FI催化剂配体的研究进展

FI催化剂作为一类新型聚烯烃催化剂,具有高活性、耐高温等特性,在催化聚合方面表现出良好的性能,不但可以催化乙烯与极性及非极性单体共聚,而且可以通过改变主催化剂苯氧基亚胺配体的结构,得到具有不同结构的聚合物。本文介绍了FI主催化剂的基本结构、合成方法、结构与催化性能的关系以及基于苯氧基亚胺配体基本结构的新型催化剂的研究进展。     

独立寻址的色温可调白光有机电致发光二极管

提出了一种利用Ag/Al电极作为叠层结构的连接层,有效调控白色有机电致发光器件(WOLEDs)的发射光谱和提高器件的发光效率的新方法。当连接层厚度从9nm降到5nm,白光区域内的色坐标从(0.27,0.29)变化到(0.38,0.31)。此外,通过调控任意色度的互补色(蓝黄)WOLEDs,成功地制备了色温从8009K到4539K的可以独立寻址的器件。最后,论文讨论了基于独立寻址实现色温可控的红绿蓝三基色WOLEDs的光电性能。     

ITO再生处理对有机电致发光器件特性的影响

分别采用Na OH和HCl溶液对废旧氧化铟锡(ITO)基板进行再生处理,用原子力显微镜(AFM)观测了处理后的ITO表面形貌,并基于再生处理过的ITO制备了有机电致发光器件(OLED),系统研究了器件的性能。结果表明,上述方法可以有效去除废旧ITO残留的铝电极并改变其表面的化学结构,提高了器件的特性,尤其以Na OH单次处理最为有效。以此制备的OLED器件电流效率达到12.08 cd/A,较之未回收利用的新ITO所制备的器件提高了14.7%;外量子效率达到5.23%,提高了11.7%。另外,经不同方法处理后,器件中生色团与生色团之间、生色团与助色团之间的空间位阻增大,器件发光光谱肩峰效应增强。     

薄膜厚度对GZO透明导电膜及其LED器件性能的影响

采用射频磁控溅射的方法制备了GZO透明导电薄膜,通过原子力显微镜(AFM)、X射线衍射仪(XRD)、霍尔效应测试仪及紫外-可见光分光光度计等手段研究了厚度对于GZO薄膜性能的影响,并制备了相应的LED器件。实验结果表明:随着薄膜厚度增加,薄膜结晶质量提高,薄膜的电阻率也随之降低。当厚度为500 nm时,薄膜的电阻率最低为2.79×10^-4 Ω·cm,同时其在460 nm蓝光区域的光透过率高达97.9%。对所制备的以GZO薄膜为透明电极的LED器件进行了测试分析,发现GZO薄膜厚度对LED的正向电压影响不大,但对LED芯片的出光效率有较大影响。     

Improved performance of polymer solar cells by using inorganic,organic, and doped cathode buffer layers

The interface between the active layer and the electrode is one of the most critical factors that could affect the device performance of polymer solar cells. In this work, based on the typical poly(3-hexylthiophene):[6,6]-phenyl C61-butyric acid methyl ester(P3HT:PCBM) polymer solar cell, we studied the effect of the cathode buffer layer(CBL) between the top metal electrode and the active layer on the device performance. Several inorganic and organic materials commonly used as the electron injection layer in an organic light-emitting diode(OLED) were employed as the CBL in the P3HT:PCBM polymer solar cells. Our results demonstrate that the inorganic and organic materials like Cs_2CO_3, bathophenanthroline(Bphen), and 8-hydroxyquinolatolithium(Liq) can be used as CBL to efficiently improve the device performance of the P3HT:PCBM polymer solar cells. The P3HT:PCBM devices employed various CBLs possess power conversion efficiencies(PCEs) of 3.0%–3.3%, which are ca. 50% improved compared to that of the device without CBL. Furthermore, by using the doped organic materials Bphen:Cs_2CO_3 and Bphen:Liq as the CBL, the PCE of the P3HT:PCBM device will be further improved to 3.5%, which is ca. 70% higher than that of the device without a CBL and ca. 10% increased compared with that of the devices with a neat inorganic or organic CBL.     

冕西稀土成矿带氟碳铈矿自然重砂特征及其找矿意义

冕西地区稀土成矿条件优越、资源丰富,已发现的稀土矿床(点)构成一北东向长约数十公里、面积数百平方公里的稀土成矿带,氟碳铈矿作为该带内单一的工业矿物,其自然重砂分布特征明显、异常规模大、强度高,与喜山期碱性含矿杂岩体和哈哈断裂、雅砻江断裂及其派生的次级断裂等控矿构造都有成因上的联系,与La,Y化探异常吻合程度高,并与已知稀土矿床(点)有极好的响应。氟碳铈矿自然重砂异常对该成矿带内稀土矿找矿预测及勘查具有重要指示作用,其可作为重要预测因子参与该区稀土找矿预测。作者通过对区内氟碳铈矿自然重砂异常分析研究,提出了潜在找矿区域,开展异常查证有望取得找矿突破。