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A novel approach is presented for the encapsulation of organic functional molecules between two sheets of 1 nm thin silicate layers, which like glass are transparent and chemically stable. An ordered heterostructure with organic interlayers strictly alternating with osmotically swelling sodium interlayers can be spontaneously delaminated into double stacks with the organic interlayers sandwiched between two silicate layers. The double stacks show high aspect ratios of >1000 (typical lateral extension 5000 nm, thickness 4.5 nm). This newly developed technique can be used to mask hydrophobic functional molecules and render them completely dispersible in water. The combination of the structural anisotropy of the silicate layers and a preferred orientation of molecules confined in the interlayer space allows polymer nanocomposite films to be cast with a well‐defined orientation of the encapsulated molecules, thus rendering the optical properties of the nanocoatings anisotropic.  相似文献   
3.
The axisymmetric buckling (delamination) of a circular disk (plate) with a penny-shaped crack is analyzed using a continuum model, piecewise-homogeneous model, and the three-dimensional linearized theory of stability. The FEM is used. The analysis is carried out using various singular and ordinary finite elements. The numerical results obtained indicate that it is not necessary to use singular finite elements to solve the problem Published in Prikladnaya Mekhanika, Vol. 43, No. 9, pp. 120–129, September 2007.  相似文献   
4.
将层板横截面分为含裂纹区与不含裂纹区,在每一区内,根据夏变函数理论与特征函数展开法,得到了各自区内满足所有支配方程、裂纹表面边界条件与层间连续条件的位移与应力的特征展开式,然后利用分区广义变分原理满足裂纹表面边界以外的边界条件以及两区之间的交界条件,并由此求得奇异场控制量(广义应力强度因子)。  相似文献   
5.
压电传感器探测层合板分层的数值分析   总被引:1,自引:0,他引:1  
尹林  王晓明  沈亚鹏 《力学学报》1995,27(Z1):58-65
用修正的准三维有限元法分析了受单轴拉伸表面覆盖有压电薄膜的复合材料层合板。文中首先讨论了压电薄膜层对层合板层间应力的影响,然后在存在分层裂纹的情况下,计算了压电层的电压分布。结果表明将压电薄膜作为传感器来进行分层探测是可行的。文中最后考虑了多种因素对传感灵敏度的影响。  相似文献   
6.
应用Rayleigh-Ritz法对含有单个椭圆形分层的复合材料对称层板在压剪载荷联合作用下的脱层屈曲问题进行了分析计算。给出相应于不同的椭圆长短半轴之比a/b值下及不同椭回主轴的偏角时,脱层屈曲的临界应变值。此计算考虑了层板的拉伸剪切藕合刚度影响及子层本身弯曲-扭转耦合刚度,和拉伸-弯曲耦合刚度的影响,给出有工程参考价值的计算结果。  相似文献   
7.
Failure behavior of the delaminated stiffened composite plates under compression is studied by the finite element method, based on a Global-Local variational model. A virtual crack closure technique and a self-adaptive grid moving scheme are proposed to predict the delamination growth process. The contact effect along the delamination front is considered. The numerical results show that the influences of the distribution and location of the stiffeners, the configuration and size of the delamination, the boundary condition and the contact upon the failure behavior of the plates are significant. The project supported by the National Natural Science Foundation of China (59975014)  相似文献   
8.
《Composite Interfaces》2013,20(5):469-478
The effect of carbon fiber textile for flexural reinforcement to deteriorated reinforced concrete floor slab is tested in laboratory by cutting out six specimens from existing structure aged more than 70 years. The repair method between concrete and carbon fiber textile is used as experimental parameter. From the test results, deformation, bond characteristic of carbon fiber textile and the applicability of carbon fiber textiles to flexural reinforcement of floor slabs are discussed.  相似文献   
9.
《Composite Interfaces》2013,20(5):337-349
The lamination of composite elements such as sheets or fibres made from ceramic powders represents a cheap and easy way of making tough ceramics. The fabrication and failure behaviour of such layered structures is described. It is shown that crack growth along the interfaces is dominated by dynamic effects due to the storage of excess elastic energy and that effects of loading state, in the silicon carbide/graphite system at least, appear to be relatively unimportant. Crack deflection at interfaces is also discussed and it is shown that observations made in these systems are not consistent with existing theories. Various possibilities are investigated.  相似文献   
10.
In this work a bi-material beam exhibiting partly bilinear behaviour under a uniform temperature change is analyzed. The essence of solution is based on the approach of Timoshenko’s mechanics of materials. The main aim of the present analysis is to understand the effect of the bilinear behaviour on the peeling moment. This theoretical mechanics model mentioned here can give us useful insights to improve the resistance against the delamination.  相似文献   
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