首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   27138篇
  免费   1760篇
  国内免费   1530篇
化学   15956篇
晶体学   153篇
力学   388篇
综合类   63篇
数学   6419篇
物理学   7449篇
  2023年   201篇
  2022年   336篇
  2021年   938篇
  2020年   619篇
  2019年   714篇
  2018年   437篇
  2017年   492篇
  2016年   611篇
  2015年   696篇
  2014年   923篇
  2013年   1839篇
  2012年   1177篇
  2011年   1308篇
  2010年   1200篇
  2009年   1617篇
  2008年   1683篇
  2007年   1903篇
  2006年   1400篇
  2005年   784篇
  2004年   672篇
  2003年   869篇
  2002年   857篇
  2001年   840篇
  2000年   559篇
  1999年   438篇
  1998年   445篇
  1997年   325篇
  1996年   408篇
  1995年   365篇
  1994年   373篇
  1993年   406篇
  1992年   349篇
  1991年   208篇
  1990年   161篇
  1989年   136篇
  1988年   152篇
  1987年   190篇
  1986年   200篇
  1985年   308篇
  1984年   223篇
  1983年   137篇
  1982年   281篇
  1981年   462篇
  1980年   425篇
  1979年   463篇
  1978年   369篇
  1977年   279篇
  1976年   241篇
  1974年   74篇
  1973年   149篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
These days, an important concern in water contamination is the remaining dyes from various sources (for instance, dye and dye intermediates industries, pulp and paper industries, textile industries, craft bleaching industries, tannery, and pharmaceutical industries, etc.), and a broad range of persistent organic contamination has been entered to the wastewater treatment systems or natural water supplies. Indeed, it is extremely hazardous and toxic to the living organism. Therefore, it is necessary to remove these organic pollutants before releasing them into the environment. Photocatalysis is a quickly growing technology for sewage procedures. For this purpose, Cu2HgI4 nanostructures were prepared via facile, and cost-effective sonochemical method. The effect of varied circumstances, such as various surfactants, sonication power, and sonication time was considered on the crystallinity, structure, shape, and particle size of products. Cu2HgI4 possesses a suitable bandgap (2.2 eV) in the visible area. The photocatalytic performance of the Cu2HgI4 was surveyed for the elimination of various organic dyes under visible radiation and exposed that this compound could degrade and remove methyl orange about 94.2% in an acidic medium after 160 min under visible light. Besides, the result showed that various parameters, including, pH, dye concentration, types of dyes, catalyst dosages, and time of irradiation affected the photocatalytic efficiency.  相似文献   
2.
In this article, a way to employ the diffusion approximation to model interplay between TCP and UDP flows is presented. In order to control traffic congestion, an environment of IP routers applying AQM (Active Queue Management) algorithms has been introduced. Furthermore, the impact of the fractional controller PIγ and its parameters on the transport protocols is investigated. The controller has been elaborated in accordance with the control theory. The TCP and UDP flows are transmitted simultaneously and are mutually independent. Only the TCP is controlled by the AQM algorithm. Our diffusion model allows a single TCP or UDP flow to start or end at any time, which distinguishes it from those previously described in the literature.  相似文献   
3.
《中国物理 B》2021,30(5):56501-056501
Thermal expansion control is always an obstructive factor and challenging in high precision engineering field. Here,the negative thermal expansion of Nb F_3 and Nb OF_2 was predicted by first-principles calculation with density functional theory and the quasi-harmonic approximation(QHA). We studied the total charge density, thermal vibration, and lattice dynamic to investigate the thermal expansion mechanism. We found that the presence of O induced the relatively strong covalent bond in Nb OF_2, thus weakening the transverse vibration of F and O in Nb OF_2, compared with the case of Nb F_3.In this study, we proposed a way to tailor negative thermal expansion of metal fluorides by introducing the oxygen atoms.The present work not only predicts two NTE compounds, but also provides an insight on thermal expansion control by designing chemical bond type.  相似文献   
4.
Chinese Annals of Mathematics, Series B - In the present article, the authors find and establish stability of multiplier ideal sheaves, which is more general than strong openness.  相似文献   
5.
