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1.
The reactions of bis(trimethylstannyl)ethyne, Me3Sn–C?C–SnMe3 ( 4 ), with trimethylsilyl‐ or dimethylsilyl‐dialkylboryl‐substituted alkenes 1 – 3 afford organometallic‐substituted allenes 5 , 6 and 8 , 9 in high yield. In the case of (E)‐2‐trimethylsilyl‐3‐diethylboryl‐2‐pentene ( 1) , a butadiene derivative 7 could be detected as an intermediate prior to rearrangement into the allene. All reactions were monitored by 29Si and 119Sn NMR, and the products were characterized by an extensive NMR data set (1H, 11B, 13C, 29Si, 119Sn NMR). Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
2.
The microscopic theory of the blue phases of chiral liquid crystal is proposed. Beginning with the potential between two molecules, by using the cell model of liquid, applying statistical physical method, the distribution function and the free energy of the system are obtained. By using variational approach and zero-order approximation, the differential equation that the order parameter tensor of the blue phase can satisfy is obtained. Then we change the differential equation to the eigenequation problem in quantum mechanics. Considering the symmetry of the blue phases,the order parameter tensors of blue phases Ⅰ and Ⅱ can be made up of the eigenvectors. Our results are the same as the results of Ginzberg-Landau‘s phenomenological theory. The parameters in the order parameter tensors that we calculate in the located system are close to the predecessors‘ results. 相似文献
3.
Ryosuke Sakai Issei Otsuka Toshifumi Satoh Ryohei Kakuchi Harumi Kaga Toyoji Kakuchi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):325-334
The asymmetric polymerization of 4′‐isocyanatobenzo‐18‐crown‐6 with the lithium amide of (S)‐(2‐methoxymethyl)pyrrolidine successfully proceeded to afford end‐functionalized poly(4′‐isocyanatobenzo‐18‐crown‐6) with (S)‐(2‐methoxymethyl)pyrrolidine (polymer 2 ). In the circular dichroism (CD) spectrum of 2 , a clear positive Cotton effect was observed in the range of 240–350 nm corresponding to the absorption of the polymer backbone, indicating that 2 partially formed a one‐handed helical structure, which was preserved by the chirality of (S)‐(2‐methoxymethyl)pyrrolidine bonding to the terminal end in 2 . In the titration experiments for the CD intensity of 2 in the presence of D ‐ and L ‐Phe·HClO4 (where Phe is phenylalanine), a small but remarkable difference was observed in the amount of the chiral guest needed for saturation of the CD intensity and in the saturated CD intensity, indicating that the extremely stable, one‐handed helical part should exist in the main chain of 2 , which was not inverted even when the unfavorable chiral guest for the predominant helical sense, L ‐Phe·HClO4, was added. In addition, helical polymer 2 exhibited a chiral discrimination ability toward racemic guests; that is, the guests were extracted from the aqueous phase into the organic phase with enantiomeric excess. The driving force of the chiral discrimination ability of 2 should certainly be attributed to the one‐handed helical structure in 2 . © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 325–334, 2006 相似文献
4.
S. V. Basenko I. A. Gebel M. G. Voronkov L. V. Klyba R. G. Mirskov 《Russian Chemical Bulletin》1998,47(8):1571-1573
Methyl(vinyl)dichlorosilane reacts with DMSO in the presence of hexamethyldisiloxane to give the corresponding linear oligosiloxanes
of the general formula Me3Si(OSiMeVin)
n
OSiMe3 (n=1–6) as well as MeSi(OSiMe3)3 and Me3Si(MeOSiVin)
m
OSi(OSiMe3)(Me)OSiMe3 (m=1–2). The same reaction in the presence of chlorotrimethylsilane results in oligomers of the general formula Me3Si(OSiMeVin)
n
Cl (n=1–3). A possible scheme of their formation is discussed.
Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 8, pp. 1614–1616, August, 1998. 相似文献
5.
