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1.
金属锂作为电池的负极材料具有极高的比容量和极低的氧化还原电位,能够显著提升电池的能量密度。然而,金属锂负极在实际应用中所面临的主要问题是锂枝晶、界面副反应和电极体积变化大的难题。在本文中,我们提出了一种通过将定量的金属锂与三维骨架进行复合形成三维泡沫锂负极的策略,并利用三维泡沫锂来抑制锂枝晶的生长和缓解电极的体积变化。因此,三维泡沫锂电极有利于金属锂负极的高效利用,并能借助其与平面锂箔相比更高的比表面积和更多的反应位点来提升电池的倍率性能。因此,通过采用三维泡沫锂,对称电池的循环寿命和倍率性能都得到了有效的提升。EIS数据结果表明,三维泡沫锂能够减小对称电池的电荷转移阻抗。而且,将三维泡沫锂作为负极组装的LTO全电池,与锂箔作为负极相比,循环1000周平均放电比容量从65 mAh·g-1提升至121 mAh·g-1。 相似文献
2.
This review summarizes recent progress in understanding the oxygen reduction and evolution reactions at the lanthanum strontium manganite electrode of a high-temperature solid oxide cell. Information provided here is put into the perspective of the defect chemistry of lanthanum strontium manganite and its impact on the electrode reaction mechanisms itself. After summarizing recent views on the oxygen reduction reaction mechanism, the focus turns to the oxygen evolution reaction, which is significantly less treated in the literature. A combination of the information in the literature on both reactions was the basis for modified reaction mechanism of the oxygen evolution reaction to be proposed under consideration of recent experimental observations and theoretical findings. 相似文献
3.
Arya Ghosh Subash C.B. Gopinath Sayeed Mohammad Firdous Santheraleka Ramanathan 《印度化学会志》2022,99(8):100604
Human Mammary Tumor Virus (HMTV) or Mouse Mammary Tumor Virus holds similarity as an endogenous onco-retrovirus belongs to retroviridae family, predominantly infects the epithelial cell of human as well as mouse. With the recognition of nano-biosensor in nanotechnology, ideal interdigitated electrode (IDE) was genuinely performed for HMTV detection. Aluminium enriched IDE (AlIDE) was fabricated for high performance detection with a cost-effective photolithography technique. In this research, (3-glycidyloxypropyl) trimethoxysilane refined platform was selected to detect the conductivity with HMTV target DNA interaction on the designed AlIDE. Strong binding affinity of streptavidin-biotin with target DNA enhanced the sensitivity by empowering higher number of HMTV probe and target complementation on sensing surface. Furthermore, the target DNA was immobilized on probe modified AlIDE and a quantitative value of 100 aM attained as a lowest detection. A linear with dose-dependent duplex formation was shown with the regression coefficient value of 0.964. Negative control has shown insignificant detection at 10 pM, which justifies the higher fold discrimination with specificity. The excellence of AlIDE performance in detection of HMTV may pave the way for more verification on other diseases. 相似文献
4.
电催化二氧化碳还原反应(E-CO2RR)可在温和条件下将CO2转化成高附加值燃料或化学品,近年来受到广泛关注,其在实际反应中涉及到气体扩散和多电子转移等复杂过程,构筑高效、稳定的催化电极是其发展的核心之一。然而,传统涂敷电极制备时,需要将催化剂与粘结剂混合涂覆于集流体表面,此过程会造成活性位点包埋和传质过程受限,致使催化剂活性位利用率下降,同时在反应过程中电极表面容易粉化,造成稳定性下降,难以重复利用。因此,如何调控电极反应界面,提升催化剂活性位的利用率仍面临挑战。将催化剂原位生长于集流体上得到的一体化电极可直接应用于电催化反应,不仅有利于提升活性位利用率以及电荷传输能力,还能有效调控三相界面处的微观反应环境(如pH、反应物及反应中间体的浓度等),从而实现电催化性能强化。本文综述了一体化电极用于E-CO2RR的最新进展,分析了结构和表界面调控对E-CO2RR性能的影响规律,并对该领域仍然存在的挑战和未来一体化E-CO2RR电极的发展进行了评述与展望。 相似文献
5.
Hemn A. H. Barzani Hoshyar Saadi Ali Cihat Şahin Musa Kıran Yavuz Yardım 《Electroanalysis》2022,34(8):1280-1288
An effective electrochemical sensor was constructed using an unmodified boron-doped diamond electrode for determination of genistein by square-wave voltammetry. Cyclic voltammetric investigations of genistein with HClO4 solution indicated that irreversible behavior, adsorption-controlled and well-defined two oxidation peaks at about +0.92 (PA1) & +1.27 V (PA2). pH, as well as supporting electrolytes, are important in genistein oxidations. Quantification analyses of genistein were conducted using its two oxidation peaks. Using optimized experiments as well as instrumental conditions, the current response with genistein was proportionately linear in the concentrations range of 0.1 to 50.0 μg mL−1 (3.7×10−7−1.9×10−4 mol L−1), by the detection limit of 0.023 μg mL−1 (8.5×10−8 mol L−1) for PA1 and 0.028 μg mL−1 (1.1×10−7 mol L−1) for PA2 in 0.1 mol L−1 HClO4 solution (in the open circuit condition at 30 s accumulation time). Ultimately, the developed method was effectively applied to detect genistein in model human urine samples by using its second oxidation peak (PA2). 相似文献
6.
