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1.

Polyacrylonitrile/ferrocyanide composite incorporated with cetrimonium bromide (PFICB) was synthesized and evaluated as a novel bifunctional adsorbent for coremoval of Cs+ and HCrO4?. Results of the reaction time effect showed that adsorption of Cs+ and HCrO4? onto PFICB were rapid processes. The effect of the solution pH in the range 2.5–10 revealed that PFICB had the ability to simultaneously remove Cs+ and HCrO4?. The maximum adsorption capacity of PFICB was found to be 41.79 mg/g for Cs+ and 19.39 mg/g for HCrO4?. These values were compared with those reported in literature using other adsorbents.

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In this work, for the first time, Solanum melongena plant extract was used for the green synthesis of Pd/MnO2 nanocomposite via reduction osf Pd(II) ions to Pd(0) and their immobilization on the surface of manganese dioxide (MnO2) nanoparticles (NPs) as an effective support. The synthesized nanocomposite were characterized by various analytical techniques such as Fourier transform infrared (FT‐IR), X‐ray diffraction (XRD), transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM), energy dispersive X‐ray spectroscopy (EDS) and UV–Vis spectroscopy. The catalytic activity of Pd/MnO2 nanocomposite was used as a heterogeneous catalyst for the one‐pot synthesis of 5‐substituted 1H‐tetrazoles from aryl halides containing various electron‐donating or electron‐withdrawing groups in the presence of K 4 [Fe (CN) 6 ] as non‐toxic cyanide source and sodium azide. The products were obtained in good yields via a simple methodology and easy work‐up. The nanocatalyst can be recycled and reused several times with no remarkable loss of activity.  相似文献   
4.
In this work, low‐moisture glycidyl azide polymer (GAP) was successfully prepared using a modified two‐step method. The modified method resembles the structure of the classical two‐step method, which is widely used to prepare the GAP. Firstly, epichlorohydrin (ECH) is polymerized into polyepicholorohydrin (PECH), which is subjected afterward to azidation step using sodium azide (NaN3). Interestingly, minimizing the water content in the final GAP product, which is a challenging when dealing with GAP as a rocket propellant binder, was effectively achieved by utilizing low boiling point solvents instead of the relatively high boiling point Dimethyl formamide (DMF), monitoring the volatility of ECH and controlling the exothermicity of the reaction. Prepared GAP samples were investigated using Fourier transformer infra‐red (FT‐IR), gel‐permeation chromatography (GPC) and elemental analysis apparatus (CHNS) were used to characterize the product. The moisture % in the final product was examined using the Karl‐Fisher Technique. Results showed the successful preparation of GAP with low water content (<0.01 %), high average molecular weight (> 2000 g · mol–1), 42.82 % nitrogen, a viscosity of 3484 cP at 20 °C, yield ranges between 95–98 % and a polydispersity index of 1.2. The prepared GAP is promising for replacement of the classical GAPs in the energetic materials applications.  相似文献   
5.
A new series of substituted pryrrolobenzimidazoles have been prepared via regioselective displacement of chlorine atom from dichloropyrrolobenzimidazoles with various amine nucleophiles. The dichloro compounds were obtained from the reaction of ortho phenylene diamine compounds with dichloromaleic anhydride.  相似文献   
6.
Measuring the Lewis-acidic surface sites in catalysis is problematic when the material‘s surface area is very low (SBET ≤1 m2 ⋅ g−1). For the first time, a quantitative assessment of total acidic surface sites of very small surface area catalysts (MoO3 as pure and mixed with 5–30 % CdO (wt/wt), as well as CdO for comparison) was performed using a smart new probe molecule, tetrahydrofuran (THF). The results were nearly identical compared to using another commonly used probe molecule, pyridine. This audition is based on the limited values of the surface area of these samples that likely require a relatively moderate basic molecule as THF with pKb=16.08, rather than strong basic molecules such as NH3 (pKb=4.75) or pyridine (pKb=8.77). We propose mechanisms for the interaction of vapour phase molecules of THF with the Lewis-cationic Mo and Cd atoms of these catalysts. Besides, dehydration of isopropyl alcohol was used as a probe reaction to investigate the catalytic activity of these catalysts to further support our findings in the case of THF in a temperature range of 175–300 °C. A good agreement between the obtained data of sample MoO3-10 % CdO, which is characterised by the highest surface area value, the population of Lewis-acidic sites and % selectivity of propylene at all the applied reaction temperatures was found.  相似文献   
7.
This work aimed to tune the comprehensive properties of Fe-P-C-based amorphous system through investigating the role of microalloying process on the crystallization behavior,glass forming ability(GFA),soft magnetic features,and mechanical properties.Considering minor addition of elements into the system,it was found that the simultaneous microalloying of Ni and Co leads to the highest GFA,which was due to the optimization of compositional heterogeneity and creation of near-eutectic composition.Moreover,the FeCoNiCuPC amorphous alloy exhibited the best anelastic/viscoplastic behavior under the nanoindentation test,which was owing to the intensified structural fluctuations in the system.However,the improved plasticity by the extra Cu addition comes at the expense of magnetic properties,so that the saturation magnetization of this alloying system is significantly decreased compared to the FeCoPC amorphous alloy with the highest soft magnetic properties.In total,the results indicated that a combination of added elemental constitutes,i.e.,Fe69Co5Ni5Cu1P13C7 composition,provides an optimized state for the comprehensive properties in the alloying system.  相似文献   
8.
Cross‐coupling reactions mediated by dual nickel/photocatalysis are synthetically attractive but rely mainly on expensive, non‐recyclable noble‐metal complexes as photocatalysts. Heterogeneous semiconductors, which are commonly used for artificial photosynthesis and wastewater treatment, are a sustainable alternative. Graphitic carbon nitrides, a class of metal‐free polymers that can be easily prepared from bulk chemicals, are heterogeneous semiconductors with high potential for photocatalytic organic transformations. Here, we demonstrate that graphitic carbon nitrides in combination with nickel catalysis can induce selective C?O cross‐couplings of carboxylic acids with aryl halides, yielding the respective aryl esters in excellent yield and selectivity. The heterogeneous organic photocatalyst exhibits a broad substrate scope, is able to harvest green light, and can be recycled multiple times. In situ FTIR was used to track the reaction progress to study this transformation at different irradiation wavelengths and reaction scales.  相似文献   
9.
Gold nanoparticles (AuNPs) have been demonstrated to serve as effective nanomaterial‐based enzyme mimetics (nanozymes) for a number of enzymatic reactions under mild conditions. The intrinsic glucose oxidase and peroxidase activities of single AuNPs and Ag–Au nanohybrids, respectively, were investigated by single NP collision electrochemical measurements. A significantly high turnover number of nanozymes was obtained from individual catalytic events compared with the results from the classical, ensemble‐averaged measurements. The unusual enhancement of catalytic activity of single nanozymes is believed to originate from the high accessible surface area of monodispersed NPs and the high activities of carbon‐supported NPs during single‐particle collision at a carbon ultramicroelectrode. This work introduces a new method for the precise characterization of the intrinsic catalytic activities of nanozymes, giving further insights to the design of high‐efficiency nanomaterial catalysts.  相似文献   
10.
A manifold that contains small perturbations will induce a perturbed partial differential equation. The partial differential equation that we select is the Poisson equation – in order to explore the interplay between the geometry of the manifold and the perturbations. Specifically, we show how the problem of symmetry determination, for higher-order perturbations, can be elegantly expressed via geometric conditions.  相似文献   
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