全文获取类型
收费全文 | 9661篇 |
免费 | 1482篇 |
国内免费 | 1598篇 |
专业分类
化学 | 10773篇 |
晶体学 | 327篇 |
力学 | 45篇 |
综合类 | 45篇 |
数学 | 11篇 |
物理学 | 1540篇 |
出版年
2024年 | 10篇 |
2023年 | 152篇 |
2022年 | 205篇 |
2021年 | 379篇 |
2020年 | 582篇 |
2019年 | 439篇 |
2018年 | 383篇 |
2017年 | 383篇 |
2016年 | 546篇 |
2015年 | 580篇 |
2014年 | 578篇 |
2013年 | 1052篇 |
2012年 | 647篇 |
2011年 | 537篇 |
2010年 | 508篇 |
2009年 | 535篇 |
2008年 | 580篇 |
2007年 | 654篇 |
2006年 | 602篇 |
2005年 | 587篇 |
2004年 | 515篇 |
2003年 | 427篇 |
2002年 | 278篇 |
2001年 | 195篇 |
2000年 | 177篇 |
1999年 | 149篇 |
1998年 | 134篇 |
1997年 | 144篇 |
1996年 | 143篇 |
1995年 | 145篇 |
1994年 | 101篇 |
1993年 | 74篇 |
1992年 | 74篇 |
1991年 | 33篇 |
1990年 | 26篇 |
1989年 | 27篇 |
1988年 | 25篇 |
1987年 | 25篇 |
1986年 | 24篇 |
1985年 | 22篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 7篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1978年 | 3篇 |
1977年 | 7篇 |
1976年 | 6篇 |
1975年 | 3篇 |
1973年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
水热合成法制备了不同磁性纳米洋葱碳(MCNOs)负载量(0%、1%、3%、5%)的MCNOs/CdS光催化剂。并通过X射线衍射分析(XRD)、扫描电子显微镜(SEM)、傅里叶红外光谱(FT-IR)、X射线光电子能谱(XPS)、紫外可见光光谱(UV-Vis)、磁滞回线测定仪(VSM)对其进行表征,探究了MCNOs负载比例对催化剂在可见光下降解RhB性能及机理的影响。结果表明,MCNOs能有效提高CdS的光催化效果,复合3%MCNOs后降解率为96%,与纯CdS相比降解率提高了30%,磁性分析表明,其具有良好的顺磁性并能实现催化剂的有效回收。MCNOs/CdS在可见光下催化降解RhB的一级反应动力学直线有较好的拟合度,表明制备的催化剂有较好的催化活性。 相似文献
2.
Jiraya Kiriratnikom Xun Zhang Xiaohan Cao Bo Chu Chengjian Zhang Xinghong Zhang 《Journal of polymer science. Part A, Polymer chemistry》2022,60(15):2262-2268
Facile construction of sulfur-rich polymers using readily available raw chemicals is an area aggressively pursued but challenging. Herein we use common feedstocks of ethylene oxide (EO), propylene oxide (PO), and carbonyl sulfide (COS) to synthesize copoly(thioether)s which are traditionally produced from unpleasant and difficult to store episulfides. In this protocol, the EO/COS coupling selectively generates a pure poly(ethylene sulfide) (PES) with melting temperature (Tm) values up to 172°C and high yields up to 98%. The EO/PO/COS terpolymerization leads to the incorporation of soft poly(propylene sulfide) (PPS) and hard PES segments together, affording a random PES-co-PPS copoly(thioether) with the complete consumption of EO and PO. Additionally, by simply varying the EO/PO feeding ratio, the obtained copoly(thioether)s possess tunable thermal properties, Tm values in the range of 76–144°C, and excellent solubility. These copolymerizations are conducted in one-pot/one-step at industrially favored reaction temperatures of 100–120°C using catalysts of common organic bases, suggesting a facile and practical manner. Especially, the copoly(thioether) exhibits high refractive indices up to 1.68 owing to its high sulfur content, suggesting a broad application prospect in optical materials. 相似文献
3.
Haruki Inoue Dr. Shin-ichi Naya Atsunobu Akita Dr. Hisashi Sugime Prof. Dr. Hiroaki Tada 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(46):e202201653
Gold nanoparticles with different mean sizes were formed on antimony-doped tin oxide nanocrystals by the temperature-varied deposition-precipitation method (Au/ATO NCs). Au/ATO NCs possess strong absorption in the near-infrared region due to Drude excitation in addition to the localized surface plasmon resonance (LSPR) of AuNPs around 530 nm. Au/ATO NCs show thermally activated catalytic activity for the oxidation of cinnamyl alcohol to cinnamaldehyde by hydrogen peroxide. The catalytic activity increases with a decrease in the mean Au particle size (dAu) at 5.3 nm≤dAu≤8.2 nm. Light irradiation (λex >660 nm, ∼0.5 sun) of Au/ATO NCs increases the rate of reaction by more than twice with ∼95 % selectivity. Kinetic analyses indicated that the striking enhancement of the reaction stems from the rise in the temperature near the catalyst surface of ∼30 K due to the photothermal effect of the ATO NCs. 相似文献
4.
5.
