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1.
The total drag force on the surface of a body, which is the sum of the form drag and the skin friction drag in a 2D domain, is numerically evaluated by integrating the energy dissipation rate in the whole domain for an incompressible Stokes fluid. The finite element method is used to calculate both the energy dissipation rate in the whole domain as well as the drag on the boundary of the body. The evaluation of the drag and the energy dissipation rate are post-processing operations which are carried out after the velocity field and the pressure field for the flow over a particular profile have been obtained. The results obtained for the flow over three different but constant area profiles—a circle, an ellipse and a cross-section of a prolate spheroid—with uniform inlet velocity are presented and it is shown that the total drag force times the velocity is equal to the total energy dissipation rate in the entire finite flow domain. Hence, by calculating the energy dissipation rate in the domain with unit velocity specified at the far-field boundary enclosing the domain, the drag force on the boundary of the body can be obtained.  相似文献   
2.
In this study, oxidation of bisphenol-A (IUPAC name – 2,2-(4,4-dihydroxyphenyl, BPA), which is an endocrine disrupting phenolic compound used in the polycarbonate plastic and epoxy resin industry, was investigated using sono-photo-Fenton process under visible light irradiation in the presence of an iron containing perovskite catalyst, LaFeO3. The catalyst prepared by sol–gel method, calcined at 500 °C showed a catalytic activity in BPA oxidation using sono-photo-Fenton process with a degradation degree and a chemical oxygen demand (COD) reduction of 21.8% and 11.2%, respectively. Degradation of BPA was studied by using individual and combined advanced oxidation techniques including sonication, heterogeneous Fenton reaction and photo oxidation over this catalyst to understand the effect of each process on degradation of BPA. It was seen, the role of sonication was very important in hybrid sono-photo-Fenton process due to the pyrolysis and sonoluminescence effects caused by ultrasonic irradiation. The prepared LaFeO3 perovskite catalyst was a good sonocatalyst rather than a photocatalyst. Sonication was not only the effective process to degrade BPA but also it was the cost effective process in terms of energy consumption. The studies show that the energy consumption is lower in the sono-Fenton process than those in the photo-Fenton and sono-photo- Fenton processes.  相似文献   
3.
The present work reports a novel dual-pulse ultrasound enhanced electrochemical degradation (US-ECD) process that synchronizes alternatively ultrasound pulses and potential pulses to degrade nitrobenzene in aqueous solution with a high percentage degradation and low energy consumption. In comparison to the test results generated from the conventional US-ECD and original electrochemical degradation (ECD) process, the dual-pulse US-ECD process increased degradation percentages to nitrobenzene by 2% and 17%, respectively, while energy used in the pulse process was only about 46.5% of that was used in the conventional US-ECD process. Test results demonstrated a superior performance of the dual-pulse US-ECD process over those of other conventional ones. Impacts of pulse mode, initial pH value, cell voltage, supporting electrolyte concentration and ultrasonic power on the process performances were investigated. With operation conditions optimized in the study at pH = 3.0, cell voltage = 10 V, ultrasonic power = 48.84 W, electrolyte concentration = 0.1 M and an experiment running time of 30 min, the percentage degradation of nitrobenzene could reach 80% (US pulse time = 50 ms and ECD pulse time = 50 ms). This process provided a reliable and effective technical approach to degrade nitrobenzene in aqueous solution and significantly reduced energy consumption in comparison to the conventional US-ECD or original ECD treatment.  相似文献   
4.
In this study, strain rate effects on the compressive mechanical properties of randomly structured carbon nanotube (CNT) networks were examined. For this purpose, three-dimensional atomistic models of CNT networks with covalently-bonded junctions were generated. After that, molecular dynamics (MD) simulations of compressive loading were performed at five different strain rates to investigate the basic deformation characteristic mechanisms of CNT networks and determine the effect of strain rate on stress–strain curves. The simulation results showed that the strain rate of compressive loading increases, so that a higher resistance of specimens to deformation is observed. Furthermore, the local deformation characteristics of CNT segments, which are mainly driven by bending and buckling modes, and their prevalence are strongly affected by the deformation rate. It was also observed that CNT networks have superior features to metal foams such as metal matrix syntactic foams (MMSFs) and porous sintered fiber metals (PSFMs) in terms of energy absorbing capabilities.  相似文献   
5.
