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1.
本文在加权广义Schur补的基础上, 引入并研究了Hilbert空间上分块算子矩阵的加权Moore-Penrose逆和加权EP. 进一步, 给出了加权EP算子在算子方程中的一个应用.  相似文献   
2.
高玥  卢铃  吴鸣  杨军  曹寅 《应用声学》2022,41(1):12-20
基于传声器阵列的声成像技术是解决噪声源识别的有效途径之一。该文提出了一种基于球谐分解的L2范数广义逆波束形成算法,并对此算法在分布式球形阵列布放方案下进行了定位精度及鲁棒性的对比分析研究。仿真结果显示,此算法对低频相干声源具有较高的空间定位精确度,且阵元位置误差对此算法性能的影响有限。通过在半消声室进行实验进一步证明了此算法的可行性。  相似文献   
3.
Double emulsions have been extensively used in scientific researches and industrial applications due to their attractive unique feature of multiple phases. However, constructing droplets with such a complex structure is not a simple task for all time. The simultaneous existence of two contradictory interfaces makes it hard to prepare stable double emulsions in principle and in practice. Over the past century, tremendous efforts have been devoted by myriads of scientists to make progresses in both theory and preparation of double emulsions. In this review, the current understanding of double emulsions is systematically revealed. In addition to emphasizing the corresponding pioneer and landmark works as many as possible, the state-of-the-art achievements will also be discussed. By regulating the oil-water interface with smartly designed interface-active agents in combination with varying the phase volume fractions, the basic theory framework based on the phase inversion from simple emulsions to double emulsions is also summarized. Technical preparation strategies of emulsification are introduced to show the building process of the two contradictory interfaces in one system. Furthermore, some specific biomedical applications of double emulsions are also discussed, which is expected to stimulate further innovation and utilization of double emulsions.  相似文献   
4.
人体逆向运动学问题是人体运动合成、人体运动捕获和理解的基本问题.由于人体关节链式系统的复杂性,人体逆向运动学方程往往存在多解或无解的情形.传统的方法通常采用解析或数值迭代方法求解逆向运动学问题,在给定足够多约束的情形下能够得到比较好的解,但无法处理少量约束下生成自然的人体姿态问题.近年来,从大规模数据集中学习统计模型参数的思想被广泛运用,求解人体逆向运动学的机器学习方法中经典工作|混合Gauss逆向运动求解模型(Gaussian mixture model-inverse kinematics,GMM-IK)就提出利用混合Gauss模型建模人体姿态数据分布,并采用期望最大化方法求解参数.随着深度学习技术的发展,本文提出一种自编码神经网络与数值迭代融合的方法,在给定少量约束的情形下依然能够得到自然的人体姿态,相较于GMM-IK方法,本文所提出的方法通过神经网络自动学习姿态分布,省去了模型的假设和特征的设计,且量化实验显示本文方法的关节坐标和角度重建误差相较于GMM-IK模型平均减少了25%和39%.在应用方面,本文方法可处理光学运动捕获数据,也可用于图像视频的人体姿态估计等领域.  相似文献   
5.
The rational selection of organic reactions in polymer synthesis is an important research content of polymer science. In recent years, multicomponent reaction as an efficient and green synthesis method has attracted the wide attention of researchers, injecting new and powerful vitality into the field of polymer synthesis. In the study of multicomponent reaction, researchers found the intersection of multicomponent reaction and click chemistry and put forward the concept of Multicomponent Click Reaction (MCR-Click), which is a kind of Multicomponent Reaction with high activity, atomic economy, and some green chemical properties. The application of MCR in polymer chemistry is reviewed in this paper. It is expected that this reaction will arouse the attention of polymer chemists and play a new role in polymer science.  相似文献   
6.