The synthesis and characterizations for a series of dinuclear gold (I)-di-NHC complexes, 1–8 through the trans-metalation method of their respective silver (I)-di-NHC complexes, i–viii are reported (where NHC = N-heterocyclic carbene). The successful complexation of a series of unusual non-symmetrical and symmetrical di-NHC ligands, 3,3'-(ethane-1,2-diyl)-1-alkylbenzimidazolium-1'-butylbenzimidazolium (with alkyl = methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, benzyl) with the gold (I) ions are suggested by elemental analysis, Fourier transform-infrared, 1H- and 13C-NMR data. The 13C-NMR spectra of 1–8 show a singlet sharp peak in the range of 190.00–192.00 ppm, indicating the presence of a carbene carbon that bonded to the gold (I) ion. From single crystal X-ray diffraction data, the structure of complex 6 with the formula of [di-NHC-Au (I)]2·2PF6 is obtained [where NHC = 3,3'-(ethane-1,2-diyl)-1-hexylbenzimidazolium-1'-butylbenzimidazolium]. The photophysical study in solid state of 6 displays an intense photoluminescence with a strong emission maxima, λem = 480 nm, upon excitation at 340 nm at room temperature. Interestingly, the emission maximum at 77 K shows a structural character with a strong peak at 410 nm, a medium at 433 nm and a weak at 387 nm, accompanied by a tail band to about 500 nm.  相似文献   
6.
Huihui Zhu 《代数通讯》2018,46(8):3388-3396
Let R be an associative ring with unity 1 and let a,b,cR. In this paper, several characterizations for hybrid (b,c)-inverses of a are given. Also, the hybrid (b,c)-inverse of a is characterized by the group inverse of ab, under certain hypothesis. In particular, existence criteria for the the inverse along an element are obtained. Finally, we get the double commutant property and the reverse order law of annihilator (b,c)-inverses.  相似文献   
7.
Finite dimensional ribbon Hopf(super) algebras play an important role in constructing invariants of 3-manifolds. In the present paper, the authors give a necessary and sufficient condition for the Drinfeld double of a finite dimensional Hopf superalgebra to have a ribbon element. The criterion can be seen as a generalization of Kauffman and Radford's result in the non-super situation to the ■_2-graded situation, however, the derivation of the result in the ■_2-graded case will be much more complicated.  相似文献   
8.
NIFTy , “Numerical Information Field Theory,” is a software framework designed to ease the development and implementation of field inference algorithms. Field equations are formulated independently of the underlying spatial geometry allowing the user to focus on the algorithmic design. Under the hood, NIFTy ensures that the discretization of the implemented equations is consistent. This enables the user to prototype an algorithm rapidly in 1D and then apply it to high‐dimensional real‐world problems. This paper introduces NIFTy  3, a major upgrade to the original NIFTy  framework. NIFTy  3 allows the user to run inference algorithms on massively parallel high performance computing clusters without changing the implementation of the field equations. It supports n‐dimensional Cartesian spaces, spherical spaces, power spaces, and product spaces as well as transforms to their harmonic counterparts. Furthermore, NIFTy  3 is able to handle non‐scalar fields, such as vector or tensor fields. The functionality and performance of the software package is demonstrated with example code, which implements a mock inference inspired by a real‐world algorithm from the realm of information field theory. NIFTy  3 is open‐source software available under the GNU General Public License v3 (GPL‐3) at https://gitlab.mpcdf.mpg.de/ift/NIFTy/tree/NIFTy_3 .  相似文献   
9.
10.
A simple, sensitive and rapid ultra‐high‐performance liquid chromatography–electrospray ionization–tandem mass spectrometry method was developed and validated for the quantification of warfarin and 7‐hydroxy warfarin in Sprague Dawley (SD) rats. Animals were administered a single dose of warfarin sodium formulations (crystalline and amorphous) at 12 mg/kg via oral gavage and blood was drawn over a 96‐h time course. Sample process recoveries, matrix effect and analyte stability were determined. The linearity for warfarin and 7‐hydroxy warfarin was from 5 to 2000 ng/mL in blank SD rat plasma. Correlation coefficients (r2) for standard calibration curves were >.98 and analytes quantified within ±15% of target at all calibrator concentrations. The average percent accuracy and precision for intra‐ and inter‐day were 93.7%–113.8% and ≤12.1%, respectively, for warfarin and 7‐hydroxy warfarin, across the quality control standards (5, 10, 500, 1800 and 2000 ng/mL). Acceptable analytical recovery (>55%) was achieved with process efficiencies >41.5% and matrix effects <139.9% over the analytical range. Both analytes were stable in stock solution, autosampler, benchtop and three cycles of freeze–thaw with percent accuracy ≥90.2% and precision (percent relative standard deviation) ≤14%. The validated method was successfully applied to a pre‐clinical bioavailability study of crystalline and amorphous warfarin sodium formulations in SD rats.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号