电催化醇选择性氧化为醛酮的研究进展

醇选择性氧化为相应的羰基化合物是有机化学中最常用的生成羰基化合物的反应,电催化氧化具有反应条件温和、环境友好等优点,是一种非常有前途的醇催化氧化绿色生产工艺。本文综述了直接和间接电催化氧化反应的方法,并对各类体系的催化效果进行了简要介绍。     

以学为中心理念下多层圆筒壁热传导教学设计及实施*

以多层圆筒壁热传导知识点为例,探索了以 “学”为中心教学模式的具体应用,结合智慧教学工具及手段,采用BOPPPS结构模式对教学重难点部分进行设计。实践结果表明,这种教学模式有利于激发学生的学习兴趣,提升学生的学习效果。     

Ultra-broadband enhanced nonlinear saturable absorption for Mo0.53W0.47Te2 nanosheets

Alloying in two-dimension has been a hot spot in the development of new,versatile systems of optics and electronics.Alloys have been demonstrated to be a fascinating strategy to modulate the chemical and electronic properties of two-dimensional nanosheets.We firstly reported ultra-broadband enhanced nonlinear saturable absorption of Mo0.53W0.47Te2 alloy at 0.6,1.0,and 2.0μm.The nonlinear saturable absorption of Mo0.53W0.47Te2 saturable absorber(SA)was measured by the open aperture Z-scan technique.Compared to MoTe2 and WTe2 SAs,the Mo0.53W0.47Te2 SA showed five times deeper modulation depth,8.6%lower saturable intensity,and one order larger figure of merit.Thus,our research provides a method of alloys to find novel materials with more outstanding properties for optics and optoelectronic applications.