Recently,we have derived a two–nucleon potential and consistent nuclear electromagnetic currents in chiral effective field theory with pions and nucleons as explicit degrees of freedom.The calculation of the currents has been carried out to include N 3 LO corrections,consisting of two–pion exchange and contact contributions.The latter involve unknown low-energy constants (LECs),some of which have been fixed by fitting the np Sand P-wave phase shifts up to 100 MeV lab energies.The remaining LECs entering the current operator are determined so as to reproduce the experimental deuteron and trinucleon magnetic moments,as well as the np cross section.This electromagnetic current operator is utilized to study the nd and n 3 He radiative captures at thermal neutron energies.Here we discuss our results stressing on the important role played by the LECs in reproducing the experimental data. 相似文献
6.
We study the Imbert–Fedorov (IF) shifts of a reflected Gaussian beam from uniaxially anisotropic chiral media (UACM), where the chirality appears only in one direction and the host medium is a uniaxial crystal or an electric plasma. The numerical results are presented for three kinds of UACM, respectively. It is found that the IF shifts are closely related to the propagation properties of the two eigenwaves in the UACM. In general, when either of the eigenwaves is totally reflected, the IF shifts can change abruptly near the critical angle. The cross-polarized reflection coefficient has a greater effect on the spatial IF (SIF) shift than on the angular IF (AIF) shift, and the sign of the AIF shift depends mainly on that of the difference between the co-polarized reflectivity. By designing artificially the electromagnetic parameters of the UACM, we can control the IF shifts and acquire their more abundant properties. 相似文献
7.
CHEN Xiao-Zhao LI Xiao-Ya LU Xiao-Fu 《理论物理通讯》2008,49(2):451-455
Based on the diquark model, we assume that the light scalar mesons are q^2q^-2 states rather than qq^-. The chiral effective Lagrangian for the light scalar meson is constructed, and the mass relations are obtained: the isotriplet (a0) and the isosinglet (f0) are the heaviest and are degenerate, the isodoublets (κ) are heavier and the other isosinglet (σ) is the lightest; and 2Mκ^2 = Mα0^2+ Mσ^2. Using experimental value for a0 and σ mass, we obtain Mκ=794 MeV, which is consistent with the experimental value. Then taking Г(a0^0 →ηπ^0) = 90 MeV and Г(f0→π^0π^0) = 20 MeV, we get the width of σ is: Г(σ0→π^+π^-)= 150 MeV. 相似文献
8.
We have analysed the two body non-leptonic charmed-meson decays of heavyB meson based on the factorization assumption. The transition matrix elements and the corresponding decay widths are calculated
in the heavy quark and chiral symmetry limit and the Isgur-Wise function present in the expression is determined by the wave
function model of Aliet al. The results obtained are quite interesting and agree reasonably well with the experimental data. 相似文献
9.
ZHANG Zong-Ye WANG Wen-Ling 《中国物理 C》2007,(9)
在手征SU(3)夸克模型和扩展的手征SU(3)夸克模型的框架下,用变分的方法系统地研究了同位旋为0、1,自旋宇称为0~ 、1~ 和2~ 的ud■四夸克系统6个低组态的能量.模型的参数取自以前的工作,它能很好地描述核子-核子散射相移以及核子-超子散射截面.S道相互作用的参数由拟合K介子和K~*介子的质量定出,并且考虑了具有相同量子数的态之间的态混合效应.结果表明,同位旋为0且自旋宇称为1~ 的ud■能量低于相应的K~*K~*的阈能,且该组态中KK~*的成分相当小,因此该组态的宽度可能较小,可视为一个可能的四夸克态的候选者. 相似文献
10.
In this report we investigate η-meson productions on the proton via electromagnetic and hadron probes in a chiral quark model approach. The observables, such as, differential cross section and beam asym-metry for the two productions are calculated and compared with the experiment. The five known resonances S_(11)(1535), S_(11)(1650), P_(13)(1720), D_(13)(1520), and F_(15)(1680) are found to be dominant in the reaction mech-anisms in both channels. Significant contribution from a new S_(11) resonances are deduced. For the so-called "missing resonances", no evidence is found within the investigated reactions. The partial wave amplitudes for π~-p→ηn are also presented. 相似文献