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排序方式: 共有914条查询结果,搜索用时 15 毫秒
1.
2.
导出了类Kerr介质中双模SU(1,1)相干态场与Λ型三能级原子相互作用系统的态函数,研究了Kerr效应对Λ型三能级原子布居概率、双模SU(1,1)相干态场的互关联函数、Cauchy-Schwartz不等式及二阶相干度的影响.结果表明:Kerr效应使原子与光场的耦合减弱,原子布居的崩塌与复苏的周期缩短;在初始光场较弱和较强两种情况下,类Kerr介质对双模SU(1,1)相干态场两模间的相关性、相关程度以及光子的聚束与反聚束效应产生的作用有明显的区别. 相似文献
3.
Trichloroethylene has been found to act as a rate enhancing co-factor in the liquid phase, tantalum (V) halide catalyzed, fluorine-for-chlorine exchange reaction of 1,2-dichloro-1,1-difluoroethane (R-132b) to 2-chloro-1,1,1-trifluorethane (R-133a). Several trifluoromethyl substituted benzenes have also been found to be rate-enhancing solvents. 相似文献
4.
Nicolas Meyer Mohamad Nasser Eddine Christelle Delaite Guy Hurtrez Philippe Dumas 《Journal of polymer science. Part A, Polymer chemistry》2003,41(21):3329-3335
The reactions of polystyryllithium and potassium on dimethoxymethyl 1,1‐diphenylethylene derivatives were studied in different solvents. In a polar medium, A3 and A6 star types were formed according to the stoichiometry, whereas in a nonpolar medium, hyperbranched structures were synthesized. Extensions of an already proposed mechanism in polar and nonpolar media were examined. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3329–3335, 2003 相似文献
5.
A. V. Tarasov P. O. Yablonsky Yu. A. Moskvichev 《Chemistry of Heterocyclic Compounds》2003,39(1):119-122
Various methods were studied for the oxidation of 2-methyl-5-(phenylsulfonyl)benzenesulfamide and its derivatives. The oxidation by sodium dichromate in sulfuric acid was found most efficient. The effects of temperature, concentration, reagent ratio, and time of the oxidation reaction on the yield of the desired product were investigated. Conditions were proposed for obtaining the desired product in yields up to 95%. A synthesis was developed for a series of new saccharin derivatives. 相似文献
6.
GM(1,1)改进模型及其应用 总被引:34,自引:1,他引:33
根据 GM( 1 ,1 )灰色模型的指数特性 ,通过在区间上求积分给出了关于背景值的一个比较确切的计算公式 ,讨论了由此建立的 GM( 1 ,1 )改进模型的适用范围和预测精度 .结果表明改进模型比原 GM( 1 ,1 )模型适用性要强、模拟和预测精度要高 ,不仅适用于低增长序列、也适用于高增长序列 ,不仅适用于短期预测 ,同样也适用于中、长期预测 相似文献
7.
Zh. D. Chaplanova Yu. K. Mikhailovskii V. E. Agabekov V. K. Ol’khovik N. A. Galinovskii E. A. Gracheva 《Journal of Applied Spectroscopy》2007,74(3):333-337
We have studied the spectral properties and morphology of thin films (TVD films) formed by thermal vacuum deposition of 4,4′-bis[(E)-1-(1,3-benzoxazol-2-yl)-2-ethenyl]-1,1′-biphenyl
and its substituted derivatives. We have shown that introducing bulky 2,2′-oxyhexyl substituents into the biphenyl units leads
to a shift of the fluorescence maximum for the TVD films toward shorter wavelengths, a decrease in their photostability, and
aggregation of the films during storage.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 3, pp. 300–303, May–June, 2007. 相似文献
8.
Efrosyni Themistou Amelia Kanari Costas S. Patrickios 《Journal of polymer science. Part A, Polymer chemistry》2007,45(24):5811-5823
A compact, cleavable acylal dimethacrylate cross‐linker, 1,1‐ethylenediol dimethacrylate (EDDMA), was synthesized from the anhydrous iron(III) chloride‐catalyzed reaction between methacrylic anhydride and acetaldehyde. The ability of EDDMA to act as cross‐linker was demonstrated by using it for the preparation of one neat cross‐linker network, four star polymers of methyl methacrylate (MMA), and four randomly cross‐linked MMA polymer networks using group transfer polymerization (GTP). For comparison, the corresponding polymer structures based on the commercially available ethylene glycol dimethacrylate (EGDMA) cross‐linker (isomer of EDDMA) were also prepared via GTP. The number of arms of the EDDMA‐based star polymers was lower than that of the corresponding EGDMA polymers, whereas the degrees of swelling in tetrahydrofuran of the EDDMA‐based MMA networks were higher than those of their EGDMA‐based counterparts. Although none of the EDDMA‐containing polymers could be cleanly hydrolyzed under basic or acidic conditions, they could be thermolyzed at 200 °C within 1 day giving lower molecular weight products. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5811–5823, 2007 相似文献
9.
D. Tirzite A. Krauze A. Zubareva G. Tirzitis G. Duburs 《Chemistry of Heterocyclic Compounds》2002,38(7):795-800
The alkylation of 3-cyano-1,4-dihydropyridine-2(3H)-thiones or the condensation of an aromatic aldehyde, cyanothioacetamide, acetylacetone, and methyl iodide in the presence of piperidine has given a series of novel 5-acetyl-2-alkylthio-4-aryl-6-methyl-1,4-dihydropyridine-3-carboxylic acid nitriles. A compound was obtained from 3,5-di(tert-butyl)-4-hydroxybenzaldehyde in the molecule of which were combined the active part of the antioxidant ionol and a 1,4-dihydropyridine ring. It was found that, among the compounds synthesized, the highest antiradical activity occurred in a compound having two hydroxyl groups in the 4-phenyl substituent. 相似文献
10.
Martin Winterwerber Rouzita Geiger Ursula Predoiu Hans-Hartwig Otto 《Monatshefte für Chemie / Chemical Monthly》2006,137(11):1441-1451
Summary. Reactions of cyanomethanesulfonamides with aromatic aldehydes in the presence of AcOH and piperidine produced the addition products, the 1-cyano-2-arylethenesulfonamides, whereas reactions with benzonitrile
yielded the 2-amino-1-cyano-2-phenylethenesulfonamides only when done in THF with BuLi. No addition products were isolated from the analogue reactions with 2-hydroxybenzaldehyde (salicylaldehyde). Instead,
we obtained 2-imino-2H-chromene-3-sulfonamides with good to excellent yields. These 2H-chromene derivatives allowed a number of transformations, from which the reactions with orthoformates opened an approach
to the hitherto unknown benzopyrano[3,2-e] [1,2,4]thiadiazine ring system. 相似文献