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排序方式: 共有1302条查询结果,搜索用时 15 毫秒
1.
甲氧基多溴联苯醚(methoxypolybrominated diphenyl ethers, MeO-PBDEs)广泛存在于生物体和海洋环境。以象山海域的生物体和沉积物为样本,采用固相萃取净化-气相色谱-负化学源质谱法,检测了6种MeO-PBDEs,结果显示,当目标分析物浓度为0.1~20.0 μg?L-1时,线性关系良好(R2>0.999),检出限为0.13~0.22 μg?kg-1,定量限为0.42~0.72 μg?kg-1,实际样品的平均回收率为71.2%~116.2%。MeO-PBDEs的分布状况调查结果显示,藻类样品中仅检出6-MeO-BDE-47,且浓度较低,其他生物体中检出3种MeO-PBDEs,检出率为31.3%,浓度为0.21~2.72 μg?kg-1。沉积物中无MeO-PBDEs被检出。  相似文献   
2.
Lithium (Li)-based batteries are the dominant energy source for consumer electronics, grid storage, and electrified transportation. However, the development of batteries based on graphite anodes is hindered by their limited energy density. With its ultrahigh theoretical capacity (3860 mAh∙g−1), low redox potential (−3.04 V), and satisfactorily low density (0.54 g∙cm−3), Li metal is the most promising anode for next-generation high-energy-density batteries. Unfortunately, the limited cycling life and safety issues raised by dendrite growth, unstable solid electrolyte interphase, and "dead Li" have inhibited their practical use. An effective strategy is to develop a suitable lithiophilic matrix for regulating initial Li nucleation behavior and controlling subsequent Li growth. Herein, single-atom cobalt coordinated to oxygen sites on graphene (Co-O-G SA) is demonstrated as a Li plating substrate to efficiently regulate Li metal nucleation and growth. Owing to its dense and more uniform lithiophilic sites than single-atom cobalt coordinated to nitrogen sites on graphene (Co-N-G SA), high electronic conductivity, and high specific surface area (519 m2∙g−1), Co-O-G SA could significantly reduce the local current density and promote the reversibility of Li plating and stripping. As a result, the Co-O-G SA based Li anodes exhibited a high Coulombic efficiency of 99.9% at a current density of 1 mA∙cm−2 with a capacity of 1 mAh∙cm−2, and excellent rate capability (high current density of 8 mA∙cm−2). Even at a high plating capacity of 6 mAh∙cm−2, the Co-O-G SA electrode could stably cycle for an ultralong lifespan of 1300 h. In the symmetric battery, the Co-O-G SA based Li anode (Co-O-G SA/Li) possessed a stable voltage profile of 18 mV for 780 h at 1 mA∙cm−2, and even at a high current density of 3 mA∙cm−2, its overpotential maintained a small hysteresis of approximately 24 mV for > 550 h. Density functional theory calculations showed that the surface of Co-O-G SA had a stronger interaction with Li atoms with a larger binding energy, −3.1 eV, than that of Co-N-G SA (−2.5 eV), leading to a uniform distribution of metallic Li on the Co-O-G SA surface. More importantly, when matched with a sulfur cathode, the resulting Co-O-G SA/lithium sulfur full batteries exhibited a high capacity of 1002 mAh∙g−1, improved kinetics with a small polarization of 191 mV, and an ultralow capacity decay rate of 0.036% per cycle for 1000 cycles at 0.5C (1C = 1675 mA∙g−1) with a steady Coulombic efficiency of nearly 100%. Therefore, this work provides novel insights into the coordination environment of single atoms for the chemistry of Li metal anodes for high-energy-density batteries.  相似文献   
3.
在实验室里的实验教学过程涉及到教书育人、管理育人、服务育人和环境育人。一个良好的实验环境不仅能够对学生起到潜移默化的教育作用,而且对教书育人、管理育人和服务育人工作的开展和实施也能起到推动和促进作用。本文主要介绍厦门大学化学国家级实验教学示范中心"以学生为中心",在强化实验教学环境内涵建设、提高实验环境育人质量方面的一些做法和体会,以期更好地为实验教学"思政"提供可复制、可推广的建设方案。  相似文献   
4.