Results of calculations on a model of a radiant cavity, performed in order to explore the relation between stochasticity and geometrical structure of phase space, are presented. The rate of energy exchanges, as indicator of stochasticity, is found to be quite effective. Furthermore, a trend to equipartition for such a quantity is observed at increasing energy, and this implies an increasing rigidity of high harmonic modes also in the stochastic regime of motion. Such a feature may be correlated to the shape of the spectrum which characterizes the radiant cavity with respect to nonlinear chains.  相似文献   
6.
The α-phase in Zr-2.5 Nb pressure tubes has been analysed after irradiation with neutrons for temperatures between 523 and 573 K. The α-phase contains Nb in supersaturated solid solution (about 0.5−1 wt% Nb) in the as-fabricated condition. Irradiation results in the formation of small discrete precipitates having diameters of about 5 nm. Energy Dispersive X-ray (EDX) analysis using a scanning transmission electron microscope (STEM) was complicated by the presence of a self-generated X-rays in the irradiated material and by the fact that the precipitates were small relative to the foil thickness (typically 100–200 nm). Techniques developed to measure segregation of impurities at interfaces were employed to show that the precipitates were Nb-rich, their formation being consistent with a decrease in Nb concentration in the matrix.  相似文献   
7.
研究了常压溶剂法一步合成抗氧剂3114反应热力学和动力学过程。控制温度在117±2℃,研究结果表明,反应是零级反应,反应速率常数为k=1.91×10^-3/min,反应的平衡常数为K=138.4(mol/L)^-6,反应活化能Ea=1366J/mol。  相似文献   
8.
Titanium dioxide thin films have been deposited by metalorganic chemical vapor deposition (MOCVD) over sodalime glass substrates at substrate temperatures ranging from 250 °C to 450 °C. The effect of deposition temperature on the structure and microstructure of the obtained films has been studied by x-rays diffraction (XRD) and scanning electron microscopy (SEM), respectively. Diffraction patterns show the existence of a pure anatase phase beside a texture change with the increase of deposition temperature. Micrographs show grain fragmentation with the increase in deposition temperature. UV–Vis. spectra have been recorded by spectrophotometery. The optical energy gap has been calculated for the deposited films from the spectrophotometrical data. Photocatalytic experiments have been carried out. The photocatalytic activity has been found to decrease with the increase in deposition temperature.  相似文献   
9.
Multidimensional potential energy landscapes (PELs) have a Gaussian distribution for the energies of the minima, but at the same time the distribution of the hyperareas for the basins of attraction surrounding the minima follows a power-law. To explore how both these features can simultaneously be true, we introduce an “egg-box” model. In these model landscapes, the Gaussian energy distribution is used as a starting point and we examine whether a power-law basin area distribution can arise as a natural consequence through the swallowing up of higher-energy minima by larger low-energy basins when the variance of this Gaussian is increased sufficiently. Although the basin area distribution is substantially broadened by this process, it is insufficient to generate power-laws, highlighting the role played by the inhomogeneous distribution of basins in configuration space for actual PELs.  相似文献   
10.
By controlling the pH values of prepared solutions, the 10 mol% Ce3+, 5 mol% Tb3+ co-doped KGdF4 (synthesized with pH = 3) and the 10 mol% Ce3+, 5 mol% Tb3+ co-doped GdF3 (synthesized with pH = 1) submicro/nanocrystals have been synthesized based on a citric acid assisted hydrothermal method. For comparison, the samples synthesized by co-precipitation method (without hydrothermal treatment) with pH = 3 and 1 were also collected. The X-ray diffraction data illustrate that the hydrothermal treated KGdF4 sample crystallizes in the cubic phase and the GdF3 sample crystallizes in the orthorhombic phase. However, the samples synthesized by co-precipitation method with pH = 3 and 1 are both cubic phase KGdF4. The field emission scanning electron microscopy images suggest that the hydrothermal treated KGdF4 submicro/nanocrystals present spherical morphology and the GdF3 submicrocrystals are rhombic-shaped. And the photoluminescence excitation and emission spectra as well as the luminescent dynamic curves demonstrate the difference in optical properties of the two hydrothermal treated samples.  相似文献   
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