Prof. Sławomir J. Grabowski 《Chemphyschem》2019,20(4):565-574
ωB97XD/aug-cc-pVTZ calculations were performed for complexes of dihydrogen, cyclopropane, cyclobutane and cyclopentane, with simple proton donating species such as hydrogen fluoride, hydrogen chloride, water, hydrogen cyanide and acetylene. Numerous dependencies between geometrical, energetic and topological parameters of complexes considered were found, since various theoretical approaches were applied: Quantum Theory of ‘Atoms in Molecules’ (QTAIM), Natural Bond Orbital (NBO) method and energy decomposition analysis (EDA). It was confirmed that complexes of dihydrogen and cyclopropane are linked through the A−H…σ interactions that may be classified as hydrogen bonds. In the case of complexes of cyclobutane such hydrogen bonds are rather weak. Other type and also weak A−H…C hydrogen bonds are formed for complexes with cyclopentane. 相似文献
6.
Chisa Higuchi Hiromasa Tanaka Kazunari Yoshizawa 《Journal of computational chemistry》2019,40(1):164-171
The molecular mechanism of the adhesion between silica surface and epoxy resin under atmospheric conditions is investigated by periodic density-functional-theory (DFT) calculations. Slab models of the adhesion interface were built by integrating a fragment of epoxy resin and hydroxylated (0 0 1) surface of α-cristobalite in the presence of adsorbed water molecules. Effects of adsorbed water on the adhesion interaction are evaluated on the basis of geometry-optimized structures, adhesion energies, and forces. Calculated results demonstrate that adsorbed water molecules significantly reduce both the adhesion energies and forces of the silica surface–epoxy resin interface. The reduction of adhesion properties can be associated with structural deformation of water molecules confined in the tight space between the adhesive and adherend as well as structural flexibility of the hydrogen-bonding network in the interfacial region during detachment of the epoxy resin from the hydrophilic silica surface. © 2018 Wiley Periodicals, Inc. 相似文献
7.
Wan‐Lei Yu Yong‐Chun Luo Lei Yan Dan Liu Zhu‐Yin Wang Peng‐Fei Xu 《Angewandte Chemie (International ed. in English)》2019,58(32):10941-10945
A synergistic catalytic method combining photoredox catalysis, hydrogen‐atom transfer, and proton‐reduction catalysis for the dehydrogenative silylation of alkenes was developed. With this approach, a highly concise route to substituted allylsilanes has been achieved under very mild reaction conditions without using oxidants. This transformation features good to excellent yields, operational simplicity, and high atom economy. Based on control experiments, a possible reaction mechanism is proposed. 相似文献
8.
Mo对脱合金制备的Ni-Mo电极骨架结构与析氢性能的影响 总被引:1,自引:0,他引:1
采用快速凝固结合脱合金化方法制备了不同Mo含量的纳米多孔Ni-Mo合金,通过X射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和N2吸附-脱附分析等对多孔合金的物相、形貌结构及孔径分布进行了表征,并通过线性扫描伏安、Tafel斜率、交流阻抗和循环伏安等方法测试了多孔合金电极的电催化析氢性能.结果显示,多孔合金电极材料在50 mA/cm2电流密度下析氢过电位随着Mo含量的增加先降低后升高,Ni2.5Mo2.5合金析氢活性最强,过电位为218 mV,析氢过程由Volmer-Heyrovsky步骤控制,交换电流密度为0.29 mA/cm2,经1000周循环后的极化曲线基本保持原状,50 mA/cm2电流密度下过电位增加3.67%,表现出优良的析氢稳定性. 相似文献
9.
Dhivya Manogaran 《Journal of computational chemistry》2019,40(16):1556-1569
We present a combined quantum chemical and molecular dynamics study of cyclic and noncyclic water n-mers ([(H2O]n, n = 2–6) at four different temperatures and showcase that the dynamics of small water clusters can reproduce the known properties of bulk water reasonably well. We investigate the making and breaking of the water clusters by computing the hydrogen bond strengths, average lifetimes, and relative stabilities, which are important to understand the complex solution dynamics. We compare the behavior of water clusters in the gas phase and in the solution phase as well as the variation in the properties as a function of cluster size and highlight the notably more interesting cluster dynamics of the water trimer when compared to the other water clusters. © 2019 Wiley Periodicals, Inc. 相似文献
10.
Magorzata Katarzyna Cabaj Roman Gajda Anna Hoser Anna Makal Paulina Maria Dominiak 《Acta Crystallographica. Section C, Structural Chemistry》2019,75(8):1036-1044
Crystals of hypoxanthinium (6‐oxo‐1H,7H‐purin‐9‐ium) nitrate hydrates were investigated by means of X‐ray diffraction at different temperatures. The data for hypoxanthinium nitrate monohydrate (C5H5N4O+·NO3?·H2O, Hx1 ) were collected at 20, 105 and 285 K. The room‐temperature phase was reported previously [Schmalle et al. (1990). Acta Cryst. C 46 , 340–342] and the low‐temperature phase has not been investigated yet. The structure underwent a phase transition, which resulted in a change of space group from Pmnb to P21/n at lower temperature and subsequently in nonmerohedral twinning. The structure of hypoxanthinium dinitrate trihydrate (H3O+·C5H5N4O+·2NO3?·2H2O, Hx2 ) was determined at 20 and 100 K, and also has not been reported previously. The Hx2 structure consists of two types of layers: the `hypoxanthinium nitrate monohydrate' layers (HX) observed in Hx1 and layers of Zundel complex H3O+·H2O interacting with nitrate anions (OX). The crystal can be considered as a solid solution of two salts, i.e. hypoxanthinium nitrate monohydrate, C5H5N4O+·NO3?·H2O, and oxonium nitrate monohydrate, H3O+(H2O)·NO3?. 相似文献