Solution combustion synthesis (SCS) is a worldwide used methodology for the preparation of inorganic ceramic and composite materials with controlled properties for a wide number of applications, from catalysis to photocatalysis and electrocatalysis, from heavy metal removal to sensoristics and electronics. The high versatility and efficiency of this technique have led to the introduction of many variants, which allowed important optimization to the prepared materials. Moreover, its ecofriendly nature encouraged further studies about the use of sustainable precursors for the preparation of nanomaterials for energy and environment, according to the concept of circular economy. On the other hand, the large variety of expressions to define SCS and the often-contradictory definitions of the SCS parameters witnessed a scarce consciousness of the potentiality of this methodology. In this review article, the most important findings about SCS and the selection criteria for its main parameters are critically reviewed, in order to give useful guidelines to those scientists who want to use this methodology for preparing materials with improved or new functional properties. This review aims as well (i) to bring more clarity in the SCS terminology (ii) to increase the awareness of the SCS as a convenient tool for the synthesis of materials and (iii) to propose a new perspective in the SCS, with special attention to the use of ecofriendly procedures. Part of the review is also dedicated to precautions and limitations of this powerful methodology.  相似文献   
5.
本文就日本遗弃在华化学武器销毁残渣元素分布进行了分类分析,并对残渣样品的砷形态进行检测。结果表明,黄剂及红剂销毁残渣样品中主要元素均为铁、铜、砷、钛、铅等,其中砷元素占比较大且危害最深。进一步对样品进行分析结果显示,残渣中砷形态主要为Fe-结合态、Ca-结合态、残渣态等。该实验结果为销毁残渣的二次处理提供了必要的技术支撑,在敦促日方改进销毁技术方面具有重要的现实意义。  相似文献   
6.
在管式反应器中采用苯甲酸、聚乙二醇、固体古马隆树脂(S)、液体古马隆树脂(L)为添加剂来降低煤沥青中有害物质苯并芘的含量,以期使得煤沥青可绿色化应用。采用紫外-可见分光光度计分析煤沥青中苯并芘含量。考察了反应温度、反应时间、添加剂添加量、催化剂等工艺条件对添加剂脱除煤沥青中苯并芘的影响。结果表明,不同工艺条件能降低煤沥青中苯并芘的含量。在优化条件下,不同添加剂对苯并芘脱除率由高到低依次为:液体古马隆树脂、聚乙二醇、苯甲酸和固体古马隆树脂。分析其反应机理,这与催化剂的酸性相关,发生亲电取代反应。结果表明,液体古马隆树脂(L)在催化剂存在下对煤沥青中苯并芘脱除率可达73.0%,显示了良好的应用前景。  相似文献   
7.
In the new social media era, it is becoming increasingly important to explore the propagation rules for rumors in social networks. This article is concerned with investigating a diffusive susceptible-infected rumor propagation model with a nonlinear propagation function in a spatially heterogeneous environment. We establish the uniform persistence and analyze the asymptotic behavior of the rumor-spreading steady state for the spatially heterogeneous model when one of the diffusion coefficients tends to zero. Moreover, to better reflect the effect of a time delay on the process of rumor propagation, we establish a spatially homogeneous model with a time delay and prove the existence and local stability of the corresponding equilibrium point. Furthermore, the optimal control in the spatially homogeneous environment case is derived. Finally, several numerical simulations are performed to verify the theoretical results in both spatially heterogeneous and spatially homogeneous systems.  相似文献   
8.
贴片式石英晶体振荡器广泛应用于各类电子和通信设备系统中。针对晶振在冲击环境中容易出现结构破坏而导致系统工作异常的问题,通过分析单自由度系统在不同频率冲击载荷作用下的响应特点,建立了结构的应力响应水平与相关冲击响应谱谱值之间的联系,获得了较已有结论更合理的损伤边界形式。根据典型晶振结构易损组件的力学特性建立对应的简化分析模型,得到了贴片晶振在大频率范围内的结构损伤边界。利用有限元仿真软件,对晶振结构在0.5~30 kHz频率范围内冲击载荷下的响应进行仿真分析,验证了该损伤边界的有效性。这也为以贴片晶振为代表的微小元器件在冲击环境下的可靠性研究提供了一种可行的方法。  相似文献   
9.
