Electron Transport in Configurational Model of Ferromagnetic Fulleride with Triple Orbital Degeneracy

Abstract

Phenomenon of ferromagnetic ordering was for a long time associated exclusively with transition metal and rare-earth compounds. Nowadays this view is challenged by growing evidence that in molecular carbon-based systems the ferromagnetic alignment of spins can be observed as well. We have developed a microscopical model of a fulleride electronic subsystem taking into account triple orbital degeneracy of energy states within the configurational-operator approach. Using the Green function method the energy spectrum of the model has been calculated. Conditions for the ferromagnetic state stabilization have been determined. Static electrical conductivity and effective masses of current carriers in the system with orbitally degenerated energy band have been obtained. In the ground state and for low temperatures at different forms of unperturbed density of electronic states the concentration dependences of transport characteristics for less-then-half-filled lower quasiparticle subband have been calculated.     

Hybrid Isothermal Model for the Ferrohydrodynamic Chemically Reactive Species

A hybrid isothermal model for the homogeneous-heterogeneous reactions in ferrohydrodynamic boundary layer flow is established. The characteristics of Newtonian heating and magnetic dipole in a ferrofluid due to a stretchable surface is analyzed for three chemical species. It is presumed that the isothermal cubic autocatalator kinetic gives the homogeneous reaction and the first order kinetics gives the heterogeneous (surface) reaction. The analysis is carried out for equal diffusion coefficients of all autocatalyst and reactions. Heat flux is examined by incorporating Fourier's law of heat conduction. Characteristics of materialized parameters on the magneto-thermomechanical coupling in the flow of a chemically reactive species are investigated. Further, the heat transfer rate and friction drag are depicted for the ferrohydrodynamic chemically reactive species. It is evident that the Schmidt number has increasing behavior on the rate of heat transfer in the boundary layer. Comparison with available results for specific cases is found an excellent agreement.     

一维和二维镝(Ⅲ)配合物的慢磁弛豫

分别用稀土醋酸盐和稀土高氯酸盐与希弗碱配体和巯基烟酸配体反应得到了两例镝配合物[Dy₂(OAc)₆H₂O]_n(1)和{[DyL(H₂O)₄]ClO₄·H₂O}_n(2)(L=2,2'-二硫代-二(3-吡啶甲酸)),并通过单晶X-射线衍射、元素分析、红外光谱和磁性测试对其进行了表征。结构研究和磁性测试表明:化合物1是羧基桥连的一维链结构,该化合物表现出慢磁弛豫性质,有效能垒为2 K;化合物2是通过原位生成的二硫键桥连的二维网状结构,表现出明显的铁磁相互作用和慢磁弛豫行为。     

横向磁场激励下铁磁梁式板的混沌运动分析

在磁体力分布的磁弹性理论模型和磁场准静态假定模式基础上，对于处在周期时变磁场 中的不可移简支铁磁梁式板非线性磁弹性动力特性进行定性与定量分析．首先利用磁场的摄 动技术和结构变形的模态法，导出了关于模态坐标的非线性动力方程；然后利用Ｍｅｌｎｉｋｏｖ方 法，从理论上给出这一磁弹性动力系统可能出现混沌运动的必要条件及参数范围；最后采用变 步长Ｒｕｎｇｅ－Ｋｕｔｔａ数值积分方法对其磁弹性相互作用的混沌现象进行了定量搜索与模拟，并 利用其轨迹的Ｐｏｉｎｃａｒｅ截面图与Ｌｉａｐｕｎｏｖ指数加以判断．结果表明磁弹性简支梁式板在横 向周期时变磁场中存在混沌吸引子，且在机械阻尼很小时其混沌吸引子表现出稠的特性．     

含孔软铁磁材料Mindlin板中弹性波散射问题

基于考虑磁弹相互作用的Mindlin板弯曲波动方程，采用波函数展开法，分析研究 了含孔软铁磁材料Mindlin板中弹性波散射与动应力集中问题，给出了问题的分析 解和数值算例. 通过分析发现：磁感应强度对动弯矩集中系数和动剪力集中系数有 增加的作用，特别是在低频的情况下.     

