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1.
本文以纯NaCl和CuCl粉末为原料,采用烧结法制备了尺寸为Φ5×1.8 mm的NaCl:Cu圆形剂量片,将剂量片置入四元件外壳中并用塑料薄膜密封以克服材料的吸湿性,使用InLight 200型光释光自动测量系统研究其光释光特性.结果发现,对于X/γ射线, NaCl∶Cu剂量片对于能量较低射线的光释光响应高于能量较高的同种射线.光释光曲线具有典型的指数衰减特征,剂量片的偏转角度对测量值影响最大为13.5%.原料粒径的均匀度对剂量片光释光响应数据的分布一致性具有较大影响.重复性测试实验的变异系数CV=2.28%,重复测量数据的一致性较好.在1—1000 mGy剂量范围内随着辐照剂量的增加, NaCl∶Cu烧结剂量片的光释光强度逐渐增加,且呈现良好的线性关系,较未掺杂的纯氯化钠光释光响应高2—4倍.通过烧结法制备的NaCl∶Cu剂量片可用于个人或环境剂量监测用剂量计.  相似文献   
2.
基于X射线管的X射线荧光计算机断层扫描术(CT)受多种因素影响,成像质量不佳,几何参数误差是制约其高质量图像重建的重要因素之一.本文分析成像二维平面模体与探测器相对位置偏移对投影数据的影响,并基于原始投影数据和原始重建图像再投影数据的局部线性关系实现几何偏移参数校正;利用Geant4模拟存在偏移参数的扇束X射线荧光CT系统,使用模拟投影数据验证校正方法.研究结果表明:该方法能计算出相对精确的几何偏移量,有效消除几何参数误差对重建图像的影响,校正后的重建图像信息熵降低,平均梯度和标准差提高,图像质量提升.  相似文献   
3.
A simple and selective method for the determination of silver ions was developed by utilizing the red- shift in emission wavelength of the core-shell CdSe/Cd5 quantum dots (QDs) functionalized with rhodanine upon the addition of Ag+. A linear relationship was observed between the shift and the increase in concentration of Ag+ in the range of 0.0125-12.5 μmol/L. The mechanism of the red-shift was investigated and suggested that the coordination between Ag+ and rhodanine on the QDs surface caused an increase of particle size, which resulted in the red-shift of the QDs' emission wavelength. A detection limit of 2 nmol/L was achieved. The developed method showed superior selectivity and was successfully applied to the determination of silver in environmental samples.  相似文献   
4.
We investigate the effect of alpha stable noise on stochastic resonance in a single-threshold sensor system by analytic deduction and stochastic simulation. It is shown that stochastic resonance occurs in the threshold system in alpha stable noise environment, but the resonant effect becomes weakened as the alpha stable index decreases or the skewness parameter of alpha stable distribution increases. In particular, for Cauchy noise a nonlinear relation among the optimal noise deviation parameter, the signal amplitude and the threshold is analytically obtained and illustrated by using the extreme value condition for the output signal-to-noise ratio. The results presented in this communication should have application in signal detection and image restoration in the non-Gaussian noisy environment.  相似文献   
5.
The present study reports a sensitive electro-analytical method for the simultaneous determination of dihydroxybenzene isomers by using a thiadiazole film electrode, which was readily prepared by electropolymerization of 2,5-dimercapto-1,3,4-thiadiazole on a glassy carbon electrode with cyclic voltammetry. The functionalized electrode has a distinguishable and sensitive response to dihydroxybenzene isomers. Under the optimized conditions, the linear stripping peak currents showed good linear relationships with hydroquinone, catechol and resorcinol at concentration ranges 0.50-120, 0.50-110 and 1.00-110 μmol/L, and the detection limits are 0.1, 0.1 and 0.3 μmol/L, respectively. The proposed method is applicable to the simultaneous determination of dihydroxybenzene isomers in real samples with the relative standard deviations of less than 5.7% and the recovery rates of 95.6%-106%. The constructed electrode is characterized by simple preparation, good selectivity, and high sensitivity advantages.  相似文献   
6.
以甲醇作为溶剂,用紫外分光光度法测定氯氟吡氧乙酸十二酯的含量,测得氯氟吡氧乙酸十二酯对照品溶液浓度在12.0~20.0μg/mL范围之内线性关系良好,其线性方程为A=0.0815C+0.0318(R2=0.9832).平均回收率为90.86%,RSD为5.3%(n=6),结果说明方法简便、灵敏、准确,重现性好.  相似文献   
7.
Based on the photothermal detuning technique, the three linear relations among reflectance (or trans- mittance), temperature rise, and pump beam power are studied to achieve the absolute measurement of absorption loss. The relation between temperature and reflectance and the calculation accuracy of tem- perature rise on sample surface have great impacts on the measured result. The influences of parameters involved in the method and the relation between temperature and reflectance and the temperature model of sample surface are also studied. The results show that the absolute absorption loss of optical coatings can be achieved by the proposed method. The measurement accuracy depends on the temperature model and the relation between temperature and reflectance. The linear relation between reflectance and temper- ature rise has largest slope when probe beam wavelength is 632.8 nm and incident angle is 28°. The linear relation slope between temperature rise and pump beam power decreases with the growing of beam size and modulation frequency. The results provide theoretical and experimental supports for the perfection and further application of the photothermal detuning technique.  相似文献   
8.
9.
比较了Pt和Ir催化剂在中性NaCIO4电解液中对NH3氧化的电催化活性和选择性.发现NH3和NH4OH在Pt和Ir催化剂上的电氧化性能相似,因而可用NH4OH代替NH3进行研究.NH4OH在Pt和Ir催化剂上氧化峰峰电流密度与NH4OH浓度呈很好的线性关系,因而Pt和Ir均能作为控制电位电解型NH3传感器的催化剂.当NH4OH浓度为0.013 mol/L时,NH3在Pt和Ir催化剂上的氧化峰分别位于0.4和0.8 v,NH4OH在Pt催化剂上的氧化峰峰电位负于在Ir催化剂上的,这是Pt催化剂的优点,但NH4OH在Ir催化剂上的氧化峰峰电流密度为Pt催化剂上的2.5倍以上,说明NH4OH在Ir催化剂上的检测灵敏度远高于在Pt催化剂上的.而且CO对NH3在Ir催化剂上的检测没有干扰,但在Pt催化剂上有明显干扰.因此,初步的研究结果表明,Ir催化剂较适用于定电位电解型的NH3电化学传感器的阳极催化剂.  相似文献   
10.
研究了聚亚甲基蓝/单壁碳纳米管修饰电极的制备、电化学性质,采用差分脉冲伏安法成功应用于烟酰胺腺嘌呤二核苷酸(NADH)的测定.在实验条件下,该修饰电极对NADH氧化具有很好的电催化作用,NADH浓度在2.0~500靘oL/L范围内与峰电流呈良好的线性关系,检出限为0.6 靘ol/L,结果令人满意.  相似文献   
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