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1.
Feng Cheng Shuqi Wu Wenwei Zheng Shengqun Su Takumi Nakanishi Wenhuang Xu Pritam Sadhukhan Hibiki Sejima Shimon Ikenaga Kaoru Yamamoto Kaige Gao Shinji Kanegawa Prof. Osamu Sato 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(59):e202202161
The crystallization of a complex having electron transfer properties in a polar space group can induce the polarization switching of a crystal in a specific direction, which is attractive for the development of sensors, memory devices, and capacitors. Unfortunately, the probability of crystallization in a polar space group is usually low. Noticing that enantiopure compounds crystallize in Sohncke space groups, this paper reports a strategy for the molecular design of non-ferroelectric polarization switching crystals based on the use of intramolecular electron transfer and chirality. In addition, this paper describes the synthesis of a mononuclear valence tautomeric (VT) cobalt complex bearing an enantiopure ligand. The introduction of enantiomer enables the crystallization of the complex in the polar space group (P21). The polarization of the crystals along the b-axis direction is not canceled out and the VT transition is accompanied by a change in the macroscopic polarization of the polar crystal. Polarization switching via electron transfer is realized at around room temperature. 相似文献
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A monolithic capillary column with a mixed‐mode stationary phase of reversed‐phase/hydrophilic interaction chromatography was prepared for capillary liquid chromatography. The monolith was created by an in‐situ copolymerization of a homemade monomer N,N‐dimethyl‐N‐acryloxyundecyl‐N‐(3‐sulfopropyl) ammonium betaine and a crosslinker pentaerythritol triacrylate in a binary porogen agent consisting of methanol and isopropanol. The functional monomer was designed to have a highly polar zwitterionic sulfobetaine terminal group and a hydrophobic long alkyl chain moiety. The composition of the polymerization solution was systematically optimized to permit the best column performance. The columns were evaluated by using acidic, basic, polar neutral analytes, as well as a set of alkylbenzenes and Triton X100. Very good separations were obtained on the column with the mixed‐mode stationary phase. It was demonstrated that the mixed‐mode stationary phase displayed typic dual retention mechanisms of reversed‐phase/hydrophilic interaction liquid chromatography depending on the content of acetonitrile in the mobile phase. The method for column preparation is reproducible. 相似文献
4.
Chao Tian Yuanli Liang Haixia Lin Jie Song Qi Li Rui Li 《Journal of Dispersion Science and Technology》2019,40(6):892-900
A rosin-based ester tertiary amine salt (RETAS) cationic surfactant was obtained using natural rosin as raw material. GC-MS of RETAS was detailed analyzed. The pH-responsive mechanism of rosin-based ester tertiary amine (RETA) and RETAS was confirmed by applying theoretical calculations about electrostatic potential maps of RETA and RETAS cation using Gaussian software. Mixed system surfactants were obtained by blending RETAS cationic surfactant with sodium dodecyl benzene sulfonate (SDBS) anionic surfactant. The binary mixed surfactant systems of RETAS and SDBS had obvious synergistic effect. The γcmc and CMC were 39.40?mN/m and 0.56?mmol/L at the optimum molar fraction of RETAS (α)?=?0.6, respectively. The stability time of emulsion with the optimum mixed system as emulsifier increased to 309?s at α?=?0.6. The emulsifying capacity of RETAS was much better than that of RETA. RETAS had pH-responsive targeted release and the optimum mixed system showed a relatively sustained drug release by using doxorubicin (DOX) as a model drug. These results indicate that RETAS surfactant and mixed system surfactant are both promising for applications in drug delivery and emulsification. 相似文献
