregnated onto PANI by oxidative polymerization method in order to fabricate a novel organometallic nanocomposite (hematite-PANI-NC). The hematite-PANI-NC was used as adsorbent for removal of methyl orange (MO) and eosin yellow (EY) dye from binary dye matrix under ultrasonic-assisted adsorption. Excellent MO and EY dye removal (more than 98%) was observed from binary matrix at a wide solution pH from 2.0 to 6.0, and under ultrasound wave the adsorption equilibrium was achieved within 15 min only. Both MO and EY dyes adsorption experimental data strictly followed Langmuir isotherm, and maximum monolayer adsorption capacity of 126.58 mg/g and 112.36 mg/g was observed for MO and EY dye, respectively. The uptake mechanism of MO and EY dyes onto hematite-PANI-NC is governed by electrostatic interaction, π-π bonding and hydrogen bonding between dye molecules and nanocomposite. Response surface methodology analysis reveals maximum MO and EY removal of 98.43% and 99.35% at optimum experimental conditions. This study implies that the hybrid organometallic material hematite-PANI-NC has high potential for quick and enhanced sono-assisted uptake of anionic dyes from water near neutral solution pH. 相似文献
10.
Ceren Kütahya Nicolai Meckbach Prof. Dr. Veronika Strehmel Prof. Dr. Jochen S. Gutmann Prof. Dr. Bernd Strehmel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(46):10444-10451
NIR exposure at 790 nm activated photopolymerization of monomers comprising UV-absorbing moieties by using [CuII/(TPMA)]Br2 (TPMA=tris(2-pyridylmethyl)amine) in the ppm range and an alkyl bromide as initiator. Some of them comprised structural elements selected either from those showing proton transfer or photocycloaddition upon UV excitation. Polymers obtained comprise living end groups serving as macroinitiator for controlled synthesis of block copolymers with relatively narrow molecular weight distributions. Chromatographic results indicated formation of block copolymers produced by this synthetic approach. Free-radical polymerization of monomers pursued for comparison exhibited the expected broader dispersity of molecular weight compared to photo-ATRP. Polymerization of these monomers by UV photo-ATRP failed on the contrary to NIR photo-ATRP demonstrating the UV-filter function of the monomers. This work conclusively provides a new approach for the polymerization of monomers comprising UV-absorbing moieties through photo-ATRP in the NIR region. This occurred in a simple and efficient pathway. However, studies also showed that not all monomers chosen successfully proceeded in the NIR photo-ATRP protocol. 相似文献