This study developed a nanosensor for the detection and determination of favipiravir, a presumed drug that has potential therapeutic efficacy in treating COVID-19 patients, from tablets and serum samples. This nanosensor was obtained by adding the optimum amount of diamond nanoparticles into carbon paste. For the determination of favipiravir adsorptive stripping differential pulse (AdSDPV) and adsorptive stripping square wave voltammetry (AdSSWV) were used. Limit of detection values were found as 4.83×10−9 M and 2.44×10−7 M for bulk and 5.18×10−8 M and 4.38×10−8 M for serum samples using AdSDPV and AdSSWV, respectively. Recovery studies made of the tablet and serum produced satisfactory results. 相似文献
7.
“复杂氧化还原电对电极电势的计算”一直是大学化学教学的难点,以此为例开展翻转课堂教学:教师引导学生归纳、类比,厘清难溶盐电极、配合物电极与“金属电极”之间的渊源,完成知识的内化;通过课堂翻转,学生将内化的知识在课堂实践中加以展现与深化,掌握复杂电极在标准状态下电极电势的计算方式。实践表明,该教学模式避免了学生线上学习存在的刷屏、刷题、心理浮躁等现象,有助于推动学生进行深度学习,将碎片化的知识迁移、串联、整合成体系,达到学以致用的目的。 相似文献
8.
阴极表面温度是真空弧等离子体放电过程中一个重要参数,对真空弧等离子体的形成、电极腐蚀预测、热传导以及离子源的寿命都有重要影响。真空弧离子源的阴极具有目标小,放电过程快等特点,其温度的测量,对于时间分辨率和空间分辨率要求都很高,阴极表面温度的测量技术的欠缺,使得仅靠理论解析获得的结果难以得到验证。并且等离子体放电过程中测量仪器极易受到弧光的影响,如何避免放电过程中等离子体的辐射也是采用辐射法测量阴极表面温度要考虑的问题。这无疑给其温度场的测试研究带来困难。针对脉冲真空弧等离子体开展阴极表面温度测试实验有着重要意义,在分析了真空弧等离子体放电特性以及背景辐射特性和等离子体放电阴极测温的实际需求,本文基于高速CCD相机研制了一种新型的多光谱高温计。该高温计采用单色高速CCD相机,主要避免RGB彩色相机不能完全滤除背景辐射的弧光。为使用单色CCD相机实现多光谱辐射测温,设计了高温计的光学系统,该系统采用4孔径分光系统。将4种不同波长的滤光片嵌入到1个滤光片中。该研究设计的高温计可用于2 000~6 000 K的等离子体温度测量。并在中国工程物理研究院电子工程研究所进行现场测试,测试过程中将研制的高温计,通过外部触发形式对等离子体放电过程进行跟踪拍摄,高温计完全拍摄到等离子体放电过程。利用真空弧等离子体金属电极阴极放电的实测数据对高温计进行了验证。实验结果表明,设计的新型多光谱高温计能够用于测量真空弧等离子体放电时阴极温度场信息,测量的温度值低于放电电极的沸点温度,与等离子体放电过程中出现气化现象相符,说明高温计测的是等离子体放电阴极的温度。 相似文献
9.
Ana Elisa Ferreira Oliveira Arnaldo César Pereira Mayra Asevedo Campos de Resende Lucas Franco Ferreira 《Electroanalysis》2022,34(5):809-819
In this work, a silver/silver chloride ink is fabricated using two steps. First the silver ink is prepare using silver, nail polish and acetone. Then the silver ink is painted in a paper substrate and a silver chloride layer is deposited using a bleach solution. The result is the silver/silver chloride conductive ink. The silver ink is cheap ($2.49/g), well-dispersive and very easy to fabricate. The materials were characterized by SEM and XRD. The Ag ink showed the formation of a continuous network throughout the silver ink film with fewer agglomeration. The effective chlorination process was also observed in the Ag/AgCl characterization. Since the Ag/AgCl substrate will be used as a quasi-reference electrode, it is important to investigate the electrical properties. The Ag ink showed an average ohmic resistance of 2.27 Ω. The addition of the AgCl layer decreases the conductivity, as expected. In summary, the Ag/Ag/Cl ink developed is simple, well-dispersed, cheap and with good conductivity. Therefore, it can be used as a conductive ink in the fabrication of quasi-reference electrodes. 相似文献
10.
Tlou A. Makwakwa Potlako J. Mafa Hlengilizwe Nyoni Titus A. M. Msagati 《Electroanalysis》2022,34(7):1103-1113
In the present study, an electroanalytical method that permits the optimization of factors affecting SWV for sensitive detection of mifepristone at glassy carbon electrode (GCE) using response surface methodology (RSM) with desirability function (DF) is presented. Factors selected for optimization after screening using full factorial design were frequency (X1), amplitude (X2), and pH (X3). The central composite design as a response surface methodology with desirability function (DF) was applied for obtaining the optimum level. The optimum conditions were obtained as follows: Frequency (X1=50 Hz), amplitude (X2=33.4 mV), and pH (X3=9.4), with an overall desirability function of 0.97. Subsequently, confirmatory experiments were performed in triplicates to validate the optimum conditions. The results obtained were satisfactory and agreed well with less only 11.9 % deviation from the values predicted by the model. The limit of detection (LOD) and limit of quantification (LOQ) were found to be 0.54 and 1.80 ppm, respectively. The proposed method was applied for a quantitative determination of mifepristone in spiked tap water samples. The recovery tests showed that the detection of mifepristone at GC could be evaluated on environmental samples. 相似文献