首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3002篇
  免费   490篇
  国内免费   752篇
化学   3657篇
晶体学   112篇
力学   55篇
综合类   30篇
数学   4篇
物理学   386篇
  2024年   6篇
  2023年   41篇
  2022年   89篇
  2021年   103篇
  2020年   184篇
  2019年   157篇
  2018年   121篇
  2017年   119篇
  2016年   187篇
  2015年   172篇
  2014年   170篇
  2013年   348篇
  2012年   264篇
  2011年   201篇
  2010年   125篇
  2009年   151篇
  2008年   153篇
  2007年   175篇
  2006年   195篇
  2005年   194篇
  2004年   151篇
  2003年   156篇
  2002年   137篇
  2001年   89篇
  2000年   61篇
  1999年   78篇
  1998年   66篇
  1997年   50篇
  1996年   34篇
  1995年   54篇
  1994年   37篇
  1993年   29篇
  1992年   34篇
  1991年   25篇
  1990年   15篇
  1989年   11篇
  1988年   12篇
  1987年   8篇
  1986年   12篇
  1985年   5篇
  1984年   6篇
  1983年   3篇
  1982年   2篇
  1981年   2篇
  1978年   2篇
  1976年   2篇
  1975年   3篇
  1974年   1篇
  1973年   1篇
  1972年   2篇
排序方式: 共有4244条查询结果,搜索用时 0 毫秒
1.
The development of high‐surface‐area carbon electrodes with a defined pore size distribution and the incorporation of pseudo‐active materials to optimize the overall capacitance and conductivity without destroying the stability are at present important research areas. Composite electrodes of carbon nano‐onions (CNOs) and polypyrrole (Ppy) were fabricated to improve the specific capacitance of a supercapacitor. The carbon nanostructures were uniformly coated with Ppy by chemical polymerization or by electrochemical potentiostatic deposition to form homogenous composites or bilayers. The materials were characterized by transmission‐ and scanning electron microscopy, differential thermogravimetric analyses, FTIR spectroscopy, piezoelectric microgravimetry, and cyclic voltammetry. The composites show higher mechanical and electrochemical stabilities, with high specific capacitances of up to about 800 F g?1 for the CNOs/SDS/Ppy composites (chemical synthesis) and about 1300 F g?1 for the CNOs/Ppy bilayer (electrochemical deposition).  相似文献   
2.
The metallacarborane [3,3′‐Co(1,2‐closo‐C2B9H11)2]? has been synthesized. This species allows the formation of redox couples in which both partners are negatively charged. The E1/2 potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3′‐Co(1,2‐closo‐C2B9H7I4)2]? is the most favorable, as it is isolatable and stable in air. A DFT study on stability and redox potentials of complexes has been performed.  相似文献   
3.
4.
Magnetic Properties of the Cobaltates Na6CoS4, Na6CoSe4, and K6CoS4 The alkali metal cobalt chalcogenides Na6CoS4, Na6CoSe4, and K6CoS4 crystallize in the space group P63mc with Z = 4. The structure is characterized by isolated [CoX4]-tetrahedra. The magnetic susceptibilities show Curie-Weiss behaviour. The deviations at low temperatures are caused by antiferromagnetic interactions. The magnetic moments are discussed with regard to ligand-field parameters.  相似文献   
5.
Rüffer  R. 《Hyperfine Interactions》2002,141(1-4):83-97
Hyperfine Interactions - The technique of nuclear resonant scattering has spread out in various fields during the previous years. Those fields, which have rapidly developed and attracted the...  相似文献   
6.
Cobalt-doped mesoporous titania with a crystalline framework synthesized by surfactant templating method presented highly selective (99%) and reasonable conversion rate (49%) of catalytic oxidation of para-chlorotoluene to para-chlorobenzaldehyde in acetic acid using aqueous hydrogen peroxide as oxidant for the first time. Recycling of the catalyst indicates that the catalyst can be used a number of times without losing its activity to a greater extent. By contrast, cobalt-doped mesoporous titania without a crystalline structure and cobalt doped the commercial titania, Degussa P25 prepared by impregnation method with the similar concentration of cobalt were found inactive. The effects of catalyst concentration, reaction time, reaction temperature, and solvents on the performance of the catalyst were also investigated.  相似文献   
7.
酞菁钴薄膜的折射率及吸收特性   总被引:3,自引:1,他引:2  
陈启婴  顾冬红 《光学学报》1996,16(2):07-211
通过真空镀法在单晶硅片上制备了酞菁钴薄膜,在波长扫描和入射角可变全自动椭圆偏振光谱仪上研究了CoPc薄膜的椭偏光谱并分析了其电子结构。  相似文献   
8.
Cobalt oxides were prepared by three different methods: (1) by reacting cobalt nitrate with oxalic acid, (2) co-precipitating cobalt nitrate with sodium carbonate, and (3) using sodium dodecyl sulphate as organic surfactant. All three samples were characterized before and after calcination by solvent extraction and the resulting products examined by IR spectroscopy. In the case of method 3, the removal of surfactant was followed by TGA studies. Products from all three methods were identified by XRD. Peaks in low angle XRD indicate the porous nature of the oxides. The morphology of the pores was studied by transmission electron microscopy. Some irregular pore structures were obtained for samples from methods 1 and 2, with an average size of 4–6 nm. Only the product from method 3 using SDS as template showed ordered structure and optimum size, and Brunauer-Emmet-Teller surface areas of the as-prepared, as well as the treated samples, exhibited H3 type hysteresis. The samples from the three methods were used as catalysts in the oxidation reaction of cyclohexane under mild conditions and the catalytic efficiency of the cobalt oxide was comparable with mesoporous cobalt oxides.  相似文献   
9.
10.
    
The solvent extraction of cobalt(II), nickel(II) and copper(II) using 2,4-pent-dione (Hacac) and 4-phenyl-2, 4-but-dione (Hbzac) is carried out by varying the reagent concentration and pH of the aqueous phase. Each of these metals is quantitatively separated (≈ 98%) from their binary mixtures with monovalent (Ag), divalent (Mn, Zn, Cd, Hg, Mg, Sn, Pb) and trivalent (Cr, Fe) metals. The extraction constants are calculated from the metal distribution data using linear regression analysis. The extracted species is MA2 in each case. A most significant result is separation of copper(II) from iron(III) which otherwise interferes when extracted from the acidic medium.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号