The principal purpose of Ad-Hoc wireless networks is to increase service efficiency in terms of transmission scheduling and packet transfer rate. The approaches that assume frame unicity to satisfy a given set of packets minimize the end-to-end delay. However, they do not guarantee a maximum packet delivery rate due to the difficulty of establishing robust paths for packet transfer across nodes deployed in the network, especially in a three-dimensional (3D) environment. The objective is to minimize the end-to-end delay by ensuring the maximum delivery of packets to their destinations. Furthermore, the signal-to-interference-and-noise-ratio (SINR) model is considered to optimize transmission scheduling. In this paper, an optimal node coordinates optimization approach is proposed to extend two recently investigated schemes in the literature (S-RDSP and I-RDSP). The developed algorithms, named S-MPDR and I-MPDR, seek to reduce the end-to-end delay by delivering a collection of inserted packets over a 3D environment while also maximizing the delivery rate of these packets. Desirability functions are used to evaluate the network’s performance in various scenarios involving two different environments, Level 0 and Level 1. Numerical results demonstrate that the developed algorithms outperform both schemes in terms of end-to-end delay and packet delivery rate. In the Level 0 environment, the overall minimum delay and packet delivery rate scores provided by S-MPDR are increased by 28% and 88% compared to S-RDSP, respectively. In comparison, those provided by I-MPDR are increased by 24% and 16% compared to I-RDSP. Similarly, in the Level 1 environment, the scores provided by S-MPDR are increased by 25% and 100% compared to S-RDSP, respectively, while those provided by I-MPDR are increased by 23% and 25% compared to I-RDSP.  相似文献   
10.
智能变形、变色、变温、变谱技术发展趋势下,低特征目标加速实现与自然地物背景的特征融合,导致复杂自然背景环境下低散射、微反射、弱辐射目标的检测与评估愈发困难,特定场景下潜在威胁目标的检测方法快速决策与准确评估成为了难题。为了提升离散目标、伪装目标、弱小目标、异常目标等低特征目标与复杂自然背景环境融合场景下的多特征检测算法的选择效率及其检测准确度,提出了目标与背景环境融合度(FD)参数模型,并设计了植被伪装目标嵌入草地背景、植被伪装目标嵌入土壤背景、植被及水泥路伪装目标嵌入土壤背景以及植被、水泥路、土壤伪装目标分别嵌入草地、水泥路、土壤背景等4种不同波谱特征分布场景的模拟图像数据,以及信噪比为200,400与800的高斯白噪声分别加入场景一的3种不同级别噪声比例的模拟图像数据。通过综合目标波谱信息、背景波谱信息、数据噪声比例等多种因素的综合试验分析,开展了基于目标与环境FD模型的多特征检测算法适应性评估研究。结果表明,在标准差均小于0.08的条件下,MtACE,MtAMF,MtCEM,SumACE,SumAMF,SumCEM,WtaACE,WtaAMF,WtaCEM等9大经典多特征检测算法对于4种波谱分布场景检测结果的FD参数平均值分别为0.320 0,0.350 2,0.862 4,0.365 8,0.365 8,0.846 1,0.680 0,0.680 0和0.948 2;在标准差均小于0.07的条件下,9大经典多特征检测算法对于3种不同级别噪声比例数据检测结果的FD参数平均值分别为0.313 5,0.320 9,0.774 7,0.369 6,0.369 6,0.847 5,0.695 6,0.695 6和0.960 3。通过不同波谱分布场景及不同噪声级别条件下的检测与融合度评估试验分析,实现了多特征检测算法的适应性能排序,大幅提升复杂场景下多种低特征目标的检测效率。综合波谱与噪声因素,对于复杂场景下离散分布的低特征目标检测,9大经典多特征检测算法的优先级顺序为:MtACE>MtAMF>SumACE=SumAMF>>WtaACE=WtaAMF>MtCEM>SumCEM>WtaCEM。  相似文献   
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