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利用PVA侧链上的羟基的化学活性, 采用超支化聚胺-酯对改性纳米SiO2和PVA接枝改性, 并加入不同锂盐,制备了SiO2-g-HBPAE/PVA-g-HBPAE超支化/梳状复合型聚合物电解质, 利用SEM观察了纳米粒子在基体中的分散情况, 采用DSC、拉伸实验以及介电谱研究了锂盐种类及添加量对复合体系性能的影响. 结果表明, 超支化接枝改善了SiO2和基体的界面相容性; 磺酸类锂盐在复合材料中表现出自增塑现象, 材料的玻璃化转变温度(Tg)大幅度下降; LiClO4在基体中的离解能力强于LiCF3SO3和 LiN(SO3CF3)2; 当LiCF3SO3添加量为20 %(by mass, 下文同)时, 聚合物电解质的室温电导率达到最大值2.58×10-6 S•cm-1. 相似文献
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To improve creep resistance of directional polytetrafluoroethylene (PTFE) films, epoxy grafted nano-SiO2 is mixed with PTFE powder before sintering and calender rolling. The aligned macromolecular chains (especially those in amorphous region) of the composite films can be bundled up by the nanoparticles to share the applied stress together. In addition, incorporation of silica nanoparticles increases crystallinity of PTFE and favors microfibrillation of PTFE in the course of large deformation. As result, PTFE films exhibit lower creep strain and creep rate, and higher tensile strength and hardness. The work is believed to open an avenue for manufacturing high performance fluoropolymers by nano-inclusions. 相似文献
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纤维素芳族酯热致液晶对PET结晶成核作用的研究 总被引:3,自引:1,他引:2
用自制的热致液晶性纤维素芳族酯(CAE)作聚对苯二甲酸乙二醇酯(PET)的成核剂,研究了PET/CAE体系(CAE含量≤1%)在110~200℃温度范围内的等温结晶动力学特性.结果表明,CAE能显著加快PET结晶速率(Z),Z随结晶温度和CAE含量变化均有极大值Zmax(TC)和Zmax(WCAE),Zmax(TC)对应的温度Tmax随CAE含量增加而降低,CAE促进PET结晶的作用机理与普通成核剂不同. 相似文献
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