郑琦  黄立  包德亮  武荣庭  李彦  林晓  杜世萱  高鸿钧 《中国物理 B》2022,31(1):18202-018202
The linkage structures between monomers make great influence on the properties of polymers.The synthesis of some special linkage structures can be challenging,which is often overcome by employing special reaction conditions.Here,we build dihydropentalene linkage in poly-naphthalocyanine on Ag(110)surface.Scanning tunneling microscopy(STM)and non-contact atomic force microscopy(nc-AFM)measurements confirm the dihydropentalene linkage structure and a possible formation path with reconstruction steps is proposed.The controlled experiment on Ag(100)surface shows no dihydropentalene structures formed,which indicates the grooved substrate is necessary for the reconstruction.This work provides insights into the surface restricted reactions that can yield special structures in organic polymers.  相似文献   
7.
Removal of metal ions from water can not only alleviate the scaling problem of domestic and industrial water, but also solve the water safety problem caused by heavy metal ion pollution. Here, we fabricate a positively charged nanofiltration membrane via surfactant-assembly regulated interfacial polymerization(SARIP) of 2-methylpiperazine(MPIP) and trimesoyl chloride(TMC). Due to the existence of methyl substituent, MPIP has lower reactive activity than piperazine(PIP) but stronger affinity to hexane, resulting in a nanofiltration(NF) membrane with an opposite surface charge and a loose polyamide active layer. Interestingly, with the help of sodium dodecyl sulfate(SDS) assembly at the water/hexane, the reactivity between MPIP and TMC was obviously increased and caused in turn the formation of a positively charged polyamide active layer with a smaller pore size, as well as with a narrower pore size distribution. The resulting membrane shows a highly efficient removal of divalent cations from water, of which the rejections of MgCl2, CoCl2 and NiCl2 are higher than 98.8%, 98.0% and 98.0%, respectively, which are better than those of most of other positively charged NF membranes reported in literatures.  相似文献   
8.
高性能功能材料在诸多领域具有广泛的应用前景,是人们一直关注的研究热点。高压可以有效地改变物质的原子间距和成键方式,是获得新型功能材料的重要途径。在碳材料的高压研究中,许多有趣的功能碳材料,如光学透明碳、高强度弹性碳和超硬非晶碳等,已经通过不同的碳前驱体合成。本文简要介绍了作者近年来在低维碳基纳米复合材料高压研究中取得的进展,基于设计的不同低维碳前驱体,高压下截获了具有超硬特性、新型压致共价聚合及发光增强的碳材料。  相似文献   
9.
The synthesis of nontoxic plasticizers derived from the waste residues of the rosin-processing industry can reduce pollution and promote the high-value utilization of the waste residues of rosin. In this study, four kinds of sustainable branched plasticizers derived from a biomass resource, eugenol (derived from the waste residues of the rosin processing industry), were synthesized via one-pot solvent free polymerization and used to plasticize polyvinyl chloride (PVC). Internally plasticized PVC was fabricated using thiolated DPE (branched plasticizers based on eugenol). The thermal stability, tensile properties, microstructure, volatility behavior, and solvent extraction resistance of plasticized PVC were investigated. Compared with the behavior of the commercial plasticizer dioctyl phthalate, the thermal stability, plasticizing efficiency, and migration resistance of the branched plasticizers are superior. The acute oral toxicity dose of each branched plasticizer was extremely high at 5000 mg/kg of body weight, with no deaths among test animals. Compared with externally plasticized PVC, the internally plasticized PVC showed zero weight loss in volatility and leaching tests despite its less effective plasticization. All the branched plasticizers have potential application in plastic products.  相似文献   
10.
By combined power evolution laws of the spectral parameter and the initial constants of integration,a new differential-difference hierarchy is presented from the Toda spectral problem.The hierarchy contains the classic Toda lattice equation,the nonisospectral Toda lattice equation and the mixed Toda lattice equation as reduced cases.The evolution of the scattering data in the inverse scattering transform is analyzed in detail and exact soliton solutions are computed through the corresponding inverse scattering transform.  相似文献   
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