MAGNETOELASTIC BENDING AND STABILITY OF SOFT FERROMAGNETIC RECTANGULAR PLATES

I.IntroductionSofar,twokindsofphenomenaofmagnetoelasticinteractiontoferromagneticplatesinappliedmagneticfieldshavebeenfound.Oneisthemagnetoelasticbuchlingorillstabllitytoacantileveredbeam-plateinatransversemagneticfieldt'],thatisthephen1Onlenollot'negiltivemagneticstiffness,whiletheotheristheincreaseofnaturalfrequencyoftheplatewhichisfreelyviratinginanin-planemagneticfieldl=],thatisthephenomenonofpositivemagneticstiffness.Inordertosimulatethesetwokindsofexperimentalphenomena,sometheoreticalmo…     

软铁磁薄板磁弹性屈曲的理论模型

铁磁弹性薄板的磁弹性屈曲问题一直作为电磁——弹性力学相互作用的一个基本模型进行研究，而作用在其磁介质上的磁力计算则是定量理论预测准确与否的关键．到目前为止，文献上已有的理论模型对悬臂铁磁梁式悬臂板在横向磁场中磁弹性屈曲的理论预测值始终高于实验值，有的甚至相差１００％左右．本文基于电磁力计算的微观安培电流模型，严格给出了软铁磁薄板等效横向磁力的宏观计算表达式．在此基础上，建立了电磁——力学相互耦合作用的非线性理论模型．该模型能描述铁磁薄板结构在非均匀横向磁场环境中的磁弹性失稳（或屈曲）．其定量分析采用了有限元法和有限差分法相结合．数值结果显示：本模型给出的磁弹性屈曲的临界磁场值与实验值符合良好．与此同时，文中还对文献中认为较成功的Ｍｏｏｎ－Ｐａｏ模型的基本假设进行了分析．定量结果发现：Ｍｏｏｎ－Ｐａｏ理论模型的基本假设仅在梁式板的长厚比Ｌ／ｈ比较大时（约在２００左右），是可以接受的，而当Ｌ／ｈ较小时，该假设将导致理论值与实验值的较大误差．Ｌ／ｈ比值越小，理论值与实验值的误差越大     

ANALYSIS ON THE MAGNETO-ELASTIC-PLASTIC BUCKLING/SNAPPING OF CANTILEVER RECTANGULAR FERROMAGNETIC PLATES

An analysis of buckling/snapping and bending behaviors of magneto-elastic-plastic interaction and coupling for cantilever rectangular soft ferromagnetic plates is presented.Based on the expression of magnetic force from the variational principle of ferromagnetic plates,the buckling and bending theory of thin plates,the Mises yield criterion and the increment theory for plastic deformation,we establish a numerical code to quantitatively simulate the behaviors of the nonlinearly multi-fields coupling problems by the finite element method.Along with the phenom- ena of buckling/snapping and bending,or the characteristic curve of deflection versus magnitude of applied magnetic fields being numerically displayed,the critical loads of buckling/snapping, and the influences of plastic deformation and the width of plate on these critical loads,the plastic regions expanding with the magnitude of applied magnetic field,as well as the evolvement of deflection configuration of the plate are numerically obtained in a case study.     

EuS/Ta异质结的极大磁电阻效应

在铁磁/超导异质结中,铁磁体的交换场通过近邻效应将导致超导体准粒子态密度的塞曼劈裂.基于该效应,在外磁场不强的情况下,通过外加磁场可以有效地调节铁磁/超导界面处的交换作用,从而实现超导体在正常态和超导态之间转换,产生极大磁电阻.本文利用脉冲激光沉积方法制备了EuS/Ta异质结并研究了其电磁特性.Ta在3.6 K以下为超导态,EuS在20 K以下为铁磁态.在2 K时,EuS/Ta异质结中可观测蝴蝶型磁滞回线,证明在低磁场下(<±0.18 T)异质结中EuS铁磁态和Ta超导态共存.磁输运测试表明,通过施加外磁场可以有效调节EuS的交换场,随着交换场的增大,同时也加强了界面处的交换作用,从而抑制Ta的超导态,实现了Ta在超导态和正常态之间的转变,在EuS/Ta异质结中观测到了高达144000%的磁电阻.本文制备的EuS/Ta异质结具有极大磁电阻效应,在自旋电子学器件中有潜在的应用前景.