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Baeyer–Villiger oxidation of cyclohexanone by molecular oxygen with Fe–Sn–O mixed oxides as catalysts 下载免费PDF全文
Fe–Sn–O mixed oxides were synthesized and used as catalysts for Baeyer–Villiger oxidation of cyclohexanone, which showed both high catalytic activity and selectivity. X‐ray powder diffraction and scanning electron microscopy suggested that the Fe–Sn–O catalysts had a tetragonal structure with a grain size of 29.3 nm. An ε‐caprolactone yield as high as 98.8% was obtained in a small‐scale experiment (5 mmol of cyclohexanone). In a scale‐up test (20 mmol of cyclohexanone), the cyclohexanone conversion and ε‐caprolactone yield were 96.7 and 96.5%, respectively. In addition, the catalysts can be reused five times without any major decline in catalytic activity. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Electrically Switchable Magnetic Molecules: Inducing a Magnetic Coupling by Means of an External Electric Field in a Mixed‐Valence Polyoxovanadate Cluster 下载免费PDF全文
Dr. Salvador Cardona‐Serra Dr. Juan M. Clemente‐Juan Prof. Eugenio Coronado Dr. Alejandro Gaita‐Ariño Dr. Nicolas Suaud Dr. Ondrej Svoboda Dr. Roland Bastardis Prof. Nathalie Guihéry Dr. Juan J. Palacios 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(2):763-769
Herein we evaluate the influence of an electric field on the coupling of two delocalized electrons in the mixed‐valence polyoxometalate (POM) [GeV14O40]8? (in short V14) by using both a t‐J model Hamiltonian and DFT calculations. In absence of an electric field the compound is paramagnetic, because the two electrons are localized on different parts of the POM. When an electric field is applied, an abrupt change of the magnetic coupling between the two delocalized electrons can be induced. Indeed, the field forces the two electrons to localize on nearest‐neighbors metal centers, leading to a very strong antiferromagnetic coupling. Both theoretical approaches have led to similar results, emphasizing that the sharp spin transition induced by the electric field in the V14 system is a robust phenomenon, intramolecular in nature, and barely influenced by small changes on the external structure. 相似文献
8.
针对RV减速器角接触球轴承承受预紧力、轴向力和径向力等联合外载荷作用的工况,分析得出了内、外圈滚道接触界面的接触区几何参数和接触载荷.在此基础上,综合考虑了角接触球轴承的接触区宏观几何、接触载荷、真实表面粗糙度、瞬态效应等因素,建立了角接触球轴承混合润滑数学模型,分析了在不同工况下角接触轴承的润滑状况及表面以下应力分布.结果表明:随着载荷的不断增加,钢球与内圈沟道之间的油膜厚度会不断减少,导致干接触面积迅速扩大,接触点表面以下最大应力增大;转速的增加会使油膜变厚,干接触面积缩小.该结果对角接触球轴承的实际工程应用具有重要借鉴意义. 相似文献
9.
基于载荷分担理论的渐开线斜齿轮热混合弹流润滑分析 总被引:5,自引:4,他引:1
沿接触线把斜齿轮分成许多小薄片,每一薄片看成具有当量角速度的直齿轮,根据欧拉方程得到任一接触点处的曲率半径和表面速度.然后基于载荷分担、弹流润滑和粗糙线接触理论,建立了考虑表面粗糙度的斜齿轮传动混合热弹流润滑模型.研究了斜齿轮传动稳态载荷分布下牛顿流体和Carreau流体时的润滑特性.结果表明:牛顿流体和Carreau非牛顿流体模型下,中心油膜厚度、油膜承载比例、油膜温升随时间和接触线的变化规律相同.牛顿流体下的摩擦系数较工程实际偏大.Carreau非牛顿流体模型下摩擦系数和工程实际相符,其随接触线啮合位置的变化规律与油膜厚度正好相反. 相似文献
10.
Hideaki Murasugi Dr. Shohei Kumagai Dr. Hiroaki Iguchi Prof. Dr. Masahiro Yamashita Dr. Shinya Takaishi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(42):9885-9891
Crystal structures of a series of organic–inorganic hybrid gold iodide perovskites, formulated as A2[AuII2][AuIIII4] [A=methylammonium (MA) ( 1 ) and formamidinium (FA) ( 2 )], A′2[I3]1−x[AuII2]x[AuIIII4] [A′=imidazolium (IMD) ( 3 ), guanidinium (GUA) ( 4 ), dimethylammonium (DMA) ( 5 ), pyridinium (PY) ( 6 ), and piperizinium (PIP) ( 7 )], systematically changed depending on the cation size. In addition, triiodide (I3−) ions were partly incorporated into the AuI2− sites of 3 – 7 , whereas they were not incorporated into those of 1 and 2 . Such a difference comes from the size of the organic cation. Optical absorption spectra showed characteristic intervalence charge-transfer bands from AuI to AuIII species, and the optical band gap increased as the size of the cation became larger. 相似文献